三溴化氮

三溴化氮
Nitrogen tribromide molecule
IUPAC名
nitrogen tribromide
识别
CAS号 15162-90-0
PubChem 3082084
ChemSpider 20480821
SMILES
 
  • N(Br)(Br)Br
InChI
 
  • InChI=1S/3BrH.N/h3*1H;/p-3
性质
化学式 Br3N
摩尔质量 253.72 g·mol−1
熔点 −100 °C时爆炸[1]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

三溴化氮是一种无机化合物，化学式为NBr3。它可由溴或次溴酸盐和氨在稀的缓冲水溶液中反应生成，[2]或者溴和叠氮化溴反应得到。[3]氨和溴进行辉光放电，经处理后可以得到红色的NBr3·6NH3。[4]纯的三溴化氮在1975年才被制得。[5]

参考文献

  1. ^ Lide, David R., Handbook of Chemistry and Physics 87, Boca Raton, Florida: CRC Press: 4–73, 1998, ISBN 0-8493-0594-2 
  2. ^ Hend Galal-Gorchev, J. Carrell Morris. Formation and Stability of Bromamide, Bromimide, and Nitrogen Tribromide in Aqueous Solution. Inorganic Chemistry. 1965-06, 4 (6): 899–905 [2019-06-02]. ISSN 0020-1669. doi:10.1021/ic50028a029. （原始内容存档于2020-11-07） （英语）. 
  3. ^ Thomas M. Klapötke. The reaction of bromine azide with bromine. Polyhedron. 1997-01, 16 (15): 2701–2704 [2019-06-02]. doi:10.1016/S0277-5387(96)00586-4. （原始内容存档于2018-06-23） （英语）. 
  4. ^ Martin Schmeisser. Nitrogen bromide. Zeitschrift fuer Anorganische und Allgemeine Chemie, 1941. 246: 284-302. ISSN: 0044-2313
  5. ^ Jander, Jochen; Knackmuss, Juergen; Thiedemann, Klaus U. Preparation and isolation of nitrogen tribromide and nitrogen dibromide monoiodide（德文）. Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1975. 30B (5-6): 464-465. ISSN: 0340-5087

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