硫化铥

硫化铥
别名 三硫化二铥
硫化铥(III)
识别
CAS号 12166-30-2  checkY
性质
化学式 S3Tm2
摩尔质量 434.06 g·mol−1
外观 黄色晶体
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

硫化铥是一种无机化合物，化学式为Tm2S3。它可由铥和硫在氯化钠熔体中于850 °C反应得到，[1]或氧化铥和硫化氢在1200~1300 °C的反应来制备。[2]

它和三氟化铥在高温反应，可以得到TmSF。[3]它和硫氧化铀（UOS）在高温反应，可以得到(UO)2TmS3。[4]

参考文献

  1. ^ Thomas Schleid, Falk Lissner. Single crystals of F-Tm2S3 and T-Yb2S3. Journal of Alloys and Compounds. 1992-11, 189 (1): 69–74 [2023-04-05]. doi:10.1016/0925-8388(92)90048-E. （原始内容存档于2018-06-21） （英语）. 
  2. ^ Collin, G.; Loriers, J. Oxysulfides and sesquisulfides of terbium, holmium, thulium, and lutetium. Compt. Rend.. 1965. 260 (19). 5043-5046.
  3. ^ Zinchenko, V. F.; Efryushina, N. P.; Antonovich, V. P.; Eremin, O. G.; Stamikosto, O. V.; Kovalevskaya, I. P. Synthesis and optical properties of rare earth sulfofluorides. Ukrainskii Khimicheskii Zhurnal (Russian Edition), 2000. 66 (3-4): 16-19.
  4. ^ Guittard, M.; Vovan, T.; Julien-Pouzol, M.; Jaulmes, S.; Laruelle, P.; Flahaut, J. Description and structural study of a new family of sheet compounds of the general composition (UO)2RS3 (R = Gd to Lu and Y). Zeitschrift fuer Anorganische und Allgemeine Chemie, 1986. 540-541: 59-66.

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