磷化锂

磷化锂
识别
CAS号 12057-29-3  checkY
SMILES
 
  • [Li+].[Li+].[Li+].[P-3]
性质
化学式 Li3P
摩尔质量 51.8 g·mol−1
外观 棕色晶体[1]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

磷化锂是一种无机化合物，化学式为Li3P，它是锂的磷化物之一。它是六方晶系晶体，空间群P63/mmc，晶胞参数a=4.2286 Å，c=7.5566 Å，V=117.02 Å3。[2]它可由锂和红磷在钽质容器中反应得到，或通过一磷化锂和锂反应制得：[1]

3 Li + P → Li3P
LiP + 2 Li → Li3P

它可以和水反应，放出磷化氢：[1]

Li3P + 3 H2O → 3 LiOH + PH3

参考文献

  1. ^ 1.0 1.1 1.2 G Nazri. Preparation, structure and ionic conductivity of lithium phosphide. Solid State Ionics. 1989-04, 34 (1-2): 97–102 [2021-12-10]. doi:10.1016/0167-2738(89)90438-4. （原始内容存档于2018-06-30） （英语）. 
  2. ^ Yongkwan Dong, Francis J. DiSalvo. Reinvestigation of trilithium phosphide, Li 3 P. Acta Crystallographica Section E Structure Reports Online. 2007-04-15, 63 (4): i97–i98 [2021-12-10]. ISSN 1600-5368. doi:10.1107/S1600536807008422. （原始内容存档于2021-12-09）. 

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