一硅化三铬

一硅化三铬
识别
CAS号 12018-36-9  checkY
PubChem 6336547
ChemSpider 4891693
SMILES
 
  • [Si].[Cr].[Cr].[Cr]
EINECS 234-639-3
性质
化学式 Cr3Si
摩尔质量 184.07 g·mol−1
氣味
密度 6.4 g/cm3[1]
熔点 1770 °C[1]
溶解性 难溶
结构
晶体结构 Cubic, cP8[2]
空间群 Pm3n, No. 223
晶格常数 a = 0.4556 nm
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

一硅化三铬是一种无机化合物,化学式Cr3Si,它是硅化物之一。它可以在粉和四氯化硅高温的反应中生成,但该反应会同时生成铬的其它硅化物。[3]Cr5Si3和硅反应,可以得到Cr3Si。[4]

它是一些化合物的晶体结构原型,属于Cr3Si结构的化合物有Nb3Al、Ti3Sb、Ti3Au等。[5]

参考文献

  1. ^ 1.0 1.1 Haynes, William M. (编). CRC Handbook of Chemistry and Physics 97th. CRC Press. 2016: 4.57. ISBN 9781498754293. 
  2. ^ Jauch, W.; Schultz, A. J.; Heger, G. Single-crystal time-of-flight neutron diffraction of Cr3Si and MnF2 comparison with monochromatic-beam techniques. Journal of Applied Crystallography. 1987, 20 (2): 117–119. doi:10.1107/S002188988708703X. 
  3. ^ Tsuneo Sasahara, Mayumi Someno, Kyuya Nagasaki. Reaction of Chromium with Silicon Tetrachloride. Journal of the Japan Institute of Metals. 1960, 24 (2): 78–82 [2022-11-02]. ISSN 0021-4876. doi:10.2320/jinstmet1952.24.2_78. (原始内容存档于2022-11-02) (英语). 
  4. ^ E. G. Colgan, B. Y. Tsaur, J. W. Mayer. Phase formation in Cr‐Si thin‐film interactions. Applied Physics Letters. 1980-11-15, 37 (10): 938–940 [2022-11-02]. ISSN 0003-6951. doi:10.1063/1.91767. (原始内容存档于2022-11-02) (英语). 
  5. ^ Cr3Si (A15) Structure: A3B_cP8_223_c_a. Encyclopedia of Crystallographic Prototypes. [2022-11-02]. (原始内容存档于2022-11-02). 

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