Bromyl fluoride

Bromyl fluoride
Names
Other names
Bromine fluoride dioxide
Identifiers
3D model (JSmol)
  • InChI=1S/BrFO2/c2-1(3)4
    Key: MQCDGGKZTTYBRJ-UHFFFAOYSA-N
  • O=Br(=O)F
Properties
BrFO2
Molar mass 130.900 g·mol−1
Appearance colorless liquid
Melting point −9 °C (16 °F; 264 K)
reacts with water
Related compounds
Related compounds
 Iodyl fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Bromyl fluoride is an inorganic compound of bromine, fluorine, and oxygen with the chemical formula BrO2F.[1][2]

Synthesis

  • A reaction of K[BrF4O] with HF.[3]
  • Also, reactions of BrF5 with IO2F, IOF3, and I2O5 produce BrO2F.[3]
  • Hydrolysis of bromine pentafluoride at low temperatures:
BrF5 + 2H2O → BrO2F + 4HF

Physical properties

The compound forms a colorless volatile liquid that decomposes at temperatures above 10°C. Corrodes glass at room temperature. Highly reactive and unstable.[4]

Chemical properties

  • Decomposes when heated:
3BrO2F → BrF3 + Br2 + 3O2
  • Reacts violently with water (with an explosion):
BrO2F + H2O → HBrO3 + HF
  • Reacts with alkalis:
BrO2F + 2NaOH → NaBrO3 + NaF + H2O

References

  1. ^ Christe, Karl O.; Curtis, E. C.; Jacob, Eberhard (1 October 1978). "Bromyl fluoride. Vibrational spectra, force field, and thermodynamic properties". Inorganic Chemistry. 17 (10): 2744–2749. doi:10.1021/ic50188a011. ISSN 0020-1669. Retrieved 5 June 2023.
  2. ^ Baran, Enrique J. (January 1976). "Vibrational Properties of Bromyl Fluoride". Spectroscopy Letters. 9 (6): 323–327. doi:10.1080/00387017608067443. ISSN 0038-7010. Retrieved 5 June 2023.
  3. ^ a b Gillespie, Ronald J.; Spekkens, Paul H. (1 January 1977). "Bromyl fluoride and bromosyl trifluoride: preparation and chemical and spectroscopic properties". Journal of the Chemical Society, Dalton Transactions (16): 1539–1546. doi:10.1039/DT9770001539. ISSN 1364-5447. Retrieved 5 June 2023.
  4. ^ Seppelt, Konrad (19 December 2019). "Reactions of Bromine Fluoride Dioxide, BrO 2 F, for the Generation of the Mixed‐Valent Bromine Oxygen Cations Br 3 O 4 + and Br 3 O 6 +". Angewandte Chemie International Edition. 58 (52): 18928–18930. doi:10.1002/anie.201912271. ISSN 1433-7851. PMC 6973041. Retrieved 5 June 2023.

Read other articles:

Daftar pembawa bendera Argentina pada Olimpiade

Argentina padaOlimpiadeKode IOCARGKONKomite Olimpiade ArgentinaSitus webwww.coarg.org.ar (dalam bahasa Spanyol)Medali 21 25 28 Total 74 Penampilan Musim Panas1900190419081912192019241928193219361948195219561960196419681972197619801984198819921996200020042008201220162020Penampilan Musim Dingin19281932–193619481952195619601964196819721976198019841988199219941998200220062010201420182022 Cristian Simari Birkner membawa bendera Argentina pada Olimpiade Musim Dingin 2010 di Vancouv...

 

 

Pertapaan Bunda Pemersatu Gedono

Pertapaan GedonoInformasi biaraNama lengkapPertapaan Bunda Pemersatu GedonoOrdoTrapis (OCSO)Didirikan12 April 1987Biara indukPertapaan Santa Maria Rawaseneng, TemanggungDidedikasikan kepadaMaria Bunda PemersatuKeuskupanKeuskupan Agung SemarangTokohPendiriDom Frans Harjawiyata, OCSOAbbasIbu Abdis Martha Elisabeth Driscoll, OCSOTokoh penting yang terkaitIbu Abdis Cristiana Piccardo, OCSORomo Suitbertus Ari Sunardi OCSOArsitekturArsitekRD Y.B. MangunwijayaSitusLokasiDusun Weru,Desa Jetak,Getasan...

 

 

THEO

Orbiter mission to Enceladus This article is about the proposed space mission. For other uses, see Theo (disambiguation). THEONamesTesting the Habitability of Enceladus's Ocean (THEO)Mission typeAstrobiology reconnaissanceOperatorNASAMission durationproposed: 6-month science phase[1] Spacecraft propertiesSpacecraftTHEOPayload mass≈80 kg[2]Dimensionscylindrical: 4.5 m height × 1. m diameter[2]Power594 W from a 72 m2 solar array Start of missionLau...

2006 UEFA Super Cup

Football match2006 UEFA Super CupMatch programme coverEvent31st UEFA Super Cup Barcelona Sevilla 0 3 Date25 August 2006VenueStade Louis II, MonacoMan of the MatchDani Alves (Sevilla)[1]RefereeStefano Farina (Italy)[2]Attendance17,480[3]← 2005 2007 → The 2006 UEFA Super Cup was the 31st edition of the annual UEFA Super Cup, a UEFA-sponsored football club match that pitted the winners of the UEFA Champions League against the winners of the UEFA Cup. It took p...

 

 

KSWH-LP

Radio station at Henderson State University in Arkadelphia, Arkansas KSWH-LPArkadelphia, ArkansasBroadcast areaClark County, ArkansasFrequency102.5 MHzBrandingThe Pulse 102.5ProgrammingFormatDefunct (formerly College)OwnershipOwnerHenderson State University FoundationHistoryFirst air dateSeptember 5, 1969 (KSWH-FM)2004Former frequencies99.9 MHz (2003-2014)Technical informationFacility ID134820ClassL1ERP100 wattsHAAT30 meters (98 feet)Transmitter coordinates34°07′44″N 93°03′37″Wþ...

 

 

Sulqan Rural District

Rural district in Tehran province, Iran Rural District in Tehran, IranSulqan Rural District Persian: دهستان سولقانRural DistrictSulqan Rural DistrictCoordinates: 35°52′35″N 51°14′06″E / 35.87639°N 51.23500°E / 35.87639; 51.23500[1]CountryIranProvinceTehranCountyTehranDistrictKanElevation1,600−1,750 m (−4,140 ft)Population (2016)[2] • Total5,013Time zoneUTC+3:30 (IRST) Sulqan Rural District...

David Thewlis

David ThewlisThewlis pada tahun 2008LahirDavid Thewlis20 Maret 1963 (umur 61)Blackpool, InggrisPekerjaanAktor, Sutradara, Penulis skenario, PengarangTahun aktif1985-sekarangSuami/istriSara Sugarman ​ ​(m. 1992; c. 1994)​PasanganAnna Friel(2001–2010)Anak1 David Wheeler (lahir 20 Maret 1963), dikenal secara profesional sebagai David Thewlis (/ˈθjuːlɪs/), adalah seorang aktor Inggris, sutradara, penulis skenario, dan Pengarang. The...

 

 

Palmarès des nations au Championnat du monde masculin de handball

Cet article reprend le palmarès par nation du Championnat du monde masculin de handball. D'abord de périodicité non définie, celle-ci devient biennale – les années impaires – à partir de 1993. Le tenant du titre est le Danemark. Les finales Édition Nbpart. Pays hôte(s) Finale Petite finale no  Année Champion Score Finaliste Troisième Score Quatrième 1re 1938 4 Allemagne Allemagne (1/3) TTR Autriche Suède TTR Danemark 2e 1954 6 Suède Suède (1/4) 17 − 14 Équipe unifié...

 

 

German submarine U-1303

German World War II submarine U-995 Type VIIC/41 at the Laboe Naval Memorial. This U-boat is almost identical to U-1303. History Nazi Germany NameU-1303 Ordered2 April 1942 BuilderFlensburger Schiffbau-Gesellschaft, Flensburg Yard number496 Laid down8 April 1943 Launched10 February 1944 Commissioned5 April 1944 FateScuttled on 5 May 1945 General characteristics TypeType VIIC/41 submarine Displacement 757 long tons (769 t) surfaced 857 long tons (871 t) submerged Length 67.10 m ...

Coca-Cola Coliseum

Arena at Exhibition Place in Toronto, Canada Coca-Cola ColiseumCoca-Cola ColiseumLocation in TorontoShow map of TorontoCoca-Cola ColiseumLocation in OntarioShow map of OntarioCoca-Cola ColiseumLocation in CanadaShow map of CanadaFormer names CNE Coliseum (1921–2003) Royal Coliseum[1] Ricoh Coliseum (2003–2018) Toronto Coliseum (July 2015) Address45 Manitoba DriveLocationToronto, Ontario, CanadaCoordinates43°38′09″N 79°24′54″W / 43.63583°N 79.41500°W...

 

 

Hougomont (barque)

Four-masted steel barque Not to be confused with Hougoumont (ship). Hougomont docked in an unidentified port circa 1900 (State Library of South Australia PRG 1373-15-80) History NameHougomont OperatorGustaf Erikson[1] BuilderScott Shipbuilding and Engineering Company, Greenock, Scotland[2] Completed1897 FateScuttled 8 January 1933 in Stenhouse Bay Statushistoric shipwreck[2] General characteristics TypeBarque[2] Tonnage2378[2] Length292 ft 3 i...

 

 

Victor and Corona

2nd-century Christian martyrs SaintsVictor and CoronaIlluminated miniature of the martyrdom of Saints Victor and Corona, on a full leaf from a Book of Hours, France (Paris), c. 1480.MartyrsDiedc. 170 ADVenerated inRoman Catholic ChurchEastern Orthodox ChurchFeast14 May (Roman Catholic Church)11 November (Eastern Orthodox Church, Julian calendar)PatronageFeltre; Castelfidardo; Corona is invoked in connection with causes involving money, such as gambling or treasure hunting. Saints Victor ...

American Physical Society

Organization of physicists Not to be confused with the American Physical Society which was absorbed by the Royal Physical Society of Edinburgh in 1796. American Physical SocietyAbbreviationAPSFormationMay 20, 1899; 125 years ago (1899-05-20)TypeScientificPurposeTo advance and diffuse the knowledge of physicsLocationAmerican Center for PhysicsCollege Park, Maryland, United StatesMembership 50,000Websitewww.aps.org The American Physical Society (APS) is a not-for-profit member...

 

 

Three Forms of Unity

Reformed church originating in continental Europe The Three Forms of Unity is a collective name for the Belgic Confession, the Canons of Dort, and the Heidelberg Catechism, which reflect the doctrinal concerns of continental Calvinism and are accepted as official statements of doctrine by many Calvinist churches. History The Synod held at Dort From 1618 to 1619, the Dutch government on behalf of the Dutch Reformed Church, called and convened the Synod of Dort. Dutch delegates, along with twen...

 

 

Fredericton

Capital city of New Brunswick, Canada This article is about the capital of New Brunswick. For other uses, see Fredericton (disambiguation). City in New Brunswick, CanadaFrederictonCityThe City of Fredericton[a]From top to bottom; left to right: Fredericton skyline, Pedestrian bridge of the Nashwaak River, Christ Church Cathedral, New Brunswick Legislative Building FlagCoat of armsLogoNicknames: Freddy, Freddy BeachMotto(s): Fredericopolis, silvae filia nobilis  (La...

Binary blob

Software published only in binary code Not to be confused with Binary large object (BLOB). In the context of free and open-source software, proprietary software only available as a binary executable is referred to as a blob or binary blob. The term usually refers to a device driver module loaded into the kernel of an open-source operating system, and is sometimes also applied to code running outside the kernel, such as system firmware images, microcode updates, or userland programs.[1]...

 

 

إسحاق خالاتنيكوف

إسحاق خالاتنيكوف (بالروسية: Исаак Маркович Халатников)‏  معلومات شخصية الميلاد 17 أكتوبر 1919 [1]  دنِبرُو[2]  الوفاة 9 يناير 2021 (101 سنة) [3]  تشيرنوغولوفكا  مواطنة الاتحاد السوفيتي  عضو في الجمعية الملكية،  والأكاديمية الروسية للعلوم،  وأكاديمية ...

 

 

Circulo Cubano de Tampa

United States historic placeCirculo Cubano de TampaU.S. National Register of Historic Places Show map of FloridaShow map of the United StatesLocation10th Ave. and 14th St., Tampa, FloridaCoordinates27°57′44″N 82°26′40″W / 27.96222°N 82.44444°W / 27.96222; -82.44444Arealess than one acreNRHP reference No.72000320[1]Added to NRHPNovember 15, 1972 Wikimedia Commons has media related to Circulo Cubano de Tampa. Informational sign in front of C...

Sumatera Tengah

Sumatera TengahBekas provinsi Indonesia1948–1957Lokasi Sumatera Tengah di IndonesiaIbu kotaBukittinggiSejarahPemerintahan • JenisProvinsiGubernur • 1948–1950 Mohammad Nasroen• 1951–1958 Roeslan Moeljohardjo Sejarah • Dimekarkan dari Sumatera 1948• Dipecah menjadi 3 provinsi 1957 Didahului oleh Digantikan oleh Sumatera (provinsi Indonesia) Sumatera Barat Riau Jambi Sumatera Tengah adalah sebuah provinsi Republik Indonesia yang wujud antar...

 

 

Lantatur

Jendela drive-through McDonald's di Inggris. Beberapa rantai makanan cepat saji, seperti ini Rally yang terletak di dekat New Orleans, LA, memiliki dua drive-throughs. Kotak surat drive-through di AS. Lantatur atau kendara lewat (bahasa Inggris: drive-through atau drive-thru) adalah jenis layanan pesan bawa pulang yang disediakan suatu niaga, di mana pelanggannya dapat menggunakan suatu layanan atau membeli suatu produk tanpa perlu meninggalkan mobil atau sepeda motor. Cara ini pertama ka...