己硼烷(12)

己硼烷(12)
识别
CAS号 12008-19-4  checkY
SMILES
 
  • [BH3]1[BH3][BH2]1[BH2]2[BH3][BH3]2
性质
化学式 H12B6
摩尔质量 76.96 g·mol−1
外观 无色液体
熔点 -82.3 °C（191 K）
沸点 85 °C（185 °F；358 K） (approx)
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

己硼烷(12)是一种无机化合物，化学式为B6H12，它是无色的可燃液体，易水解。它的纯净样品稳定性更高，其它硼烷杂质会促进它的分解。[1]它曾被Stock和Siecke在1924年发表但后来被撤回，在1960年，Gibbins和Shapiro通过质谱对其进行了确认。[2]

它可通过在激波管中热解乙硼烷或三硼氢化物和酸反应制得，并通过气相色谱进行分离。[1]它可以和三甲胺反应，生成2(CH3)3N·B5H9和(CH3)3N·BH3。[3]

参考文献

  1. ^ 1.0 1.1 Lutz, C. A.; Phillips, D. A.; Ritter, D. M. Hexaborane-12 Isolation and Identification. Inorg. Chem. (1964), 3(8), 1191-1194. doi:10.1021/ic50018a029
  2. ^ S. G. Gibbins and I. Shapiro. A new hexaborane. J. Am. CHem. Soc. 1960. 82 (11). doi:10.1021/ja01496a075.
  3. ^ Alva L. Collins and Riley Schaeffer. Studies of Boranes. XXVIII. Reactions of hexaborane(12). Inorg. Chem. 1970, 9, 9, 2153–2156. doi:10.1021/ic50091a038.

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