Values are given in terms of temperature necessary to reach the specified pressure.
Valid results within the quoted ranges from most equations are included in the table for comparison.
A conversion factor is included into the original first coefficients of the equations to provide the pressure in pascals (CR2: 5.006, SMI: -0.875).
Ref. SMI uses temperature scale ITS-48. No conversion was done, which should be of little consequence however.
The temperature at standard pressure should be equal to the normal boiling point, but due to the considerable spread does not necessarily have to match values reported elsewhere.
log refers to log base 10
(T/K) refers to temperature in Kelvin (K)
(P/Pa) refers to pressure in Pascal (Pa)
References
CRC.a-m
David R. Lide (ed), CRC Handbook of Chemistry and Physics, 84th Edition. CRC Press. Boca Raton, Florida, 2003; Section 6, Fluid Properties; Vapor Pressure
Uncertainties of several degrees should generally be assumed. (e) Indicates extrapolated values beyond the region of experimental data, subject to greater uncertainty. (i) Indicates values calculated from ideal gas thermodynamic functions. (s) Indicates the substance is solid at this temperature. As quoted from these sources:
a - Lide, D.R., and Kehiaian, H.V., CRC Handbook of Thermophysical and Thermochemical Data, CRC Press, Boca Raton, Florida, 1994.
b - Stull, D., in American Institute of Physics Handbook, Third Edition, Gray, D.E., Ed., McGraw Hill, New York, 1972.
c - Hultgren, R., Desai, P.D., Hawkins, D.T., Gleiser, M., Kelley, K.K., and Wagman, D.D., Selected Values of Thermodynamic Properties of the Elements, American Society for Metals, Metals Park, OH, 1973.
d - TRCVP, Vapor Pressure Database, Version 2.2P, Thermodynamic Research Center, Texas A&M University, College Station, TX.
e - Barin, I., Thermochemical Data of Pure Substances, VCH Publishers, New York, 1993.
f - Ohse, R.W. Handbook of Thermodynamic and Transport Properties of Alkali Metals, Blackwell Scientific Publications, Oxford, 1994.
g - Gschneidner, K.A., in CRC Handbook of Chemistry and Physics, 77th Edition, p. 4-112, CRC Press, Boca Raton, Florida, 1996.
h - Leider, H.R; Krikorian, O.H; Young, D.A (1973). "Thermodynamic properties of carbon up to the critical point". Carbon. 11 (5). Elsevier BV: 555–563. doi:10.1016/0008-6223(73)90316-3. ISSN0008-6223..
i - Wagner, W., and de Reuck, K.M., International Thermodynamic Tables of the Fluid State, No. 9. Oxygen, Blackwell Scientific Publications, Oxford, 1987.
j - Marsh, K.N., Editor, Recommended Reference Materials for the Realization of Physicochemical Properties, Blackwell Scientific Publications, Oxford, 1987.
k - Alcock, C. B.; Itkin, V. P.; Horrigan, M. K. (1984). "Vapour Pressure Equations for the Metallic Elements: 298–2500K". Canadian Metallurgical Quarterly. 23 (3). Informa UK Limited: 309–313. Bibcode:1984CaMQ...23..309A. doi:10.1179/cmq.1984.23.3.309. ISSN0008-4433.
l - Stewart, Richard B.; Jacobsen, Richard T. (1989). "Thermodynamic Properties of Argon from the Triple Point to 1200 K with Pressures to 1000 MPa". Journal of Physical and Chemical Reference Data. 18 (2). AIP Publishing: 639–798. Bibcode:1989JPCRD..18..639S. doi:10.1063/1.555829. ISSN0047-2689.
m - S̆ifner, O.; Klomfar, J. (1994). "Thermodynamic Properties of Xenon from the Triple Point to 800 K with Pressures up to 350 MPa". Journal of Physical and Chemical Reference Data. 23 (1). AIP Publishing: 63–152. Bibcode:1994JPCRD..23...63S. doi:10.1063/1.555956. ISSN0047-2689.
CR2
David R. Lide (ed), CRC Handbook of Chemistry and Physics, 84th Edition, online version. CRC Press. Boca Raton, Florida, 2003; Section 4, Properties of the Elements and Inorganic Compounds; Vapor Pressure of the Metallic Elements
The equations reproduce the observed pressures to an accuracy of ±5% or better. Coefficients from this source:
f - Marshall, A.L.; Dornte, R.W.; Norton, F.J. (1937). "The Vapor Pressure of Copper and Iron". Journal of the American Chemical Society. 59 (7): 1161-1166. doi:10.1021/ja01286a001.
g - Schuman, Robert; Garrett, A. B. (1944). "The Vapor Pressure of Beryllium at 1170-1340K". Journal of the American Chemical Society. 66 (3). American Chemical Society (ACS): 442–444. doi:10.1021/ja01231a040. ISSN0002-7863.;Schuman, Robert; Garrett, A (1945). "Correction. The Vapor Pressure of Beryllium at 1170-1340K". Journal of the American Chemical Society. 67 (12). American Chemical Society (ACS): 2279. doi:10.1021/ja01228a605. ISSN0002-7863.
i - van Liempt, J. A. M. (1936). "Die Dampfdrücke des Bariums". Recueil des Travaux Chimiques des Pays-Bas. 55 (6). Wiley: 468–470. doi:10.1002/recl.19360550604. ISSN0165-0513..
k - Int. National Critical Tables, vol. 3, p. 306, (1928).
l - Baur, Emil; Brunner, Roland (1934). "Dampfdruckmessungen an hochsiedenden Metallen". Helvetica Chimica Acta (in German). 17 (1). Wiley: 958–969. doi:10.1002/hlca.193401701120. ISSN0018-019X.
m - Anderson, J. S. (1943). "43. The vapour pressure of metallic indium". Journal of the Chemical Society (Resumed). Royal Society of Chemistry (RSC): 141. doi:10.1039/jr9430000141. ISSN0368-1769.
n - Reimann, A.L.; Grant, C. Kerr (1936). "III.Some high-temperature properties of niobium". The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science. 22 (145). Informa UK Limited: 34–48. doi:10.1080/14786443608561665. ISSN1941-5982.
q - Johnston, H. L.; Marshall, A. L. (1940). "Vapor Pressures of Nickel and of Nickel Oxide". Journal of the American Chemical Society. 62 (6). American Chemical Society (ACS): 1382–1390. doi:10.1021/ja01863a015. ISSN0002-7863.
r - Jones, Howard A.; r, Irving Langmu; Mackay, G. M. J. (1927-08-01). "The Rates of Evaporation and the Vapor Pressures of Tungsten, Molybdenum, Platinum, Nickel, Iron, Copper and Silver". Physical Review. 30 (2). American Physical Society (APS): 201–214. Bibcode:1927PhRv...30..201J. doi:10.1103/physrev.30.201. ISSN0031-899X.
s - H.A. Jones, I. Langmuir, Gen. Electric Rev., vol. 30, p. 354, (1927).
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