Phosphorus tricyanide

Phosphorus tricyanide
Names

Other names Tricyanophosphine
Identifiers
CAS Number	1116-01-4^Y
3D model (JSmol)	Interactive image
ChemSpider	120617
PubChem CID	136869
CompTox Dashboard (EPA)	DTXSID30149693
InChI InChI=1S/C3N3P/c4-1-7(2-5)3-6 Key: VXFKMOLPHLQGLH-UHFFFAOYSA-N
SMILES N#CP(C#N)C#N
Properties
Chemical formula	P(CN)₃
Appearance	white crystals
Boiling point	190 °C (374 °F; 463 K) sublimes^[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Phosphorus tricyanide is an inorganic compound with the chemical formula P(CN)₃. It can be produced by the reaction of phosphorus trichloride and trimethyl(iso)cyanosilane.^[2] The reaction of phosphorus tribromide and silver cyanide in diethyl ether produce phosphorus tricyanide too.^[1] Its thermal decomposition can produce graphite phase C₃N₃P.^[3] Phosphorus tricyanide reacts with Re(CO)₅FBF₃ to form {P[CN-Re(CO)₅]₃}(BF₄)₃.^[4]

References

^ ^a ^b Noeth, Heinrich; Vetter, Hans Joachim. Dialkylaminophosphoranes. II. Preparation and reaction of dimethylaminohalophosphoranes, (Me2N)3-nPXn. Chemische Berichte, 1963. 96: 1109-1118. ISSN 0009-2940.
^ T. A. Bither, W. H. Knoth, R. V. Lindsey, W. H. Sharkey (August 1958). "Trialkyl- and Triaryl(iso)cyanosilanes 1". Journal of the American Chemical Society. 80 (16): 4151–4153. doi:10.1021/ja01549a010. ISSN 0002-7863. Archived from the original on 2022-06-25. Retrieved 2022-06-15.{{cite journal}}: CS1 maint: multiple names: authors list (link)
^ Brian L. Chaloux, Brendan L. Yonke, Andrew P. Purdy, James P. Yesinowski, Evan R. Glaser, Albert Epshteyn (2015-07-14). "P(CN) 3 Precursor for Carbon Phosphonitride Extended Solids". Chemistry of Materials. 27 (13): 4507–4510. doi:10.1021/acs.chemmater.5b01561. ISSN 0897-4756. Archived from the original on 2022-06-15. Retrieved 2022-06-15.{{cite journal}}: CS1 maint: multiple names: authors list (link)
^ Wolfgang Sacher, Alfred Schmidpeter, Wolfgang Beck (April 2015). "Organometallic Lewis Acids, Part LIX [1] Pentacarbonylrhenium Complexes with Phosphorus Tricyanide and Dicyanophosphide: Organometallic Lewis Acids, Part LIX". Zeitschrift für anorganische und allgemeine Chemie. 641 (5): 762–764. doi:10.1002/zaac.201500068. Archived from the original on 2022-06-15. Retrieved 2022-06-15.{{cite journal}}: CS1 maint: multiple names: authors list (link)

v t e Phosphorus compounds
Phosphides	AlP AsP BP BiP Cs₂P₅ Ca₃P₂ Cd₃P₂ Cu₃P DyP ErP EuP GdP AuP FeP Fe₃P HfP HoP InP LaP Li₃P LuP MoP MoP₂ Mo₃P NbP NdP NpP Np₃P₄ OsP₂ Ru₂P PtP₂ PrP PrP₅ PuP ScP SmP SmP₅ Sr₃P₂ TbP SnP₃ ThP₇ TmP YP YbP ZnP₂ Zn₃P₂ ZrP ZrP₂
Other compounds	PBr₃ PBr₅ PBr₇ PCl₃ PCl₅ P₂Cl₄ PF₃ PF₅ PI₃ PH₃ PN P₃N₅ PO P₂O₃ P₂O₄ P₂O₅ P₄S₃ P₄S_x P₄S₁₀

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