Tellurite fluoride

A tellurite fluoride is a mixed anion compound containing tellurite and fluoride ions. They have also been called oxyfluorotellurate(IV) where IV is the oxidation state of tellurium in tellurite.

Comparable compounds are sulfite fluorides or selenite fluorides.

List

name formula ratio

TeO3:F

mw crystal
system 		space group unit cell Å volume density optical comment references
Li7(TeO3)3F P63 a =11.4178 c =4.8433 band gap 4.75 eV
KTe3O6F 3:1 rhombohedral R3 a=9.486, c=13.774, Z=6 [1]
ScTeO3F 239.56 orthorhombic Pnma a = 5.7740 b = 22.062 c = 5.500 700.6 colourless [2]
titanium(IV) tellurium(IV) trioxide difluoride TiTeO3F2 1:1 361.50 orthorhombic Pnma a = 7.392 b = 16.369 c=6.4886 Z=8 785.1 colourless [3]
divanadium(IV) ditellurium(IV) heptaoxide difluoride V2Te2O7F2 2:2 507.38 triclinic P1 a = 4.882 b = 5.112 c = 7.243 α = 108.17° β = 91.64° γ = 92.63° 171.4 green-brown [3]
CrIIITeO3F 1:1 [4]
FeTeO3F 1:1 250.45 monoclinic P21/n a = 5.0667 b = 5.0550 c = 12.397 β = 97.63° Z=4 314.72 green [4]
Co2TeO3F2 1:2 331.46 orthorhombic Pnma a=7.3810 b=10.1936 c=5.3013 Z=4 398.86 5.520 purple [5]
Co15F2(TeO3)14 14:2 3380.35 trigonal R3 a =11.6649 c =27.317 Z=3 3219.1 5.231 blue [6]
Cu7(TeO3)6F2 6:2 triclinic P1 a =4.9844 b =9.4724 c =9.958, α =82.318° β =76.275° γ =78.847° [7]
GaTeO3F 1:1 monoclinic P21/n a = 5.0625 b = 4.9873 c = 12.166 β = 97.952 (13)° Z=4 304.22 colourless [4]
RbTe3O6F 3:1
InTeO3F 1:1 309.42 a = 7.939 b = 5.3867 c = 8.053 β = 91.06° 344.35 colourless [8][2]
InTe2O5F 2:1 orthorhombic Cmmm a = 7.850, b = 27.637, c = 4.098, Z = 4 889.1 [8]
In3TeO3F7 1:7 orthorhombic Cmmm a  = 7.850(2) A, b  = 27.637(6) A, c  = 4.098 [8][9]
In3(SO4)(TeO3)2F3(H2O) P212121 a =8.3115 b =9.4341 c =14.807 band gap 4.10 eV [10]
BaF2TeF2(OH)2 Pmn21 SHG ~3 × KDP fluorotellurite [11]
Ba2Ga3F3(Te6F2O16) a =8.8753 b =8.8753 c =11.655 band gap 4.4 eV [12]
Ba(MoOF2)(TeO4) 1:2 478.87 monoclinic P21/c a 5.4281 b 10.1306 c 12.3186 β 116.145° Z=4 608.09 5.231 colourless [13]
Ba(MoO2F)2(TeO3)2 2:2 782.42 orthorhombic Aba2 a=12.5605 b=11.0264 c=7.2858 Z=4 1009.1 5.150 colourless [14]
Ba(WOF2)(TeO4) 566.77 monoclinic P21/c a 5.4483 b 10.0179 c 12.3134 β 115.422(6)° Z=4 607.00 6.202 green [13]
Pb2Al3F3(Te6F2O16) orthorhombic P4/mbm a =8.7627 b =8.7627 c =11.235 band gap 4.1 eV [12]
PbVTeO5F 484.73 orthorhombic Pbca a=9.8976 b=8.0685 c=13.070 1043.8 6.169 orange;

birefringence 0.142 at 590 nm

Pb2Ga3F3(Te6F2O16) orthorhombic P4/mbm a =8.8439 b =8.8439 c =11.580 band gap 4.2 eV [12]
Bi4TeO4F2(TeO3)2(SeO3)2 2:2 1670.64 monoclinic P21/c a=7.0304 b=6.6782 c=17.355 β=106.155 Z=2 782.66 7.089 colourless [15]

References

  1. ^ Laval, J.P.; Guillet, L.; Frit, B. (April 2002). "KTe3O6F: a new layer TeO2 structure, stuffed with KF units". Solid State Sciences. 4 (4): 549–556. Bibcode:2002SSSci...4..549L. doi:10.1016/S1293-2558(02)01290-6.
  2. ^ a b Jennene Boukharrata, Nefla; Laval, Jean-Paul; Thomas, Philippe (2008-07-15). "Two new types of oxyfluorotellurates(IV): ScTeO 3 F and InTeO 3 F". Acta Crystallographica Section C Crystal Structure Communications. 64 (7): i57 – i61. Bibcode:2008AcCrC..64I..57J. doi:10.1107/S0108270108017150. ISSN 0108-2701. PMID 18599966.
  3. ^ a b Laval, Jean Paul; Jennene Boukharrata, Nefla (2009-01-15). "New vanadium(IV) and titanium(IV) oxyfluorotellurates(IV): V 2 Te 2 O 7 F 2 and TiTeO 3 F 2". Acta Crystallographica Section C Crystal Structure Communications. 65 (1): i1 – i6. Bibcode:2009AcCrC..65I...1L. doi:10.1107/S0108270108036755. ISSN 0108-2701. PMID 19129587.
  4. ^ a b c Laval, Jean Paul; Jennene Boukharrata, Nefla; Thomas, Philippe (2008-02-15). "New oxyfluorotellurates(IV): M TeO 3 F ( M = Fe III , Ga III and Cr III )". Acta Crystallographica Section C Crystal Structure Communications. 64 (2): i12 – i14. Bibcode:2008AcCrC..64I..12L. doi:10.1107/S0108270107062683. ISSN 0108-2701. PMID 18252985. S2CID 22908353.
  5. ^ Hu, Shichao; Johnsson, Mats (2012). "Synthesis and crystal structure of two synthetic oxofluoride framework compounds – Co2TeO3F2 and Co2SeO3F2". Dalton Transactions. 41 (41): 12786–12789. doi:10.1039/c2dt31188g. ISSN 1477-9226. PMID 22968840.
  6. ^ Lü, Minfeng; Jiang, Jianhua; Zhu, Bei; Zhao, Yuwei; Zhu, Tianyu; Yang, Haoming; Jin, Yong; Kabbour, Houria; Choi, Kwang-Yong; Harrison, William T. A. (2020). "Lone-pair self-containment in pyritohedron-shaped closed cavities: optimized hydrothermal synthesis, structure, magnetism and lattice thermal conductivity of Co 15 F 2 (TeO 3 ) 14". Dalton Transactions. 49 (7): 2234–2243. doi:10.1039/C9DT04176A. hdl:2164/15901. ISSN 1477-9226. PMID 32003383. S2CID 210983894.
  7. ^ Hu, Shichao; Mace, Amber; Johnsson, Mats; Gnezdilov, Vladimir; Lemmens, Peter; Tapp, Joshua; Möller, Angela (2014-07-21). "Crystal Structure and Magnetic Properties of the S = 1 / 2 Quantum Spin System Cu 7 (TeO 3 ) 6 F 2 with Mixed Dimensionality". Inorganic Chemistry. 53 (14): 7661–7667. doi:10.1021/ic5009686. ISSN 0020-1669. PMID 24956023.
  8. ^ a b c Jennene Boukharrata, N.; Laval, J.P. (February 2011). "Synthesis and structure determination of In3TeO3F7: An indium oxyfluorotellurate IV derived from W bronze structure with Te4+ in hexagonal tunnels". Journal of Alloys and Compounds. 509 (5): 1517–1522. doi:10.1016/j.jallcom.2010.10.139.
  9. ^ Jennene Boukharrata, N.; Laval, J.P. (February 2011). "Synthesis and structure determination of In3TeO3F7: An indium oxyfluorotellurate IV derived from W bronze structure with Te4+ in hexagonal tunnels". Journal of Alloys and Compounds. 509 (5): 1517–1522. doi:10.1016/j.jallcom.2010.10.139.
  10. ^ Gong, Ya-Ping; Ma, Yun-Xiang; Ying, Shao-Ming; Mao, Jiang-Gao; Kong, Fang (2019-08-19). "Two Indium Sulfate Tellurites: Centrosymmetric In 2 (SO 4 )(TeO 3 )(OH) 2 (H 2 O) and Non-centrosymmetric In 3 (SO 4 )(TeO 3 ) 2 F 3 (H 2 O)". Inorganic Chemistry. 58 (16): 11155–11163. doi:10.1021/acs.inorgchem.9b01730. ISSN 0020-1669. PMID 31365247. S2CID 199054944.
  11. ^ Zhou, Jinjie; Wu, Hongping; Yu, Hongwei; Jiang, Shutong; Hu, Zhanggui; Wang, Jiyang; Wu, Yicheng; Halasyamani, P. Shiv (2020-03-11). "BaF 2 TeF 2 (OH) 2 : A UV Nonlinear Optical Fluorotellurite Material Designed by Band-Gap Engineering". Journal of the American Chemical Society. 142 (10): 4616–4620. doi:10.1021/jacs.0c00702. ISSN 0002-7863. PMID 32096982. S2CID 211525259.
  12. ^ a b c Li, Peng-Fei; Kong, Fang; Mao, Jiang-Gao (June 2020). "MII2M3IIIF3(Te6F2O16) (MII = Pb, Ba; MIII = Al, Ga): New mixed anionic tellurites with isolated Te6 coplanar rings". Journal of Solid State Chemistry. 286: 121288. Bibcode:2020JSSCh.28621288L. doi:10.1016/j.jssc.2020.121288. S2CID 213626229.
  13. ^ a b Liang, Ming-Li; Ma, Yun-Xiang; Hu, Chun-Li; Kong, Fang; Mao, Jiang-Gao (2018). "A(VO 2 F)(SeO 3 ) (A = Sr, Ba) and Ba(MOF 2 )(TeO 4 ) (M = Mo, W): first examples of alkali-earth selenites/tellurites with a fluorinated d 0 -TM octahedron". Dalton Transactions. 47 (5): 1513–1519. doi:10.1039/C7DT04442A. ISSN 1477-9226. PMID 29313546.
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