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This is a list of gases at standard conditions, which means substances that boil or sublime at or below 25 °C (77 °F) and 1 atm pressure and are reasonably stable.

List

This list is sorted by boiling point of gases in ascending order, but can be sorted on different values. "sub" and "triple" refer to the sublimation point and the triple point, which are given in the case of a substance that sublimes at 1 atm; "dec" refers to decomposition. "~" means approximately.

Name	Formula	Boiling pt (°C)	Melting pt (°C)	Molecular weight	CAS No
Helium-3	³He	−269.96	N/A	3	14762-55-1
Helium-4	⁴He	−268.928	N/A	4	7440-59-7
Hydrogen	H₂	−252.879	−259.16	2	1333-74-0
Deuterium^[1]	D₂	−249.49	−254.43	4	7782-39-0
Tritium^[2]	T₂	−248.12	−254.54	6	10028-17-8
Neon	Ne	−246.046	−248.59	20	7440-01-9
Nitrogen	N₂	−195.795	−210.0	28	7727-37-9
Carbon monoxide	CO	−191.5	−205.02	28	630-08-0
Fluorine	F₂	−188.11	−219.67	38	7782-41-4
Argon	Ar	−185.848	−189.34	40	7440-37-1
Oxygen	O₂	−182.962	−218.79	32	7782-44-7
Methane	CH₄	−161.5	−182.50	16	74-82-8
Krypton	Kr	−153.415	−157.37	84	7439-90-9
Nitric oxide	NO	−151.74	−163.6	30	10102-43-9
Oxygen difluoride	F₂O	−144.3	−223.8	54	7783-41-7
Tetrafluoromethane	CF₄	−127.8	−183.6	88	75-73-0
Nitrogen trifluoride	NF₃	−128.74	−206.79	71	7783-54-2
Silane	SiH₄	−111.9	−185	32	7803-62-5
trans-Dinitrogen difluoride	N₂F₂	−111.45	−172	66	13776-62-0
Ozone	O₃	−111.35	−193	48	10028-15-6
Xenon	Xe	−108.099	−111.75	131	7440-63-3
cis-Dinitrogen difluoride	N₂F₂	−105.75	−195	66	13812-43-6
Ethylene	CH₂=CH₂	−103.7	−169.2	28	74-85-1
Phosphorus trifluoride	PF₃	−101.8	−151.5	88	7783-55-3
Chlorine monofluoride	ClF	−101.1	−155.6	54.5	7790-89-8
Boron trifluoride	BF₃	−99.9	−126.8	68	7637-07-2
Fluorosilane	SiH₃F	−98.6		50	13537-33-2
Trifluorosilane	SiHF₃	−95	−131	86	13465-71-9
Trifluoromethyl hypofluorite^[3]	CF₃OF	−95	−215	104	373-91-1
Diborane	B₂H₆	−92.49	−164.85	28	19287-45-7
3,3-Difluorodiazirine^[4]	CF₂N₂	−91.3		78	693-85-6
Ethane	CH₃CH₃	−88.5	−182.8	30	74-84-0
Nitrous oxide	N₂O	−88.48	−90.8	44	10024-97-2
Germane	GeH₄	−88.1	−165	77	7782-65-2
Phosphine	PH₃	−87.75	−133.8	34	7803-51-2
Trifluoramine oxide	NOF₃	−87.5	−161	87	13847-65-9
Tetrafluorosilane	SiF₄	−86	−90.2	104	7783-61-1
1,1-Difluoroethene	CF₂=CH₂	−85.5	−144	64	75-38-7
Trifluoronitrosomethane	CF₃NO	−85	−196.6	99	334-99-6
Azidotrifluoromethane	CF₃N₃	−85	−152	111	3802-95-7
Hydrogen chloride	HCl	−85	−114.17	36.5	7647-01-0
Difluorodioxirane^[5]	F₂COO	≈−85	≤−160	82	96740-99-7
Acetylene	CH≡CH	−84.7	−81.5	26	74-86-2
Phosphorus pentafluoride	PF₅	−84.6	−93.8	126	7647-19-0
Carbonyl fluoride	COF₂	−84.5	−111.2	66	353-50-4
Trifluoromethane	CHF₃	−82.1	−155.2	70	75-46-7
Chlorotrifluoromethane	CClF₃	−81.5	−181	104.5	75-72-9
Bis(difluoroboryl)methane^[3]	BF₂CF₂BF₂	−81.4 ?		148	55124-14-6
Trifluoroisocyanomethane	CF₃NC	−80		95	105879-13-8
Difluoromethylborane	CH₃BF₂	−78.5		64	373-64-8
Carbon dioxide	CO₂	−78.464 sub	−56.561 triple	44	124-38-9
Fluoromethane	CH₃F	−78.4	−137.8	34	593-53-3
Hexafluoroethane	CF₃CF₃	−78.1	−100.015	138	76-16-4
Pentafluoromethanamine	CF₃NF₂	−78	−130	121	335-01-3
Difluorosilane	SiH₂F₂	−77.8	−122	68	13824-36-7
Tetrafluoroethene	CF₂=CF₂	−76	−131.14	100	116-14-3
Fluoroacetylene	FCCH	−74	−196	44	2713-09-9
Tetrafluorohydrazine	N₂F₄	−74	−164.5	104	10036-47-2
Nitryl fluoride	NO₂F	−72.4	−166	65	10022-50-1
Fluoroethene	CH₂CHF	−72	−160.5	46	75-02-5
Chlorotrifluorosilane	SiClF₃	−70	−138	120.5	14049-36-6
Trifluoroacetonitrile	CF₃CN	−68.8		95	353-85-5
Chlorodifluoroamine	NClF₂	−67	−195	87.5	13637-87-1
Hydrogen bromide	HBr	−66.38	−86.80	81	10035-10-6
Difluorophosphine^[6]	PHF₂	−65	−124	70	14984-74-8
Borane carbonyl	BH₃CO	−64	−137	42	13205-44-2
Fluoroperoxytrifluoromethane^[7]	CF₃OOF	−64		120
Bis(fluoroxy)difluoromethane^[8]	CF₂(OF)₂	−64		120	16282-67-0
Sulfur hexafluoride	SF₆	−63.8	−49.596 triple	146	2551-62-4
Tetrafluorooxirane^[9]	C₂F₄O	−63.5		116	694-17-7
Arsine	AsH₃	−62.5	−166	78	7784-42-1
Thiocarbonyl fluoride^[10]	CSF₂	−62.1	−163.5	82	420-32-6
Radon	Rn	−61.7	−71	222	10043-92-2
Difluorocyanamide^[3]^[11]	NF₂CN	−61	−196	78	7127-18-6
Nitrosyl fluoride	ONF	−59.9	−132.5	49	7789-25-5
Hydrogen sulfide	H₂S	−59.55	−85.5	34	7783-06-4
Trifluoroacetyl fluoride^[12]	CF₃COF	−59	−159.5	116	354-34-7
Hexafluorodimethyl ether^[13]	CF₃OCF₃	−59		154	333-36-8
Bromotrifluoromethane	CBrF₃	−57.75	−167.78	149	75-63-8
Difluoroaminooxyperfluoromethane^[3]^[14]	CF₃ONF₂	−57.63		137	4217-93-0
Methylsilane	CH₃SiH₃	−57.5	−156.5	46	992-94-9
Dioxygen difluoride	F₂O₂	−57 dec	−163.5	70	7783-44-0
Ethenone	CH₂=C=O	−56.1	−151	42	463-51-4
Sulfuryl fluoride	SO₂F₂	−55.4	−135.8	102	2699-79-8
Dichlorofluorosilane	SiHCl₂F	−54.3		119	19382-74-2
trans-1,2-Difluoroethene	CHF=CHF	−53.1		64	1630-78-0
Trifluoroethene	CF₂=CHF	−53		82	359-11-5
Arsenic pentafluoride	AsF₅	−52.8	−79.8	170	7784-36-3
Phosphorothioic trifluoride	PSF₃	−52.25	−148.8	120	2404-52-6
Difluoromethane	CH₂F₂	−52	−136	52	75-10-5
Difluorocarbamyl fluoride^[15]^[16]	F₂NCOF	−52	−152.2	99	2368-32-3
Stannane	SnH₄	−51.8	−146	123	2406-52-2
Tetrafluoropropyne^[17]	CF₃C≡CF	−50.39		112	20174-11-2
Carbonyl sulfide	OCS	−50.2	−138.8	60	463-58-1
Pentafluoroethyl hypofluorite^[18]	C₂F₅OF	−50		154
Chlorodifluorosilane^[19]	SiHClF₂	~−50		102.5	80003-43-6
Digallane	Ga₂H₆	~−50 dec		145.494	12140-58-8
Thionyl tetrafluoride	SOF₄	−48.5	−99.6	124	13709-54-1
3,3,3-Trifluoro-1-propyne	CF₃CCH	−48.3		94	661-54-1
Pentafluoroethane	CF₃CHF₂	−48.1	−100.6	120	354-33-6
Propene	C₃H₆	−47.6	−185.2	42	115-07-1
Chlorodifluorophosphine	PClF₂	−47.3	−164.8	104.5	14335-40-1
Carbonyl chloride fluoride	COClF	−47.2	−148	82.5	353-49-1
1,1,1-Trifluoroethane	CF₃CH₃	−47	−111.8	84	420-46-2
Trifluoromethyl hypochlorite^[3]	CF₃OCl	−47	−164	120.5	22082-78-6
Perchloryl fluoride	ClO₃F	−46.75	−147	102.5	7616-94-6
Selenium hexafluoride	SeF₆	−46.6 sub	−34.6 triple	193	7783-79-1
Cyanogen fluoride	FCN	−46	−82	45	1495-50-7
Fluorine nitrate	FNO₃	−46	−175	81	7789-26-6
Pentafluoronitrosoethane^[20]	C₂F₅NO	−45.7		137	354-72-3
Difluoromethylene dihypofluorite^[21]	CF₂(OF)₂	−45.8	−142	120	16282-67-0
cis-1,2-Difluoroethene	CHF=CHF	−45		64	1630-77-9
1,1-Difluoro-1-propene^[3]	CH₃CH=CF₂	−44		78	430-63-7
Dimethylfluoroborane^{[citation needed]}	(CH₃)₂BF	−44		60	353-46-8
Fluoro(trifluoromethyl)silane^[22]	CF₃SiH₂F	−44		118
Thionyl fluoride	SOF₂	−43.8	−110.5	86	7783-42-8
Phosphorus chloride tetrafluoride	PClF₄	−43.4	−132	142.5	13498-11-8
Methyldiborane	CH₃B₂H₅	−43		42	23777-55-1
Difluoro(trifluoromethyl)phosphine^[23]	CF₃PF₂	−43		138	1112-04-5
N,N,1,1-Tetrafluoromethylamine^[24]	CHF₂NF₂	−43		103	24708-53-0
Propane	C₃H₈	−42.25	−187.7	44	74-98-6
Trifluoro(trifluoromethyl)silane^[25]	CF₃SiF₃	−42		154	335-06-8
Bromotrifluorosilane	BrSiF₃	−41.7	−70.5	169	14049-39-9
Hydrogen selenide	H₂Se	−41.25	−65.73	81	7783-07-5
Chlorodifluoromethane	CHClF₂	−40.7	−175.42	86.5	75-45-6
Sulfur tetrafluoride	SF₄	−40.45	−125	108	7783-60-0
Hexafluorodiazomethane cis^[26]	CF₃NNCF₃	−40	−127	166	73513-59-4
Phosphoryl fluoride	POF₃	−39.7 sub	−39.1 triple	104	13478-20-1
Chloropentafluoroethane	CF₃CClF₂	−39.1	−99	135.5	76-15-3
Tetrafluoro(trifluoromethyl)phosphorane^[27]	CF₃PF₄	−39	−113	176	1184-81-2
tetrafluorophosphorane^[28]	PHF₄	−39.0	−100	108	13659-66-0
Tellurium hexafluoride	TeF₆	−38.9	−37.6 triple	242	7783-80-4
Vinyldifluoroborane^[29]	CH₂=CHBF₂	−38.8	−133.4	76	358-95-2
(Trifluoromethyl)silane	CF₃SiH₃	−38.3	−124	100	10112-11-5
Heptafluoroethanamine^[3]	C₂F₅NF₂	−38.1	−183	171	354-80-3
Tetrafluoroallene^[30]	CF₂=C=CF₂	−38		112	461-68-7
Hexafluorooxetane^[31]	C₃F₆O	−38		166	425-82-1
Trifluoromethanethiol^[32]	CF₃SH	−37.99	−157.11	102	1493-15-8
Fluoroethane	CH₃CH₂F	−37.7	−143.2	48	353-36-6
Bis(trifluoromethyl)peroxide	CF₃OOCF₃	−37		170	927-84-4
Pentafluoropropanenitrile^[33]	C₂F₅CN	−37		145	422-04-8
Perfluorodimethylamine^[34]	(CF₃)₂NF	−37		171	359-62-6
Octafluoropropane	C₃F₈	−36.8	−147.7	188	76-19-7
Germanium tetrafluoride	GeF₄	−36.5	−15 triple	149	7783-58-6
Cyclopropene	C₃H₄	−36		40	2781-85-3
Trifluoromethyl fluoroformate^[35]	CF₃OC(O)F	−36	≈−120	132	3299-24-9
Trifluoromethyl isocyanate^[36]	CF₃NCO	−36		111	460-49-1
Tetrafluoro-1,2-diazetidine	C₂F₄N₂H₂	−36		130
Hydrogen iodide	HI	−35.5	−50.76	128	10034-85-2
Pentafluorosulfur hypofluorite	SOF₆	−35.1	−86	162	15179-32-5
Difluoromethoxy(trifluoro)methane	CF₃OCHF₂	−35.0	−157	136	3822-68-2
Propadiene	CH₂=C=CH₂	−34.8	−136	40	463-49-0
Chlorine	Cl₂	−34.04	−101.5	71	7782-50-5
Trifluoromethyl fluoroformate^[3]^[37]	CF₃OC(O)F	−34		132	3299-24-9
Diboron tetrafluoride	B₂F₄	−34	−56	98	13965-73-6
Ammonia	NH₃	−33.33	−77.73	17	7664-41-7
Hexafluorocyclopropane^[38]	-CF₂CF₂CF₂-	−33	−80	150	931-91-9
Trifluoronitromethane^[39]	CF₃NO₂	−32		115	335-02-4
Dichlorodifluorosilane	SiCl₂F₂	−32	−44	137	18356-71-3
(Difluoroamino)difluoroacetonitrile^[40]	NF₂CF₂CN	−32		128	5131-88-4
Hexafluoromethanediamine^[3]^[41]	(NF₂)₂CF₂	−31.9	−161.9	154	4394-93-8
Bis(trifluoromethyl)diazene trans^[3]	CF₃NNCF₃	−31.1		166	372-63-4
Cyclopropane	C₃H₆	−31	−127.6	42	75-19-4
Chlorosilane	SiH₃Cl	−30.4	−118	66.5	13465-78-6
Hexafluoropropylene	CF₂=CFCF₃	−30.2	−156.6	150	116-15-4
Chloroacetylene	HCCCl	−30	−126	60.5	593-63-5
Methyltrifluorosilane	CH₃SiF₃	−30	−73	100	373-74-0
Fluorine azide^[42]	FN₃	−30	−139	61.019	14986-60-8
Dichlorodifluoromethane	CCl₂F₂	−29.8	−157.7	121	75-71-8
2,3,3,3-Tetrafluoropropene^[43]	CF₃CF=CH₂	−29.5	−152.2	114	754-12-1
Tetrafluorodiaziridine^[3]	CF₄N₂	−29		116	17224-09-8
fluoroxypentafluoroselenium^[44]^[45]^[46]	F₅SeOF	−29	−54	209	27218-12-8
Perfluorooxetane	C₃OF₆	−28.6	−117	166	425-82-1
Chlorotrifluoroethene	CClF=CF₂	−28.3	−158.14	116.5	79-38-9
Methyldifluorophosphine	CH₃PF₂	−28	−110	84	753-59-3
Perfluoroacetone	CF₃COCF₃	−27.4	−125.45	166	684-16-2
Trifluoro(trifluoromethyl)oxirane	C₂OF₃CF₃	−27.4	−144	166	428-59-1
Thiazyl trifluoride	N≡SF₃	−27.1	−72.6	103	15930-75-3
Trifluoroacetyl chloride	CF₃COCl	−27	−146	132.5	354-32-5
3,3,3-Trifluoropropene	CF₃CH=CH₂	−27		96	677-21-4
Phosphonium chloride	PH₄Cl	−27 sub		70.5	24567-53-1
Formyl fluoride	HCOF	−26.5	−142.2	48	1493-02-3
1,1,1,2-Tetrafluoroethane	CF₃CH₂F	−26.1	−103.296	102	811-97-2
Trifluoromethyl trifluorovinyl ether^[3]	CF₃OCF=CF₂	−26		166	1187-93-5
Methyl trifluoromethyl ether	CF₃OCH₃	−25.2	−149.1	100	421-14-7
Bis(trifluoromethyl)nitroxide^[47]	(CF₃)₂NO	−25	−70	168	2154-71-4
Sulfur cyanide pentafluoride^[48]	SF₅CN	−25	−107	153	1512-13-6^[49]
Dimethyl ether	CH₃OCH₃	−24.8	−141.49	46	115-10-6
1,1,1,4,4,4-Hexafluoro-2-butyne	CF₃C≡CCF₃	−24.6	−117.4	162	692-50-2
1-Chloro-1-fluoroethene^[3]	CClF=CH₂	−24.1		80.5	2317-91-1
1,1-Difluoroethane	CHF₂CH₃	−24.05	−118.6	66	75-37-6
2-Fluoropropene^[50]	CH₃CF=CH₂	−24		60	1184-60-7
Borirane	C₂H₄BH	−24	−129	40	39517-80-1
Chloromethane	CH₃Cl	−23.8	−97.4	50.5	74-87-3
Trifluoronitrosoethylene^[51]	CF₂=CFNO	−23.7		111	2713-04-4
Pentafluoro(trifluoromethoxy)ethane^[52]	C₂F₅OCF₃	−23.6		204	665-16-7
Difluoramine [de]	NHF₂	−23.6	−116	53	10405-27-3
1,1-Difluorocyclopropane^[53]	CF₂CH₂CH₂	−23.5		78	558-29-2
Propyne or methylacetylene	CH₃CCH	−23.2	−103.0	40	74-99-7
Diazomethane	CH₂N₂	−23	−145	42	334-88-3
Methylgermane	CH₃GeH₃	−23	−158	91	1449-65-6
Prop-1-en-1-one or methylketene	CH₃CH=CO	−23	−80	56	6004-44-0
Vinylsilane	CH₂=CHSiH₃	−22.8		58	7291-09-0
Trifluoroiodomethane	CF₃I	−22.5	−110	196	2314-97-8
Ethynylsilane	HC≡CSiH₃	−22.5		56	1066-27-9
Hexafluoro-1,3-dioxolane^[54]	c-CF2OCF2OCF2-	−22.1		182.02	21297-65-4
Chloromethane sulfonyl chloride^[3]	CH₂ClS(O)(O)Cl	−22		149	3518-65-8
Trifluoromethyl peroxychloride^[3]	CF₃OOCl	−21.9	−132	136.5	32755-26-3
Carbonyl selenide	COSe	−21.7	−124.4	107	1603-84-5
Trifluoromethanesulfonyl fluoride	CF₃SOF	−21.7		136	335-05-7
Chlorine trifluoride dioxide	ClO₂F₃	−21.6	−81.2	124.5	38680-84-1
Carbonyl bromide fluoride	COBrF	−21		127	753-56-0
Bromopentafluoroethane	C₂BrF₅	−21		199	354-55-2
Cyanogen	NCCN	−21	−27.83	52	460-19-5
Methoxysilane	CH₃OSiH₃	−21	−98.5	62	2171-96-2
1,1,3,3,3-Pentafluoropropene	CF₂=CHCF₃	−21	-153	132	690-27-7
Carbonyl bromide fluoride^[3]	CBrFO	−20.6		127	753-56-0
Trifluoromethylsulfur pentafluoride^[3]	CF₃SF₅	−20.4	−87	196	373-80-8
Chlorotrifluorogermane	GeClF₃	−20.3	−66.2	165.5	14188-40-0
Trimethylborane	(CH₃)₃B	−20.2	−159.93	56	593-90-8
Dimethylsilane	(CH₃)₂SiH₂	−20	−150	60	1111-74-6
1,1,2,2-Tetrafluoroethane	CHF₂CHF₂	−19.9	−89	102	359-35-3
Formaldehyde	H₂CO	−19.1	−92	30	50-00-0
Hexafluorodisilane	SiF₃SiF₃	−19.1	−18.7 triple	170	13830-68-7
Sulfur chloride pentafluoride	SClF₅	−19.05	−64	158.5	13780-57-9
1-Chloro-2,2-difluoroethene	CHCl=CF₂	−18.8	−138.5	98.5	359-10-4
E-1,2,3,3,3-Pentafluoropropene	CFH=CFCF₃	−18.7		132	5595-10-8
1,1,1,2,2-Pentafluoropropane	CF₃CF₂CH₃	−18		133	1814-88-6
Hexafluoropropene	CF₂=CFCF₃	−18	−153	150	116-15-4
Fluoral^[55]	CF₃CHO	−18		98	75-90-1
2-Chloro-1,1-difluoroethylene^[56]	CF2=CHCl	−17.7	−138.5	98	359-10-4
Difluoroamino sulfur pentafluoride^[57]	NF₂SF₅	−17.5		179	13693-10-2
Stibine	SbH₃	−17	−88	125	7803-52-3
1,1,2,2,3,3,3-Heptafluoropropane^[58]	CF₂HCF₂CF₃	−17	−148.5	170	2252-84-8
1,1,1,2,3,3,3-Heptafluoropropane	CF₃CHFCF₃	−16.34	−126.8	170	431-89-0
Phosphorus(III) bromide difluoride	PBrF₂	−16.1	−133.8	149	15597-40-7
Methylphosphine	CH₃PH₂	−16		48	593-54-4
Fluorine perchlorate	FOClO₃	−16	−167.3	118.5	10049-03-3
Bis(trifluoromethyl) trioxide^[59]	CF₃OOOCF₃	−16	−138	186
1,3,3,3-Tetrafluoropropene^[3]	CF₃CH=CHF	−16	−104.53	114	1645-83-6
N,N-Difluoromethanamine^[3]^[60]	CH₃NF₂	−15.9	−114.8	53	753-58-2
1-Trifluoromethyl-1,2,2-trifluorocyclopropane^[53]	CF₃C₃H₂F₃	−15.8		152
Disiloxane	(SiH₃)₂O	−15.2	−144	78	13597-73-4
cis-1-Fluoropropene	CH₃CH=CHF	−15		60	19184-10-2
trans-1-Fluoropropene	CH₃CH=CHF	−15?		60	20327-65-5
Nitryl chloride	NO₂Cl	−15	−145	81.5	13444-90-1
Chlorazide	ClN₃	−15	−100	77.47	13973-88-1
Disilane	Si₂H₆	−14.8	−129.4	62	1590-87-0
Z-1,2,3,3,3-Pentafluoropropene	CHF=CFCF₃	−14.7		132	5528-43-8
Bromodifluoromethane	CHBrF₂	−14.6	−145	131	1511-62-2
Chloroethene	CH₂=CHCl	−13.8	−153.84	62.5	75-01-4
Monoethylsilane^[61]	CH₃CH₂SiH₃	−13.7	−180	60	2814-79-1
Chlorine pentafluoride	ClF₅	−13.1	−103	130.5	13637-63-3
Perfluorocyclopropene^[62]	-CF=CFCF2-	−13	−60	112	19721-29-0
1,1,1-Trifluoropropane	CF₃CH₂CH₃	−13		98	421-07-8
1-Chloro-1,1,2,2-tetrafluoroethane	CClF₂CHF₂	−13	−117	135.5	354-25-6
Carboimidic difluoride	CF₂NH	−13 dec	−90	65	2712-98-3
Plumbane	PbH₄	−13		211	15875-18-0
Methyl nitrite	CH₃NO₂	−12	−16	61	624-91-9
Trifluoromethylarsine^[63]	CF₃AsH₂	−12		146	420-42-8
1-Chloro-1,2,2,2-tetrafluoroethane	CHClFCF₃	−11.96	−199.15	136.5	2837-89-0
Isobutane	(CH₃)₂CHCH₂	−11.7	−159.42	58	75-28-5
Trifluoromethoxy sulfur pentafluoride^[64]	CF₃OSF₅	−11	−143	212	1873-23-0
Thiothionyl fluoride	SSF₂	−10.6	−164.6	102	101947-30-2
Sulfur dioxide	SO₂	−10.05	−75.5	64	7446-09-5
Pentafluorocyclopropane^[62]	-CHFCF₂CF₂-	−10	−10	132	872-58-2
2-Fluoropropane	CH₃CHFCH₃	−10		62	420-26-8
Pentafluoroethyl hypochlorite^[65]	C₂F₅OCl	−10±		170.5	22675-67-8
Fluoroformyl sulfurpentafluoride^[66]	SF₅C(O)F	−10		174
Trifluoromethyl fluoroformyl peroxide^[67]	CF₃OOC(O)F	~−10		148	16118-40-4
Perfluorodimethoxymethane	CF₃OCF₂OCF₃	−10	−161	220	53772-78-4
1-Chloro-1,1-difluoroethane	CClF₂CH₃	−9.6	−130.8	100.5	75-68-3
Chlorofluoromethane	CH₂ClF	−9.1	−133.0	68.5	593-70-4
Pentafluoroethyl isocyanate^[68]	C₂F₅NCO	−9		157	356-74-1
Bis(trifluoromethyl)chloramine^[69]	(CF₃)₂NCl	−9		187.5
Selenium dioxydifluoride	SeO₂F₂	−8.4	−99.5	149	14984-81-7
Fluoro(trifluoro-methyl)diazine^[3]	CF₄N₂O	−7.63		132	815-10-1
Isobutene	(CH₃)₂C=CH₂	−7.0	−140.7	56	115-11-7
3-Fluoropropene	CH₂=CHCH₂F	−7		60	818-92-8
Bis(trifluromethyl)amine^[3]	(CF₃)₂NH	−7		153	371-77-7
Ethoxytrifluorosilane^[70]	CH₃H₂OSiF₃	−7	−122	118	460-55-9
Trifluoromethylsulfur trifluoride^[71]	CF₃SF₃	−7	−110	158	374-10-7
Perfluoro-2-methyl-1,2-oxazetidine^[72]	(CF₃-N)CF₂CF₂O	−6.8		199
Tris(trifluoromethyl)-amine^[34]	(CF₃)₃N	−6.5		221	432-03-1
Methylamine	CH₃NH₂	−6.4	−93.42	31	74-89-5
1-Butene	CH₂=CHCH₂CH₃	−6.3	−185.33	56	106-98-9
Diphosphorus tetrafluoride	P₂F₄	−6.2	−86.5	138	13824-74-3
Chloryl fluoride	ClO₂F	−6	−115	86.5	13637-83-7
Trifluoromethyl iminosulfur difluoride^[73]	CF₃N=SF₂	−6		153	1512-14-7
Perfluorocyclobutane	-CF₂CF₂CF₂CF₂-	−5.91	−40.16	200	115-25-3
Perfluoro-2-butene	CF₃CCF=CF₃	−5.9		200	360-89-4 trans
Nitrosyl chloride	ONCl	−5.55	−59.4	65.5	2696-92-6
Difluorocarbamoylchloride	CClF₂NO	−5.5		115.5	16847-30-6
Hexafluoro 1,2-dioxolane^[74]	-CF₂CF₂CF2OO-	−5	−115.5	182.02
2,3,3,3-tetrafluoro-2-(trifluoromethyl)-propanenitrile^[75]	N≡CCF(CF₃)₂	−4.7	−118	195.038	42532-60-5
1,3-Butadiene	CH₂=CHCH=CH₂	−4.6	−108.9	54	106-99-0
Ethyltrifluorosilane^[76]	CH₃CH₂SiF₃	−4.4	−105	114	353-89-9
Difluoro-N-fluoromethanimine	F₂C=NF	−4		83	338-66-9
1,1-Dimethyldiborane	(CH₃)₂B(μ-H)₂BH₂	−4	−150.2	56	16924-32-6
trans-1-Chloro-2-fluoroethene^[77]	CHCl=CHF	−4		80.5	2268-32-8
Bromochlorodifluoromethane	CF₂ClBr	−3.7	−159.5	165.5	353-59-3
N-Nitroso-bis(trifluoromethyl)amine^[78]	ONN(CF₃)₂	−3.5		182
Trifluoromethyl 1,1,2,2-tetrafluoroethyl ether^[54]	CF₃OCF₂CF₂H	−3.3	−141	186	2356-61-8
1-Fluoropropane^[3]	CH₂FCH₂CH₃	−3.2	−159	62	460-13-9
3-Fluoropropene^[50]	CH₂CHCH₂F	−3		60	818-92-8
Dimethylperoxide	CH₃OOCH₃	−3	−100	62	690-02-8
Trifluoromethyl thionitrite^[79]	CF₃SNO	−3		131
Dichlorodifluorogermane	GeCl₂F₂	−2.8	−51.8	182	24422-21-7
Bromotrifluoroethene	CBrF=CF₂	−2.5		161	598-73-2
Trifluoromethane sulfinyl fluoride^[3]	CF₃SOF	−2.5		136	812-12-4
Perfluorobutane	C₄F₁₀	−2.1	−129	238	355-25-9
Hydrogen telluride	H₂Te	−2	−49	130	7783-09-7
1-Chloroheptafluoropropane^[80]	CF₃CF₂CF₂Cl	−2		204.5	422-86-6
2-Chloroheptafluoropropane^[80]	CF₃CFClCF₃	−2		204.5	76-18-6
Bis(trifluoromethyl)selenium^[81]	(CF₃)₂Se	−2		217	371-79-9
Trifluoromethyl sulfinyl fluoride^[71]	CF₃S(O)F	−1.6		136	812-12-4
1,1,1,2,2,3-Hexafluoropropane	CF₃CF₂CFH₂	−1.44	−98.38	152	677-56-5
1,1,1,3,3,3-Hexafluoropropane	CF₃CH₂CF₃	−1.4	−93.6	152	690-39-1
Pentafluoroguanidine^[82]	CF₅N₃	−1		149	10051-06-6
1,1,2,2-Tetrafluoropropane^[83]	CHF₂CF₂CH₃	−0.8	−121.1	116	40723-63-5
Heptafluoronitrosopropane^[20]	C₃F₇NO	−0.7		199	354-72-3
Trifluoromethanesulfenylchloride^[3]	CF₃SCl	−0.6		136.5	421-17-0
1,1,1,2-Tetrafluoropropane	CF₃CHFCH₃	−1-0		116	421-48-7
1,1,2,2,3,3-Hexafluoropropane^[3]	CHF₂CF₂CHF₂	−0.3	−98.38	152	680-00-2
Butane	C₄H₁₀	0	−140	58	106-97-8
2,2-Difluoropropane	CH₃CF₂CH₃	0	−104.8	80	420-45-1
Perfluoroisobutane	C₄F₁₀	0		238	354-92-7
Nitrosyl bromide	NOBr	0	−56	110	13444-87-6
Xenon tetroxide	XeO₄	0 dec	−35.9	195	12340-14-6
Trifluoromethylsulfonyl hypofluorite^[84]	CF₃SO₂OF	0	−87	168
Trifluoromethyl chloroformate^[85]	CF₃OC(O)Cl	0		148.5	23213-83-4
Decafluorodiethyl ether^[86]	CF₃CF₂OCF₂CF₃	0		254	358-21-4
Perfluorocyclobutanone^[87]	-CF₂CF₂CF₂C(O)-	0		178	699-35-4
Trifluoromethyl peroxonitrate^[3]	CF₃OONO₂	0.4		129	50311-48-3
Thiazyl fluoride^[88]	NSF	0.4	−89	65.07	18820-63-8
Perfluorotetrahydrofuran	-OCF₂CF₂CF₂CF₂-	0.6	−85	216	773-14-8
pentafluorotellurium hypofluorite^[89]	F₅TeOF	0.6
Tetrafluoro(trifluoromethylimino)-λ⁶-sulfane^[90]	F₄S=NCF₃	0.75±0.25		191
trans-2-Butene	CH₃CH=CHCH₃	0.9	−43.3	56	624-64-6
Methylcyclopropane	CH₃CHCH₂CH₂	1	−177.2	56	594-11-6
Bis(trifluoromethyl)phosphine^[91]	(CF₃)₂PH	1		170
Oxalyl fluoride^[15]	CFOCFO	1±1	−12.42	94	359-40-0
Methylstannane	CH₃SnH₃	1.4		137	1631-78-3
Azomethane	CH₃N=NCH₃	1.5	−78	58	503-28-6
1,1,2,3,3-Pentafluoropropene	CF₂=CFCHF₂	1.5	−101.2	132	433-66-9
Bromosilane	SiH₃Br	1.9	−94	111	13465-73-1
Methylarsine	CH₃AsH₂	2	−143	92	593-52-2
Hexafluorocyclobutene	C₄F₆	2	−60	162	697-11-0
Chlorine monoxide	Cl₂O	2.2	−120.6	87	7791-21-1
Cyclobutene	C₄H₆	2.5		54	822-35-5
Difluorodimethylsilane	(CH₃)₂SiF₂	2.5	−87.5	96	353-66-2
1,1,1-Trifluoroazomethane^[3]	CF₃NNCH₃	2.5		112	690-21-1
dichorotrifluorophosphorane^[28]	PCl₂F₃	2.5	−124	159	13659-65-9
Trimethylamine	(CH₃)₃N	2.8	−117.1	59	75-50-3
1,1-Dichloro-1,2,2,2-tetrafluoroethane	CCl₂FCF₃	3	−56.6	152	374-07-2
Sulfur bromide pentafluoride	SBrF₅	3.1	−79	207	15607-89-3
1,1,2-Trifluoroethane	CHF₂CH₂F	3.5	−84	84	430-66-0
1,2-Dichloro-1,1,2,2-tetrafluoroethane	CClF₂CClF₂	3.6	−92.52	171	76-14-2
cis-2-Butene	CH₃CH=CHCH₃	3.72	−138.9	56	590-18-1
Phosphorus dihydride trifluoride^[28]	PH₂F₃	3.9	−52	90
Bromomethane	CH₃Br	4	−93.66	95	74-83-9
1,2-Dimethyldiborane	[(CH₃)BH₂]₂	4	−124.9	56	17156-88-6
Selenium chloride pentafluoride	SeClF₅	4.5	−19	209.5	34979-62-9
1,1,4,4-Tetrafluoro-1,3-butadiene^[92]	CF₂=CFCF=CF₂	4.5±		162	407-70-5
Trifluoromethyl phosphorodifluoridate^[84]	CF₃OP(O)F₂	4.6	−96.2	170	39125-43-4
Bromoacetylene	C₂HBr	4.7		105	593-61-3
Iodine heptafluoride	IF₇	4.8	6.5 triple	250	16921-96-3
Dimethylchloroborane^[3]	(CH₃)₂BCl	4.9	−39.9	76.5	1803-36-7
Perfluoro-1-butene^[3]	CF₃CF₂CF=CF₂	5		200	357-26-6
Pentafluorosulfanyl cyanate^[90]^[93]	F₅SOCN	5-5.5	−60	169
1,1,2,3,4,4-Hexafluoro-1,3-butadiene	CF₂CFCFCF₂	5.4	−132	162	685-63-2
Bis(difluoromethyl) ether	CHF₂OCHF₂	5.5		118	1691-17-4
Methyl pentafluoroethyl ether	CH₃OC₂F₅	5.6		140	22410-44-2
Tris(difluoroamine)fluoromethane^[3]	(NF₂)₃CF	5.6	−136.9	187	14362-68-6
Perfluoro ethyl methyl ether	C₂F₅OCF₃	5.61		204
1-Bromo-2,2-difluoro-ethylene^[94]	CHBr=CF₂	5.7		143
Perfluoro-1,3-butadiene^[95]	CF₂=CFCF=CF₂	5.8	−132	162	685-63-2
Methanethiol^[3]	CH₃SH	5.95	−123	48	74-93-1
1-Buten-3-yne	CH₂CHC≡CH	6		54	689-97-4
Methoxyethane	CH₃OC₂H₅	6	−113	60	540-67-0
Methyl vinyl ether	CH₃OCH=CH₂	6	−122	58	107-25-5
1,1,1-Trifluoro-2-chloroethane	CF₃CH₂Cl	6.1	−105.5	118.5	75-88-7
1,1,1,2,3,3-Hexafluoropropane	CF₃CH₂CF₃	6.2		152	431-63-0
Phosphorothioic chloride difluoride	PSClF₂	6.3	−155.2	136.5	2524-02-9
Perfluoro-2-methoxypropionylfluoride^[87]	CF₃OCF(CF₃)C(O)F	5-8		232
Trimethylsilane	(CH₃)₃SiH	6.7	−153.9	74	993-07-7
Carbon suboxide	OCCCO	6.8	−111.3	68	504-64-3
2-Chloropentafluoropropene^[58]	CF₃CCl=CF₂	6.8		166.5	2804-50-4
dimethylgermane^[96]	CH₃GeH₂CH₃	7.0		104.72	1449-64-5
Perfluoroisobutene	(CF₃)₂C=CF₂	7	−130	200	382-21-8
Pentafluoroethyl trifluorovinyl ether	CF₃CF₂OCFCF₂	7		216	10493-43-3
1,1-Difluoropropane	CHF₂CH₂CH₃	7-8		80	430-61-5
1,1,1,2,4,4,4-Heptafluoro-2-butene^[72]	CF₃CF=CHCF₃	7-8		182
Chloromethylsilane	CH₃ClSi	7	−135	78.5	993-00-0
Fluoromethyldifluoroborane^[97]^[98]	CH₂FBF₂	7	−47	82
Nitryl cyanide^[99]	NCNO₂	7	−85	72	105879-05-8
Silylgermane^[100]	GeH₃SiH₃	7.0	−119.7	107	13768-63-3
Phosphorus(V) dichloride trifluoride	PCl₂F₃	7.1	−125	159	13454-99-4
Sulfuryl chloride fluoride	SO₂ClF	7.1	−124.7	118.5	13637-84-8
Dimethylamine	(CH₃)₂NH	7.3	−93	45	124-40-3
3-Chloropentafluoropropene^[58]	CF₂ClCF=CF₂	7.4		166.5	79-47-0
Phosgene	COCl₂	7.5	−127.77	99	75-44-5
Chloropentafluoroacetone	CClF₂COCF₃	7.8	−133	182.5	79-53-8
1-Butyne	CH₃CH₂C≡CH	8.08	−125.7	54	107-00-6
Dichlorosilane	SiH₂Cl₂	8.3	−122	101	4109-96-0
trans-1,1,1,4,4,4-hexafluoro-2-butene^[101]	CF₃CH=CHCF₃	8.5		164	407-60-3
2-Bromo-1,1,1,2-tetrafluoroethane^[72]	CF₃CHFBr	8.65		181
Methyl chlorosilane^[3]	CH₃SiH₂Cl	8.7	−134.1	80.5	993-00-0
Pentafluorosulfanyl hypochlorite^{[citation needed]}	SF₅OCl	8.9		178.5
Dichlorofluoromethane	CHCl₂F	8.92	−135	103	75-43-4
ethylgermane^[102]	CH₃CH₂GeH₃	9.2		104.66
Neopentane	(CH₃)₄C	9.5	−16.5	72	463-82-1
Trifluoromethylperchlorate	CF₃OClO₃	9.5		168.5	52003-45-9
1,3-Butadiyne	HC≡CC≡CH	10	−35	50	460-12-8
N-Nitroso-O,N-bis(trifluoromethyl)-hydroxylamine or O-Nitroso-bis(trifluoromethy1)hydroxylamine^[103]^[104]	CF₃(CF₃O)NNO or (CF₃)₂NONO	10		198	367-54-4
Ethylene oxide	CH₂OCH₂	10.4	−112.46	44	75-21-8
1,2-Difluoroethane^[3]	CH₂FCH₂F	10.5	−118.6	66	624-72-6
1,2-Butadiene	CH₃CH=C=CH₂	11	−136.20	54	590-19-2
Dichloromethylborane	CH₃BCl₂	11		97	7318-78-7
Chlorine dioxide	ClO₂	11	−59	103	10049-04-4
2-Chloro-2,3,3,3-tetrafluoropropanoyl fluoride^[105]	CF₃CFClC(O)F	11		182.5	28627-00-1
Methyl trifluorovinyl ether^[106]	CH₃OCF=CF₂	11		112	3823-94-7
Trifluoromethyl hydroperoxide^[3]^[107]	CF₃OOH	11.3		102	16156-36-8
Methyl trifluoromethyl sulfide^[81]	CH₃SCF₃	11.5		116	421-16-9
Chlorine trifluoride	ClF₃	11.75	−76.34	128	7790-91-2
1-bromoheptafluoropropane^[80]	CF₃CF₂CF₂Br	12		249	422-85-5
Tert-butylfluoride^[108]	(CH₃)₃CF	12		76	353-61-7
1,1,1,2,2,3,3,4,4-Nonafluorobutane^[3]	CF₃CF₂CF₂CF₂H	12		220	375-17-7
2-Fluoro-2-methylpropane	CH₃(CH₃)CFCH₃	12.1		76	353-61-7
Trichlorofluorosilane	SiCl₃F	12.25		153.5	14965-52-7
Chloroethane	CH₃CH₂Cl	12.27	−138	64.5	75-00-3
Pentafluoroiodoethane^[109]	CF₃CF₂I	12.5	−92	246	354-64-3
Cyclobutane	C₄H₈	12.5	−90.7	56	287-23-0
1,1-difluoro-N-(pentafluoro-λ⁶-sulfanyl)methanimine^[90]	F₅SN=CF₂	12.5±0.5		191
2-diazo-1,1,1,3,3,3-hexafluoropropane^[110]	(CF₃)₂CN₂	12.5±0.5		178	684-23-1
Silylphosphine^[111]	SiH₃PH₂	12.7		68	14616-47-8
Cyanogen chloride	ClCN	13	−6.55	61.5	506-77-4
trans-1-Bromo-1,2-difluoroethylene^[94]	CBrF=CFH	13		143	358-99-6
Trifluoromethyl phosphine^[3]	CF₃PH₂	13.1		102	420-52-0
2,2,2-Trifluorodiazoethane^[112]	CF₃CHNN	13.2		91	371-67-5
2-Chloro-1,1,1,2-tetrafluoropropane HCFC-244bb^[113]	CF₃CClFCH₃	13.23		150.5	421-73-8
Pentafluoroethyl sulfur pentafluoride^[114]	C₂F₅SF₅	13.5		246
Phosphorus(III) dichloride fluoride	PCl₂F	13.85	−144	121	15597-63-4
2-Chloro-1,1,1,3,3,3-hexafluoropropane^[58]	CF₃CHClCF₃	14	−120.8	186.5	51346-64-6
2-Chloro-3,3,3-trifluoroprop-1-ene^[77]	CH₂=CClCF₃	14		130.5	2730-62-3
2-(Pentafluorothio)-3,3-difluorooxaziridine^[115]	SF₅(-NCF₂O-)	14.0		207	73002-62-7
Difluoro(difluorochloromethyl)amine	CClF₂NF₂	14.14		137.5	13880-71-2
Nitrosyl bromide	ONBr	14.5		110	13444-87-6
Hexafluoroisobutylene^[3]	(CF₃)₂C=CH₂	14.5		164	382-10-5
N,N-Difluoroethylamine^[60]	CH₃CH₂NF₂	14.9	−150.3	81	758-18-9
Disulfur difluoride	FSSF	15	−133	102	13709-35-8
cis-1-Chloro-2-fluoroethene^[77]	CHCl=CHF	15		80.5	2268-31-7
(Z)-1-chloro-2,3,3,3-tetrafluoropropene^[77]	CHCl=CFCF₃	15		148.5	111512-60-8
1,1,1,3,3-Pentafluoropropane^[3]	CF₃CH₂CHF₂	15.14	−102.10	134	460-73-1
Trifluoromethyl phosphorodifluoroperoxoate^[84]	CF₃OOP(O)F₂	15.5	−88.6	167	39125-42-3
(Trifluoroacetyl)sulfur pentafluoride^[66]	CF₃C(O)SF₅	15.6	−112	224	82390-51-0
Vinyl bromide	CH₂=CHBr	15.8	−137.8	107	593-60-2
Bis(fluorocarbonyl) peroxide^[116]^[15]	CF(O)OOCFO	15.9	−42.5	126	692-74-0
1-Chloro-1,1,2-trifluoroethane	CClF₂CH₂F	16		118.5	421-04-5
cis-1-Bromo-1,2-difluoroethylene^[94]	CBrF=CHF	16		143
1-Fluoro-2-methylpropane^[108]	CH₂FCHCH₃CH₃	16		76	359-00-2
Difluoromethyl 1,1,2-trifluoroethyl ether	CHF₂OCF₂CH₂F	16.14		150	69948-24-9
1-Chloro-1-fluoroethane^[3]	CHClFCH₃	16.15		82.5	1615-75-4
Fluorotrimethylsilane	(CH₃)₃SiF	16.4	−74.3	92	420-56-4
Bis(trifluoromethyl)nitramine^[69]	(CF₃)₂NNO₂	16.4		198
Hexafluoroacetone imine^[117]	CF₃C(=NH)CF₃	16.5±	−47	165	1645-75-6
Dichloro(trifluoromethyl)amine^[3]	CF₃NCl₂	16.6		154	13880-73-4
Ethylamine	CH₃CH₂NH₂	16.6	−81	45	75-04-7
1,1,1-Trifluorobutane^[118]	CF₃CH₂CH₂CH₃	16.74	−114.79	112	460-34-4
Bismuthine	BiH₃	17	−67	212	18288-22-7
2,2,3,3-Tetrafluorobutane^[72]	CH₃CF₂CF₂CH₃	17		130
tris(trifluoromethyl)phosphine^[119]	(CF₃)₃P	17		238	432-04-2
Tungsten hexafluoride	WF₆	17.1	1.9	294	7783-82-6
1-Chloro-1,2,2-trifluoroethane	CHClFCHF₂	17.3		99.5	431-07-2
Bis (trifluoromethyl) carbamyl fluoride	(CF₃)₂NC(O)F	17.5±2.5		199
Ethyl nitrite	C₂H₅NO₂	17.5		75	109-95-5
Tetraborane(10)	B₄H₁₀	18	−120	54	18283-93-7
trifluoro-(sulfinylamino)methane^[120]	CF₃N=S=O	18		131	10564-49-5
F-2,3-dihydro-1,4-dioxin^[121]	-CF₂CF₂OCF=CFO-	18.5		158
Bromofluoromethane	CH₂BrF	19 (CRC=23)		113	373-52-4
Bis(trifluoromethyl)arsine^[63]	(CF₃)₂AsH	19		214
1,1-Dichloro-2,2-difluoroethene	CCl₂=CF₂	19	−116	135	79-35-6
Perfluorovinylsulphur pentafluoride^[122]	CF₂=CFSF₅	19		208	1186-51-2
Difluorotris(trifluoromethyl)phosphorane^[119]	(CF₃)₃PF₂	19		276	661-45-0
trans-1-Chloro-3,3,3-trifluoropropene^[77]	CHCl=CHCF₃	19		130.5	102687-65-0
Fluoroformic acid anhydride^[123]	FC(O)OC(O)F	19.2	−46.2	110	177036-04-3
Trifluorovinyl isocyanate^[124]	CF₂=CFNCO	19.5		123	41594-57-4
Hydrogen fluoride	HF	20	−83.36	20	7664-39-3
Bromine monofluoride	BrF	20 dec	−33	99	13863-59-7
Perbromyl fluoride	BrO₃F	20 dec	−110	147	25251-03-0
1-Chloro-1,1,2,2-tetrafluoropropane^[125]	CF₂ClCF₂CH₃	20		150.5	421-75-0
Perfluorooxaspiro[2.3]hexane^[87]	C₅F₈O	18-21		228
pentafluoroethylsulfinyl fluoride^[71]	C₂F₅S(O)F	20		186	20621-31-2
3-Methyl-1-butene	CH₂=CHCH(CH₃)₂	20.1	−168.41	70	563-45-1
Acetaldehyde	CH₃CHO	20.2	−123.37	44	75-07-0
Chlorotetrafluoro(trifluoromethyl)sulfur	CF₃SClF₄	20.2		212.5	42179-04-4
trans-Bis(trifluoromethyl)sulfur tetrafluoride^[126]	CF₃SF₄CF₃	20.5		246	42179-02-2
Decafluorocyclopentane^[3]	C₅F₁₀	20.5		250	376-77-2
1,1-Dimethylcyclopropane	(CH₃)₂CCH₂CH₂	21	−109.0	70	1630-94-0
Acetyl fluoride	CH₃C(O)F	21	−84	62	557-99-3
Perfluoro-N-methyloxazolidine	CF₃-NCF₂OCF₂CF₂-	21		237
Bis(trifluoromethyl)cyanoamine^[69]	(CF₃)₂NCN	21		178
Bis(trifluoromethyl)sulfur difluoride^[81]	(CF₃)₂SF₂	21		198	30341-38-9
Methaneselenol^[127]	CH₃SeH	21		95	6486-05-1
Perfluoroethyldimethylamine^[34]	C₂F₅(CF₃)₂N	21±1		271	815-28-1
cis-1,2-Dichloro-1,2-difluoroethene	CClF=CClF	21.1	−119.6	133	598-88-9
Trifluoromethyl trifluoromethanesulfonate^[128]	CF₃SO₂OCF₃	21.2	−108.2	218	3582-05-6
Dinitrogen tetroxide	N₂O₄	21.15	−9.3	92	10544-72-6
Difluoroiodomethane	CHF₂I	21.5	−122	178	1493-03-4
Trifluoromethylcyclopropane^[53]	C₅H₆F₃CH₃	21.6		110	381-74-8
1,1,1-Trifluoroacetone	CF₃C(O)CH₃	21.9	−78	112	421-50-1
trans-1,2-Dichloro-1,2-difluoroethene	CClF=CClF	22	−93.3	133	27156-03-2
Heptafluoroisopropyl hypochlorite^[65]	(CF₃)₂CFOCl	22		220.5	22675-68-9
Perfluoroazoethane^[36]	C₂F₅NNC₂F₅	22		266
1,2,2-Trifluoropropane^[129]	CH₂FCF₂CH₃	22		98	811-94-9
Bis(trifluoromethyl)bromamine^[69]	(CF₃)₂NBr	22		232
Bis(trifluoromethyl)sulfide^[130]	(CF₃)₂S	22.2		170	371-78-8
Bis(trifluoromethyl)tellurium^[131]	(CF₃)₂Te	22.5	−123
1,1,1,3,3-Pentafluorobutane	CF₃CH₃CF₂CH₃	22.6	−34.1	149	406-58-6
octafluoro-1,4-dioxane^[132]	(-CF₂CF₂OCF₂CF₂O-)	22.75±0.25		232	32981-22-9
Cyanic acid	HNCO	23	−86	43	420-05-3
2-Chloropropene	CH₃CCl=CH₂	23	−137.4	76.5	557-98-2
1,2,2,2-Tetrafluoroethyl difluoromethyl ether	CF₃CHFOCHF₂	23		168	57041-67-5
1,1,1,2,3-Pentafluoropropane^[133]	CF₃CHFCH₂F	23		134	431-31-2
2,2,3,3,4,4,5-Heptafluoro oxolane^[134]	-CF₂CF₂CF₂CHFO-	23		179
Pentafluoroethyl iminosulfur difluoride^[73]	CF₃CF₂N=SF₂	23±1		203
Methoxyacetylene^[135]	CH₃OC≡CH	23±0.5		56	6443-91-0
Carbonyl fluoride iodide	COFI	23.4		174	1495-48-3
1,2,2,2-Tetrafluoroethyl difluoromethyl ether^[3]	CF₃CHFOCHF₂	23.4		168	57041-67-5
Propylsilane^[61]	CH₃CH₂CH₂SiH₃	23.5±		78	13154-66-0
Trichlorofluoromethane	CCl₃F	23.77	−110.48	137.5	75-69-4
1-Chloro-1,3,3,3-tetrafluoropropene^[58]	CF₃CH=CFCl	24		148.5	460-71-9
1,1,2,2-Tetrafluoro-1-nitro-2-nitrosoethane^[136]	NO₂CF₂CF₂NO	24.2		176	679-08-3
Germyl methyl ether^[137]	GeH₃OCH₃	24.3		107	5910-93-0
Dibromodifluoromethane^[3]	CBr₂F₂	24.45	−141.5	210	75-61-6
Heptafluoro-N-propyl isocyanate^[20]	C₃F₇NCO	24.5		211	87050-96-2
Hexafluorobut-2-yne^[72]	CF₃C≡CCF₃	24.6	−117.4	162	692-50-2
1,1,1,4,4,4-Hexafluorobutane^[138]	CF₃CH₂CH₂CF₃	24.6		166	407-59-0
Chloroheptafluorocyclobutane	C₄ClF₇	25	−39.1	216.5	377-41-3
Dimethylphosphine	(CH₃)₂PH	25		62	676-59-5
Ethyl phosphine^[139]	CH₃CH₂PH₂	25		62	593-68-0
Octafluorocyclopentene^[140]	C₅F₈	25		212	559-40-0
2-Fluorobutane^[141]	CH₃CHFCH₂CH₃	25	−121	76	359-01-3

Known as gas

The following list has substances known to be gases, but with an unknown boiling point.

Fluoroamine
Trifluoromethyl trifluoroethyl trioxide CF₃OOOCF₂CF₃ boils between 10 and 20°^[142]
Bis-trifluoromethyl carbonate boils between −10 and +10°^[37] possibly +12, freezing −60°^[143]
Difluoroaminosulfinyl fluoride F₂NS(O)F is a gas but decomposes over several hours^[144]
Trifluoromethylsulfinyl chloride CF₃S(O)Cl^[71]
Nitrosyl cyanide ?−20° blue-green gas 4343-68-4^[145]
Thiazyl chloride NSCl greenish yellow gas; trimerises.^[88]

Possible

This list includes substances that may be gases. However reliable references are not available.

cis-1-Fluoro-1-propene
trans-1-Chloropropene ?
cis-1-Chloropropene ?
Perfluoro-1,2-butadiene^[146]
Perfluoro-1,2,3-butatriene −5^[147] polymerizes^[148]
Perfluoropent-2-ene
Perfluoropent-1-ene 29-30°^[149]
Trifluoromethanesulfenylfluoride CF₃SF
Difluorocarbamyl fluoride F₂NCOF −52°
N-Sulfinyltrifluoromethaneamine CF₃NSO 18°
(Chlorofluoromethyl)silane 373-67-1 274.37 K (1.22 °C)^[3]
Difluoromethylsilane 420-34-8 237.56 K (−35.59 °C)^[3]
Trifluoromethyl sulfenic trifloromethyl ester^[150]
Pentafluoro(penta-fluorethoxy)sulfur 900001-56-6 15°
Ethenol 557-75-5 10.5° = vinyl alcohol (tautomerizes)
1,1,1,2,2,3,4,4,4-nonafluorobutane 2-10° melt −129°^[58]
trans-2H-Heptafluoro-2-butene
Pentafluoroethylhypochlorite around −10°^[65]
Trifluoromethyl pentafluoroethyl sulfide 6° 33547-10-3 ^[3]
1,1,1-Trifluoro-N-(trifluoromethoxy)methanamine 671-63-6 0.6°^[3]
1-Chloro-1,1,2,2,3,3-hexafluoropropane 422-55-9 16.7^[3]
1-Chloro-1,1,2,3,3,3-hexafluoropropane 359-58-0 17.15^[3]
2-Chloro-1,1,1,2,3,3-hexafluoropropane 51346-64-6 16.7°^[3]
3-Chloro-1,1,1,2,2,3-hexafluoropropane 422-57-1 16.7°^[3]
Trifluormethyl 1,2,2,2-tetrafluoroethyl ether 2356-62-9 11°^[3]
2-Chloro-1,1,1,3,3-pentafluoropropane HFC-235da 134251-06-2 8°^[3]
1,1,2,3,3-Pentafluoropropane 24270-66-4 −3.77
2,2,3,3,4,5,5-Heptafluoro oxolane^[134]
(Heptafluoropropyl)carbonimidic difluoride 378-00-7
Pentafluoroethyl carbonimidic difluoride 428-71-7
(Trifluoromethyl)carbonimidic difluoride 371-71-1 CF₃N=CF₂
Perfluoro[N-methyl-(propylenamine)] 680-23-9
Perfluoro-N,N-dimethylvinylamine 13821-49-3
3,3,4-Trifluoro-2,4-bis-trifluoromethyl-[1,2]oxazetidine 714-52-3
Bis(trifluoromethyl) 2,2-difluoro-vinylamine 13747-23-4
Bis(trifluoromethyl) 1,2-difluoro-vinylamine 13747-24-5
1,1,2-Trifluoro-3-(trifluoromethyl)cyclopropane 2967-53-5
Bis(trifluoromethyl) 2-fluoro-vinylamine 25211-47-6
2-Fluoro-1,3-butadiene 381-61-3
Trifluormethylcyclopropane 381-74-8
cis-1-Fluoro-1-butene 66675-34-1
trans-1-Fluoro-1-butene 66675-35-2
2-Fluoro-1-butene
3-Fluoro-1-butene
trans-1-Fluoro-2-butene
cis-2-fluoro-2-butene
trans-2-fluoro-2-butene
1-Fluoro-2-methyl-1-propene
3-Fluoro-2-methyl-1-propene
Perfluoro-2-methyl-1,3-butadiene 384-04-3
1,1,3,4,4,5,5,5-Pctafluoro-1,2-pentadiene 21972-01-0

Near misses

This list includes substances that boil just above standard condition temperatures. Numbers are boiling temperatures in °C.

1,1,2,2,3-Pentafluoropropane 25–26 °C^[151]^[3]
Dimethoxyborane 25.9 °C
1,4-Pentadiene 25.9 °C
2-Bromo-1,1,1-trifluoroethane 26 °C
1,2-Difluoroethane 26 °C
Hydrogen cyanide 26 °C
Trimethylgermane 26.2 °C^[96]
1,H-Pentafluorocyclobut-1-ene^[140]
1,H:2,H-hexafluorocyclobutane^[140]
Tetramethylsilane 26.7 °C
Chlorosyl trifluoride 27 °C
2,2-Dichloro-1,1,1-trifluoroethane 27.8 °C
Perfluoroethyl 2,2,2-trifluoroethyl ether 27.89 °C
Perfluoroethyl ethyl ether 28 °C
Perfluorocyclopentadiene C₅F₆ 28 °C^[152]
2-Butyne 29 °C
Digermane 29 °C
Perfluoroisopropyl methyl ether 29 °C
Trifluoromethanesulfonyl chloride 29–32 °C^[153]
Perfluoropentane 29.2 °C
Rhenium(VI) fluoride 33.8 °C
Chlorodimethylsilane 34.7 °C
1,2-Difluoropropane 43 °C
1,3-Difluoropropane 40-42 °C
Dimethylarsine 36 °C
Spiro[2.2]pentane 39 °C
Ruthenium(VIII) oxide 40 °C
Nickel carbonyl 42.1 °C
Trimethylphosphine 43 °C

Unstable substances

Gallane liquid decomposes at 0 °C.
Nitroxyl and diazene are simple nitrogen compounds known to be gases but they are too unstable and short lived to be condensed.
Methanetellurol CH₃TeH 25284-83-7 unstable at room temperature.^[154]
Sulfur pentafluoride isocyanide isomerises to sulfur pentafluoride cyanide.^[155]

References

Haynes, W. M., ed. (2016). CRC Handbook of Chemistry and Physics (96th ed.). Boca Raton, Florida: CRC Press/Taylor & Francis. pp. 3–4–4–101. ISBN 978-1482260960.

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List of gases