四氟化铅

四氟化铅

IUPAC名 Tetrafluoroplumbane
别名	氟化铅(IV)
识别
CAS号	7783-59-7 ^Y
PubChem	123258
ChemSpider	109871
SMILES	F[Pb](F)(F)F
EINECS	232-012-9
性质
化学式	PbF₄
摩尔质量	283.194 ^[1] g·mol⁻¹
外观	白色至米色晶体^[2]
密度	6.7 g/cm³^[2]
熔点	600 °C（873 K）（^[2]）
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

四氟化铅是一种由铅和氟形成的化合物。这种黄色固体(熔点 600 °C) 是仅有在室温下稳定的四卤化铅。^[3] 四氟化铅的结构类似四氟化锡，并且包含八面体配位的铅的平面层。其中八面体共享四个角，并且有两个彼此不共享的末端氟原子。^[4]

制备

四氟化铅可以由二氟化铅或金属铅和氟气反应而成。^[5]

{\ce {PbF2 + F2 -> PbF4}}

{\ce {Pb + 2F2 -> PbF4}}

参考资料

^ 存档副本. [2020-06-19]. （原始内容存档于2017-02-22）.
^ ^2.0 ^2.1 ^2.2 Lead Tetrafluoride | 7783-59-7. [2020-06-19]. （原始内容存档于2020-06-21）.
^ Greenwood, Norman Neill; Earnshaw, Alan. Chemistry of the elements. 2016: 375–376, 381–382. ISBN 978-0-7506-3365-9. OCLC 1040112384 （英语）.
^ Inorganic Chemistry [Paperback],2d Edition, Housecroft, Sharpe,2004, Pearson Education ISBN 0130399132, ISBN 978-0130399137
^ Handbuch der präparativen anorganischen Chemie. Stuttgart: Enke. 1975. ISBN 3-432-02328-6. OCLC 310719485 （德语）.

铅化合物

PbH₄

Pb(BF₄)₂

PbCO₃

Pb(N₃)₂
Pb(NO₃)₂

PbO
Pb₃O₄
PbO₂
Pb(OH)₂

PbF₂
PbF₄

PbSiF₆

PbP₇
Pb₃(PO₄)₂
Pb₂P₂O₇

PbS
PbS₂
PbSO₃
PbSO₄
Pb(SCN)₂

PbCl₂
PbCl₄
Pb(ClO₃)₂
Pb(ClO₄)₂

KPbI₃

PbTiO₃

PbCrO₄

PbGeO₃

PbHAsO₄
Pb₃(AsO₄)₂

PbSe
PbSeO₄

PbBr₂

PbMoO₄

Pb₂Sb₂O₇（俄语：Пироантимонат свинца(II)）

PbTe

PbI₂

镧系

PbTa₂O₆

PbWO₄

PbPo

锕系

↓

镧系

锕系

铅的有机化合物及有机酸盐

Me₄Pb · Et₄Pb · Pb(CH₃COO)₂ · Pb(CH₃COO)₄ · PbC₂O₄ · Pb(C₆H₈O₇)₂ · Pb(C₈H₅N₄O₈)₂ · C₁₆H₃₀O₄Pb · C₃₆H₇₀O₄Pb

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