六氟化钼

六氟化钼
别名 氟化钼(VI)
识别
CAS号 7783-77-9  checkY
PubChem 82219
SMILES
 
  • F[Mo](F)(F)(F)(F)F
InChI
 
  • 1S/6FH.Mo/h6*1H;/q;;;;;;+6/p-6
EINECS 232-026-5
性质
化学式 MoF6
摩尔质量 209.93 g/mol g·mol⁻¹
外观 white crystals[1] or colorless liquid
hygroscopic
密度 3.50 g/cm3[2]
熔点 17.5 °C(291 K)
沸点 34.0 °C(307 K)
溶解性 hydrolyzes
磁化率 −26.0·10−6 cm3/mol
结构
晶体结构 Orthorhombic, oP28
空间群 Pnma, No. 62
配位几何 octahedral (Oh)
偶极矩 0
相关物质
其他阳离子 六氟化钨
六氟化铀
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

六氟化钼又称氟化钼(VI),是一种无机化合物,化学式 MoF6。 它是元素的最高价氟化物。它是一种无色固体,在室温以下融化。[3]它是已知十七种六氟化物之一。

它可以由单质化合生成:[2]

Mo+3 F2=MoF6

参考资料

  1. ^ CRC Handbook of Chemistry and Physics, 90th Edition, CRC Press, Boca Raton, Florida, 2009, ISBN 978-1-4200-9084-0, Section 4, Physical Constants of Inorganic Compounds, p. 4-85.
  2. ^ 2.0 2.1 T. Drews, J. Supeł, A. Hagenbach, K. Seppelt: "Solid State Molecular Structures of Transition Metal Hexafluorides", in: Inorganic Chemistry, 2006, 45 (9), S. 3782–3788; doi:10.1021/ic052029f; PMID 16634614
  3. ^ Greenwood, N. N.; Earnshaw, A. Chemistry of the Elements 2nd. Oxford:Butterworth-Heinemann. 1997. ISBN 0-7506-3365-4. 

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