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Aluminium cyanide
Identifiers
CAS Number	87993-97-3 ;
3D model (JSmol)	Interactive image;
ChemSpider	19984794;
PubChem CID	21122287;
	InChI InChI=1S/3CN.Al/c31-2;/q3-1;+3 Key: BIABJQLRIVAXSJ-UHFFFAOYSA-N;
	SMILES [C-]#N.[C-]#N.[C-]#N.[Al+3];
Properties
Chemical formula	C3AlN3
Molar mass	105.036 g·mol−1
Appearance	white solid
Solubility in water	Reacts
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Aluminium cyanide is a metallic cyanide with a chemical formula of Al(CN)₃.^[1] It is a white solid that undergoes hydrolysis to produce aluminium hydroxide and hydrogen cyanide.^[2]

Synthesis and properties

Aluminium cyanide was first produced in 1924 as its ammoniate, Al(CN)₃·5NH₃, by reacting aluminium metal and mercury(II) cyanide in liquid ammonia to prevent hydrolysis.^[1]

2 Al + 3 Hg(CN)₂ → 2 Al(CN)₃ + 3 Hg

When the ammoniate contacts water, it produces aluminium hydroxide, ammonia, and ammonium cyanide.^[1]

The compound was produced in 2001 by the reaction of lithium tetrachloroaluminate and trimethylsilyl cyanide in diethyl ether. Its atoms form a lattice, and X-ray crystallography shows that its crystals form an octahedral Prussian-blue-like structure.^[3]

References

^ ^a ^b ^c Bergstrom, F. W. (July 1924). "The Reaction Between Mercuric Cyanide and Certain Metals in Liquid Ammonia". Journal of the American Chemical Society. 46 (7): 1559–1568. doi:10.1021/ja01672a002.
^ Axel Schulz; Jonas Surkau (2022). "Main group cyanides: from hydrogen cyanide to cyanido-complexes". Reviews in Inorganic Chemistry. 43 (1): 49–188. doi:10.1515/revic-2021-0044.
^ Darrick Williams; Brett Pleune; Kurt Leinenweber; J. Kouvetakis (2001). "Synthesis and Structural Properties of the Binary Framework C–N Compounds of Be, Mg, Al, and Tl". Journal of Solid State Chemistry. 159 (1): 244–250. Bibcode:2001JSSCh.159..244W. doi:10.1006/jssc.2001.9192.