Selenite fluoride

A selenite fluoride is a chemical compound or salt that contains fluoride and selenite anions (F−
 and SeO2−
3). These are mixed anion compounds. Some have third anions, including nitrate (NO−
3), molybdate (MoO2−
4), oxalate (C
2O2−
4), selenate (SeO2−
4), silicate (SiO2−
4) and tellurate (TeO2−
4).

Naming

A selenite fluoride compound may also be called a fluoride oxoselenate(IV) using IUPAC naming for inorganic compounds.

Production

Rare earth selenite fluorides can be produced by dissolving the rare earth selenate into molten lithium fluoride at over 800°C, whereupon the selenate loses oxygen to become selenite, and crystals of the selenite fluoride can form.[1] Another similar method involves heating the rare earth oxide, with a rare earth fluoride and selenium dioxide with a caesium bromide flux. If glass or silica containers are used, they are eaten away by the molten flux and silicates are formed some of which may be fluoride selenite silicate compounds.[2]

Related to these are the selenite chlorides and selenite bromides by varying the halogenide. Similar compounds by varying the chalcogen also include the sulfite fluorides and tellurite fluorides.

List

name formula ratio

SeO3:F

mw system space group unit cell Å volume density optical references
scandium selenite fluoride ScSeO3F 1:1 triclinic P1 <13 −173°C a=6.2769 b=6.5578 c=4.0627 α=95.478 β=95.332 γ=92.363 Z=2 3.830 [3]
monoclinic P21/m >13 a=4.0643 b =6.6109 c=6.32.35 β=93.298° Z=2 [2]
Na3Ti3O3(SeO3)4F 4:1 hexagonal P63 a =12.8439 c =5.2339 SHG 6 × KDP [4]
dimanganese difluoride selenite Mn2SeO3F2 1:2 274.83 orthorhombic Pnma a = 7.50848 b = 10.350 and c = 5.47697 Z=4 pink [5]
ferric difluoride selenite FeSeO3F 1:1 201.81 monoclinic P21/n a=4.9559 b=5.2023 c=12.040 β=97.87 Z=4 307.50 4.359 yellow [6]
ammonium diferric trifluoride diselenite NH4Fe2F3(SeO3)2 2:3 [7]
piperizinium [C4N2H12]Fe4F6(SeO3)4 2:3 933.40 monoclinic C2/c a=15.168 b=7.3973 c=16.127 β=90.044 Z=5 1928.9 3.14 brown [7]
diethylenetriamine [C4N3H14]Fe4F6(SeO3)4 2:3 [7]
dicobalt difluoride selenite Co2SeO3F2 1:2 282.82 orthorhombic Pnma a = 7.2655 b = 10.001 c = 5.3564 Z=4 389.22 4.826 pink [8]
Ni2(SeO3)F2 1:2 282.3 orthorhombic Pnma a=7.1727 b=9.9377 c=5.2364 373.25 yellow [9]
dicopper difluoride selenite Cu2(SeO3)F2 1:2 292.05 orthorhombic Pnma a = 7.066 b = 9.590 c = 5.563 Z=4 377.0 5.146 light green [10]
dizinc difluoride selenite Zn2(SeO3)F2 1:2 295.70 orthorhombic Pnma a=7.276 b=10.042 c=5.256 Z=4 384.0 5.114 colourless [11]
triethylenediamin-di-ium digallium hexafluoride selenite C6H14N2Ga2F6SeO3 1:6 494.59 Monoclinic P21/c a=12.616 b=7.2700 c=13.605 β=104.746 Z=4 1206.8 2.722 colourless [12]
ethelenediamin-di-ium gallium trifluoride selenite C2H10N2GaF3SeO3 1:3 315.80 monoclinic P21/c a=9.1107 b=8.0382 c=10.8302 β=90.045 Z=4 793.1 2.2355 colourless [12]
piperizin-di-ium gallium fluoride oxalate selenite hydrate H2pipGaFSeO3[C2O4]H2O 1:1 409.87 triclinic P1 a=6.377 b=9.2820 c=11.4112 α=66.53 β=77.44 γ=71.89 585.47 2.325 colourless [12]
(C4H15N3)2Ga4F2(SeO3)6(C2O4).4H2O 6:2 1467.11 triclinic P1 a=8.9941 b=9.4963 c=11.2959 α=77.13 β=68.073 γ=83.776 Z=1 872.17 2.793 colourless [12]
Sr(VO2F)(SeO3) 316.52 orthorhombic Pbca a=9.7816 b=8.0278 c=12.927 Z=8 1015.07 4.142 yellow [13]
yttrium selenite fluoride YSeO3F 1:1 monoclinic P21/c <319 a=6.5765 b=6.8971 c=7.1728 β=99.036 Z=4 [14][3][15]
monoclinc P 21/m >319 600° a=6.5840 b=6.9809 c=4.3434 β =95.032 Z=2 3.922 [3]
Ag3Ti3O3(SeO3)4F 1042.15 hexagonal P63 a=12.8975 c=5.2180 Z=2 751.70 4.604 colourless SHG 2×KDP [16]
Ag2ZrF2(SeO3)2 598.88 orthorhombic Cmca a=7.3640 b=31.451 c=6.2719 1452.6 5.477 colopurless [16]
dicadmium difluoride selenite Cd2(SeO3)F2 1:2 389.76 orthorhombic Pnma a=7.803 b=10.566 c=5.729 Z=4 472.4 5.480 colourless [11]
ethelenediamin-di-ium indium trifluoride selenite C2H10N2InF3SeO3 360.90 monoclinic P21/c a=9.3066 b=8.3012 c=11.2923 Z=4 871.68 2.750 colourless [12]
caesium triscandium hexafluoride diselenite CsSc3F6[SeO3]2 2:6 trigonal P3m1 a = 5.6534 c = 10.6987 Z = 1 [17]
Cs(TiOF)3(SeO3)2 2:3 635.53 hexagonal P63mc a=7.2420 c=11.8152 Z=2 536.65 3.933 Colourless SHG 5xKDP [18]
caesium triiron hexafluoride diselenite CsFe3(SeO3)2F6 2:6 trigonal P3m1 a=5.459 c=10.537 Z=1 271.9 cyan [19]
Ba(VO2F)(SeO3) 366.24 orthorhombic Pbca a=10.0539 b=8.3967 c=13.174 1112.18 4.375 yellow [13]
lanthanum selenite fluoride LaSeO3F 1:1 monoclinic P21/c a = 18.198 b = 7.1575 c = 8.464 β = 96.89 Z = 12 [1][20]
cerium selenite fluoride CeSeO3F 1:1 [14]
tetrapraseodymium selenate diselenite hexafluoride Pr4(SeO3)2(SeO4)F6 2:6 monoclinic C2/c a = 22.305 b = 7.1054 c = 8.356 β = 98.05° Z = 4 [21]
tripraseodymium fluoride tetraselenite Pr3F[SeO3]4 pale green [22]
Pr5F[SiO4]2[SeO3]3 3:1 triclinic P1 a = 7.0114 b = 9.8268 c = 12.8679 α = 70.552 β = 76.904 γ = 69.417° Z = 2 5.511 pale green [22]
trineodymium fluoride tetraselenite Nd3(SeO3)4F hexagonal P63mc a=10.515 c=7.1211 [23]
trisamarium fluoride tetraselenite Sm3(SeO3)4F hexagonal P63mc a=10.474 c=7.0224 [23]
trigadolinium tetraselenite fluoride Gd3(SeO3)4F 4:1 hexagonal P63mc a = 10.443 b = 6.9432 Z=2 [24][1]
tridysprosium tetraselenite fluoride Dy3(SeO3)4F 4:1 1014.34 hexagonal P63mc a=10.360 c=6.8647 Z=2 [1]
holmium selenite fluoride HoSeO3F 1:1 monoclinic P21/c a=6.5784 b=6.8873 c=7.1825 β =99.213 Z=4 6.43 [15]
Ho3F[SeO3]4 4:1 hexagonal P63mc a = 10.3024 c = 6.8037 Z = 2 [25]
erbium selenite fluoride ErSeO3F 1:1 monoclinic P21/c a=6.5553 b=6.8741 c=7.1516 β =99.020 Z=4 6.54 [15]
Er3F[SiO4][SeO3]2 2:1 orthorhombic Pnna a = 5.8692 b = 15.2931 c = 10.2967 Z = 4 pink [22][26]
thulium selenite fluoride TmSeO3F 1:1 monoclinic P21/c a=6.5342 b=68607 c=7.1213 β =98,828 Z=4 6.63 [15]
ytterbium selenite fluoride YbSeO3F 1:1 monoclinic P21/c a=6.5146 b=6.8475 c=7.0924 β =98.637 Z=4 6.77 [15]
Lutetium selenite fluoride LuF[SeO3] 1:1 monoclinic P21/c −173°C: a=6.4839 b=6.8128 c=7.0581 β=98.657 Z=4 308.23 6.916 [14]
triclinic P1 a=6.4486 b=6.8441 c=4.2798 α=94.063 β=98.657 γ=91.895 Z=2 187.04 5.698 [14]
monoclinic P21/m 173°C: a=6.4734 b=6.8702 c=4.2843 β=95.602 Z=2 189.63 5.621 [14]
trilutetium fluoride tetraselenite Lu3F(SeO3)4 4:1 1051.75 trigonal P63 a=9.883 c=7.066 Z=2 597.7 5.844 colourless SHG 2.5×KDP [27]
PbVO2(SeO3)F 1:1 436.09 orthorhombic Pbca a=9.812 b=8.147 c=13.026 Z=8 1041.3 5.563 yellow [28]
cadmium lead fluoride nitrate selenite PbCdF(SeO3)(NO3) 1:1 orthorhombic Pca21 a=11.121 b=10.366 c=5.3950 Z=4 621.9 5.634 SHG 2.6×KDP band gap 4.42 eV [29]
bismuth selenite fluoride BiFSeO3 1:1 354.94 orthorhombic Pca21 a=6.6774 b=6.8872 c=7.4702 Z=4 343.54 6.862 colourless SHG 13.5×KDP [30]
tribismuth triselenite pyroselenite fluoride Bi3(SeO3)3(Se2O5)F 3:1 monoclinic F21 SHG 3×KDP [31]
dibismuth potassium pentafluoride selenite KBi2SeO3F5 1:5 679.02 orthorhombic Pbcm a=4.553 b=17.80 c=8.80 Z=4 712.9 6.326 white band gap 4.08 eV [32]
dibismuth rubidium pentafluoride selenite RbBi2SeO3F5 1:5 725.39 Triclinic P1 a=8.842 b=8.917 c=9.63 α=88.28 β=89.82 γ=89.76 Z=4 758.9 6.349 white band gap 4.18 eV [32]
RbBi(SeO3)F2 1:2 459.41 orthorhombic Pnma a=13.251 b=6.073 c=6.780 Z=4 545.6 [33]
Bi4TiO2F4(SeO3)4 4:4 1499.66 monoclinic P21/c a=7.0237 b=6.6824 c=17.3240 β=106.637 Z=2 779.07 6.393 colourless [34]
Bi4NbO3F3(SeO3)4 4:3 1541.67 monoclinic P21/c a=7.0448 b=6.6814 c=17.4051 β=106.931 Z=2 783.73 6.533 colourless [34]
Bi4TeO4F2(TeO3)2(SeO3)2 2:2 1670.64 monoclinic P21/c a=7.0304 b=6.6782 c=17.355 β=106.155 Z=2 782.66 7.089 colourless [34]
Bi2F2(MoO4)(SeO3) 1:2 742.86 monoclinic P21/c a=7.1005 b=9.660 c=12.972 β=12.091 Z=4 753.82 6.546 colourless [34]
Bi2ZrO2F2(SeO3)2 2:2 833.10 triclinic P1 a=5.8047 b=6.3469 c=6.7419 α=77.665 β=71.365 γ=72.795 Z=1 222.87 6.207 colourless [34]
PbBi(SeO3)2F 2:1 orthorhombic Pca21 a=12.9672 b=4.5022 c=11.8221 SHG 10.5×KDP; band gap 3.75 eV [35]

SHG=second harmonic generator

References

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