一磷化钛

一磷化钛
别名 磷化钛(III)
识别
CAS号 12037-65-9  checkY
PubChem 82856
SMILES
 
  • P#[Ti]
InChI
 
  • 1S/P.Ti
EINECS 234-862-6
性质
化学式 TiP
摩尔质量 78.841 g·mol⁻¹
外观 灰色晶体
密度 4.08 g/cm³(固)[1]
熔点 >1400°C [1]
结构
晶体结构 六方晶系
危险性
欧盟分类 未列出
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

一磷化钛(化学式:TiP)是一种无机化合物,通常为灰色粉末。[1]它是有着高熔点的金属导体。[2]它对水或通常的稳定。[1]它的性质和碱金属碱土金属含P3−的磷化物(如Na3P)相比是不同的,那些磷化物不具备金属性,且会理科水解。[2]一磷化钛被分类为“富金属磷化物”,有着多余的来自金属的离域价电子[2]

TiP可以通过TiCl4PH3的反应制备。[1]

钛的其它磷化物,如Ti3P、[3]Ti2P、[4]Ti7P4[5]Ti5P3[6]和Ti4P3[7]等,是已知的。

参考文献

  1. ^ 1.0 1.1 1.2 1.3 1.4 D.L. Perry S.L. Phillips (1995) Handbook of inorganic compounds CRC Press ISBN 0-8493-8671-3
  2. ^ 2.0 2.1 2.2 H.G. Von Schnering, W. Hönle Phosphides - Solid state chemistry Encyclopedia of Inorganic Chemistry Ed. R. Bruce King (1994) John Wiley & Sons ISBN 0-471-93620-0
  3. ^ Hydrogen absorption in Ti3P Halter U., Mrowietz M., Weiss A Journal of the less-common metals 1986 118 343-348
  4. ^ Structure of Ti2P solved by three-dimensional electron diffraction data collected with the precession technique and high-resolution electron microscopy M. Gemmi, X. D. Zou, S. Hovmöller, A. Migliori, M. Vennström and Y. Andersson Acta Crystallogr. (2003). A59, 117-126 doi:10.1107/S0108767302022559 PMID 12604849
  5. ^ New Phases in the Ti-P and Ti-Cu-P Systems, Carrillo C W., Lundström T Acta Chem.Scand., Series A: (1979), 33, 401-402
  6. ^ Crystal Structure Refinement of Ti5P3 Carrillo C W., Lundström T Acta Chemica Scandinavica, Series A: Physical and Inorganic Chemistry 1980 34 415-419
  7. ^ Phase Relationships in the Ti-P System with some Notes on the Crystal Structures of TiP2 and ZrP2, Snell P.O, Acta Chem. Scand. 1968 22 1942-1952

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