乙酸铥

乙酸铥
英文名 Thulium(III) acetate
别名 醋酸铥
识别
CAS号 39156-80-4  checkY
性质
化学式 Tm(CH3COO)3
外观 晶体
溶解性（水） 可溶
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

乙酸铥是铥的乙酸盐，化学式为Tm(CH3COO)3，它以无水物和四水合物[1]的形式存在。

性质

乙酸铥和乙酰丙酮铁在丁二醇中于300 °C反应，可以得到六方晶系的TmFeO3。[2]

和三氟乙酸反应，生成三氟乙酸盐：[3]

Tm(CH3COO)3 + 3 CF3COOH → Tm(CF3COO)3 + 3 CH3COOH

参考文献

  1. ^ K. I. Petrov, M. G. Zaitseva, L. M. Sukova. Spectroscopic study of thulium acetate tetrahydrate single crystals. Journal of Applied Spectroscopy. 1971-08-01, 15 (2): 1058–1060 [2019-02-01]. ISSN 1573-8647. doi:10.1007/BF00607309 （英语）. 
  2. ^ Masashi Inoue, Toshihiro Nishikawa, Tomohiro Nakamura, Tomoyuki Inui. Glycothermal Reaction of Rare-Earth Acetate and Iron Acetylacetonate: Formation of Hexagonal ReFeO3. Journal of the American Ceramic Society. 1997, 80 (8): 2157–2160 [2019-02-01]. ISSN 1551-2916. doi:10.1111/j.1151-2916.1997.tb03103.x （英语）. 
  3. ^ S. I. Gutnikov, E. V. Karpova, M. A. Zakharov, A. I. Boltalin. Thulium(III) trifluoroacetates Tm(CF3COO)3 · 3H2O and Tm2(CF3COO)6 · 2CF3COOH · 3H2O: Synthesis and crystal structure. Russian Journal of Inorganic Chemistry. 2006-04-01, 51 (4): 541–548 [2019-02-01]. ISSN 1531-8613. doi:10.1134/S0036023606040061 （英语）. 

拓展阅读

  • Mondry, A., & Bukietyńska, K. (2003). The power and limits of the Judd—Ofelt theory: a case of Pr3+ and Tm3+ acetates and dipicolinates. Molecular Physics, 101(7), 923-934.

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