七乙酸氧化三铱

七乙酸氧化三铱
识别
CAS号 2378782-75-1（无水）  checkY
52705-52-9（三水）  checkY
性质
化学式 C14H21Ir3O15
摩尔质量 1005.96 g·mol−1
外观 绿色[1]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

七乙酸氧化三铱是一种化合物，化学式为[Ir3O(OAc)6](OAc)，其中OAc−为乙酸根，Ir为+3价[2]。它的三水合物可由氯化铱或氯铱(III)酸和乙酸银在乙酸中反应得到。[1]它在乙酸中可以被氧化为[Ir3O(OAc)6(H2O)2(HOAc)](OAc)2。[1]

参考文献

  1. ^ 1.0 1.1 1.2 Sakae Uemura, Alwyn Spencer, Geoffrey Wilkinson. µ 3 -Oxotrimetal acetato-complexes of chromium, manganese, iron, cobalt, rhodium, and iridium. J. Chem. Soc., Dalton Trans. 1973, (23): 2565–2571 [2023-02-24]. ISSN 0300-9246. doi:10.1039/DT9730002565 （英语）. 
  2. ^ Simanova, S. A.; Belyaev, A. N.; Bashmakov, V. I.; Troshina, O. N.; Ezerskaya, N. A.; Kiseleva, I. N.; Danilova, F. I.; Munina, V. M. Redox conversions of iridium μ3-oxoacetates in glacial acetic acid. Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation). 1993, 66 (1): 144–149. ISSN 0044-4618. 

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