Lithium hypofluorite

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Lithium hypofluorite
Names
Preferred IUPAC name Lithium hypofluorite
Other names Lithium fluoride oxide, lithium oxyfluoride
Identifiers
CAS Number	34240-84-1
3D model (JSmol)	Interactive image
PubChem CID	23678220
CompTox Dashboard (EPA)	DTXSID90187814
InChI InChI=1S/FO.Li/c1-2;/q-1;+1 Key: WYWLSUBVZXKJGO-UHFFFAOYSA-N
SMILES [Li+].[O-]F
Properties
Chemical formula	LiOF
Molar mass	41.94 g·mol⁻¹
Related compounds
Related compounds	Lithium fluoride Lithium hypochlorite
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Lithium hypofluorite is an inorganic compound with the chemical formula of Li O F. It is a compound of lithium, fluorine, and oxygen.^[1]^[2]^[3] This is a lithium salt of hypofluorous acid,^[4] and contains lithium cations Li⁺ and hypofluorite anions ⁻OF.

Synthesis

The salt theoretically results from the neutralization of hypofluorous acid (HOF) and lithium hydroxide (LiOH). It can be formed by the action of fluorine on lithium hydroxide:

6 F₂ + 6 LiOH → 2 LiF + O₂ + 4 LiOF + 6 HF

Chemical properties

The compound is quite unstable, since it contains oxygen in the oxidation state of 0. It, therefore, tends to decompose to lithium fluoride and oxygen gas:

2 LiOF → 2 LiF + O₂

References

^ Science Data Booklet. Manjunath.R. 11 July 2020. p. 146. Retrieved 12 May 2023.
^ Barin, Ihsan (1995). Thermochemical Data of Pure Substances: La-Zr. VCH. p. 965. ISBN 978-3-527-28745-1. Retrieved 12 May 2023.
^ Binnewies, M.; Milke, E. (3 December 2002). Thermochemical Data of Elements and Compounds. Wiley. p. 466. ISBN 978-3-527-30524-7. Retrieved 12 May 2023.
^ "NIST-JANAF Themochemical Tables, Fourth Edition". NIST. 1998. pp. 1–1951. Retrieved 12 May 2023.

v t e Lithium compounds (list)
Inorganic (list)	Li₂ LiAlCl₄ Li_1+xAl_xGe_2−x(PO₄)₃ LiAlH₄ LiAlO₂ LiAl_1+xTi_2−x(PO₄)₃ LiAs LiAsF₆ Li₃AsO₄ LiAt Li[AuCl₄] LiB(C₂O₄)₂ LiB(C₆F₅)₄ LiWF₆ LiBF₄ LiBH₄ LiBO₂ LiB₃O₅ Li₂B₄O₇ LiAsF₆ Li₂SnF₆ Li₂TiF₆ Li₂ZrF₆ Li₂B₄O₇·5H₂O LiBSi₂ LiBr LiBr·2H₂O LiBrO LiBrO₂ LiBrO₃ LiBrO₄ Li₂C₂ LiCF₃SO₃ CH₃CH(OH)COOLi LiC₂H₂ClO₂ LiC₂H₃IO₂ Li(CH₃)₂N LiCHO₂ LiCH₃O LiC₂H₅O LiCN Li₂CN₂ LiCNO Li₂CO₃ Li₂C₂O₄ LiCl LiCl·H₂O LiClO LiFO LiClO₂ LiClO₃ LiClO₄ LiCoO₂ Li₂CrO₄ Li₂CrO₄·2H₂O Li₂Cr₂O₇ CsLiB₆O₁₀ LiD LiF Li₂F LiF₄Al Li₃F₆Al FLiBe LiFePO₄ FLiNaK LiGaH₄ Li₂GeF₆ Li₂GeO₃ LiGe₂(PO₄)₃ LiH LiH₂AsO₄ Li₂HAsO₄ LiHCO₃ Li₃H(CO₃)₂ LiH₂PO₃ LiH₂PO₄ LiHSO₃ LiHSO₄ LiHe LiI LiIO LiIO₂ LiIO₃ LiIO₄ Li₂IrO₃ Li₇La₃Zr₂O₁₂ LiMn₂O₄ Li₂MoO₄ Li_0.9Mo₆O₁₇ LiN₃ Li₃N LiNH₂ Li₂NH LiNO₂ LiNO₃ LiNO₃·H₂O Li₂N₂O₂ LiNa Li₂NaPO₃ LiNaNO₂ LiNbO₃ Li₂NbO₃ LiO⁻ LiO₂ LiO₃ Li₂O Li₂O₂ LiOH Li₃P LiPF₆ Li₃PO₄ Li₂HPO₃ Li₂HPO₄ Li₃PO₃ Li₃PO₄ Li₂Po Li₂PtO₃ Li₂RuO₃ Li₂S LiSCN LiSH LiSO₃F Li₂SO₃ Li₂SO₄ Li[SbF₆] Li₂Se Li₂SeO₃ Li₂SeO₄ LiSi Li₂SiF₆ Li₄SiO₄ Li₂SiO₃ Li₂Si₂O₅ LiTaO₃ Li₂Te LiTe₃ Li₂TeO₃ Li₂TeO₄ Li₂TiO₃ Li₄Ti₅O₁₂ LiTi₂(PO₄)₃ LiVO₃·2H₂O Li₃V₂(PO₄)₃ Li₂WO₄ LiYF₄ Neodymium-doped LiZr₂(PO₄)₃ Li₂ZrO₃
Organic (soaps)	Hemolithin (extraterrestrial protein) Organolithium reagents Gilman reagent CH₃COOLi C₄H₆LiNO₄ LiC₂F₆NO₄S₂ LiN(SiMe₃)₂ Li₃C₆H₅O₇ C₅H₅Li LiN(C₃H₇)₂ (C₆H₅)₂PLi C₁₈H₃₅LiO₃ C₆H₁₃Li C₄H₉Li CH₃CHLiCH₂CH₃ (CH₃)₃CLi C₁₂H₂₈BLi CH₃Li Li⁺C₁₀H−8 C₅H₁₁Li C₅H₃LiN₂O₄ C₆H₅Li LiC₂CH₃ LiO₂C(CH₂)₁₆CH₃ C₄H₅LiO₄ LiEt₃BH LiOC(CH₃)₃ C₉H₁₈LiN LiC₂H₃ Vinyllithium LiC ₁₁H ₂₃COO
Minerals	Amblygonite Berezanskite Brannockite Cryolithionite Darapiosite Darrellhenryite Elbaite Fluorine Elbaite Fluor-liddicoatite Emeleusite Eucryptite LiAlSiO₄ Faizievite Hectorite Hsianghualite Jadarite LiNaSiB₃O₇OH Keatite Li(AlSi₂O₆) Kunzite Lavinskyite Lepidolite Lithiophilite LiMnPO₄ Lithiophosphate Li₃PO₄ Manandonite Manganoneptunite Nambulite Neptunite Olympite Petalite LiAlSi₄O₁₀ Pezzottaite Cs(Be₂Li)Al₂Si₆O₁₈ Rossmanite Saliotite Sogdianite Spodumene LiAl(SiO₃)₂ Sugilite Tiptopite Tourmaline Triphylite LiFePO₄ Zabuyelite Li₂CO₃ Zektzerite Zinnwaldite
Hypothetical	Li_xBe_y HLiHe⁺ LiFHeO LiHe₂ (HeO)(LiF)₂ La_2⁄3–xLi_3xTiO₃He
Other Li-related	Aluminium–lithium alloys Heteroatom-promoted lateral lithiation LB buffer Lithium atom Lithium medication LiNi_xCo_yAl_zO₂ LiNi_xMn_yCo_zO₂ Lithium soap Lithium Triangle Lucifer yellow Magnesium–lithium alloys NASICON Environmentally friendly red light flare

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