苯基铜

苯基铜
识别
CAS号 3220-49-3
PubChem 10997120
SMILES
 
  • c1ccc[cH-]c1.[Cu+]
性质
化学式 C6H5Cu
摩尔质量 140.65 g·mol−1
外观 灰绿色固体
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

苯基铜是一种金属有机化合物，化学式为C6H5Cu。[1]它最初于1923年被制得，为灰绿色晶体。

制备

它可由苯基溴化镁的乙醚溶液和碘化亚铜反应制得：

C6H5MgBr + CuI → C6H5Cu + MgBrI

性质

它于80 °C分解为铜和联苯；在水中缓慢水解：

2 C6H5Cu + H2O → Cu2O + 2 C6H6

它能够与三丁基膦或三苯基膦形成稳定配合物。[2]它在固态为低聚物，而其甲硫醚溶液为三聚体和四聚体的混合物。[3]

参考文献

  1. ^ Химическая энциклопедия 3. М.: Советская энциклопедия. Редкол.: Кнунянц И.Л. и др. 1992. ISBN 5-82270-039-8 请检查|isbn=值 (帮助) （俄语）. 
  2. ^ Georg Brauer (Hrsg.), unter Mitarbeit von Marianne Baudler u. a.: Handbuch der Präparativen Anorganischen Chemie. 3., umgearbeitete Auflage. Band I, Ferdinand Enke, Stuttgart 1975, ISBN 3-432-02328-6, S. 987.
  3. ^ Zvi Rappoport, Ilan Marek: The Chemistry of Organocopper Compounds. John Wiley & Sons, 2010, ISBN 978-0-470-77296-6, S. 152

Read other articles:

Fata Morgana (1965 film)

1965 Spanish filmFata MorganaDVD cover for 'Fata Morgana'Directed byVicente ArandaWritten byVicente ArandaGonzalo SuárezProduced byPalmiro ArandaAntonio RabinadStarringTeresa GimperaMarianne BenetCinematographyAurelio G. LarrayaEdited byEmilio RodríguezMusic byAntonio Pérez OleaDistributed byTroma EntertainmentRelease date 1965 (1965) Running time84 minutesCountrySpainLanguageSpanish Fata Morgana (also known as Left-Handed Fate) is a 1965 Spanish drama film directed by veteran filmmak...

 

Jenny Rachman

Jenny RachmanLahirJenny Rosjeni Rachman18 Januari 1959 (umur 65)Jakarta, IndonesiaAlmamaterUniversitas NasionalPekerjaanAktrispolitikusmodelTahun aktif1973—sekarangPartai politikPartai Demokrat (2014–sekarang)Suami/istri A. Hanafie (bercerai) Budi Prakoso ​(m. 1986⁠–⁠1994)​ Nitiyudo Wachjo (bercerai) Supradjarto ​(m. 2008)​ Anak2 Jenny Rosjeni Rachman (lahir 18 Januari 1959) adalah seorang pemeran, po...

 

Mary FitzAlan

Questa voce sull'argomento nobili britannici è solo un abbozzo. Contribuisci a migliorarla secondo le convenzioni di Wikipedia. Mary FitzAlan Mary FitzAlan, duchessa di Norfolk (Exeter, 1541[1] – Strand, 25 agosto 1557[2]), è stata una nobile britannica. Biografia Mary era la figlia più giovane di Henry FitzAlan, XIX conte di Arundel[3] e di sua moglie Katherine Grey[4]. Dopo la morte del loro fratello maschio, sia Mary che sua sorella Jane, divenner...

Priestly Blessing

Jewish blessing by Kohanim Priestly BlessingLarge crowds congregate on Passover at the Western Wall to receive the priestly blessingHalakhic texts relating to this articleTorah:Numbers 6:23–27Shulchan Aruch:Orach Chayim 128–130 The Priestly Blessing or priestly benediction (Hebrew: ברכת כהנים; translit. birkat kohanim), also known in rabbinic literature as raising of the hands (Hebrew nesiat kapayim),[1] rising to the platform (Hebrew aliyah ledukhan),[2] dukhenen...

 

大字 (数字)

この項目には、一部のコンピュータや閲覧ソフトで表示できない文字が含まれています（詳細）。 数字の大字（だいじ）は、漢数字の一種。通常用いる単純な字形の漢数字（小字）の代わりに同じ音の別の漢字を用いるものである。 概要 壱万円日本銀行券（「壱」が大字） 弐千円日本銀行券（「弐」が大字） 漢数字には「一」「二」「三」と続く小字と、「壱」「�...

 

Nazgûl

Disambiguazione – Nazgul rimanda qui. Se stai cercando il nome proprio femminile, vedi Nazgul (nome). Questa voce o sezione sugli argomenti Fantasy e personaggi letterari non cita le fonti necessarie o quelle presenti sono insufficienti. Puoi migliorare questa voce aggiungendo citazioni da fonti attendibili secondo le linee guida sull'uso delle fonti. Segui i suggerimenti dei progetti di riferimento 1, 2. I Nazgûl (o Úlairi)[1], gli Spettri dell'Anello (in inglese Ri...

Філософія

Частина серії проФілософіяLeft to right: Plato, Kant, Nietzsche, Buddha, Confucius, AverroesПлатонКантНіцшеБуддаКонфуційАверроес Філософи Епістемологи Естетики Етики Логіки Метафізики Соціально-політичні філософи Традиції Аналітична Арістотелівська Африканська Близькосхідна іранська Буддій�...

 

Section 125 of the Constitution Act, 1867

Provision of the Canadian Constitution Main article: Constitution Act, 1867 Proclamation bringing the Constitution Act into force, July 1, 1867 Constitution Act, 1867 Part of the Constitution of Canada PREAMBLE I. PRELIMINARY 1, 2 II. UNION 3, 4, 5, 6, 7, 8 III. EXECUTIVE POWER 9, 10, 11, 12, 13, 14, 15, 16 IV. LEGISLATIVE POWER 17, 18, 19, 20 The Senate 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36 The House of Commons 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, ...

 

Albenga

Comune in Liguria, ItalyAlbengaComuneComune di Albenga Coat of armsLocation of Albenga AlbengaLocation of Albenga in ItalyShow map of ItalyAlbengaAlbenga (Liguria)Show map of LiguriaCoordinates: 44°03′N 8°13′E / 44.050°N 8.217°E / 44.050; 8.217CountryItalyRegionLiguriaProvinceSavona (SV)FrazioniBastia, Campochiesa, Leca, Lusignano, Salea, San FedeleGovernment • MayorRiccardo TomatisArea[1] • Total36.51 km2 (14.10 sq...

Wilmington Park

Ballpark in Wilmington, Delaware Wilmington ParkLocationGovernor Printz Blvd & E 30th StWilmington, DE 19802Capacity7,000SurfaceGrassConstructionBroke ground1939OpenedMay 1, 1940Demolished1963Construction cost$185,000TenantsWilmington Clippers (AA) (1939–1941, 1946–1949)Wilmington Blue Rocks (InL) (1940–1952) Philadelphia Athletics (AL) (spring training) (1943) Philadelphia Phillies (NL) (spring training) (1944–1945)University of Delaware football (1940–1952) Wilmington Park was...

 

Ludwig Feuerbach and the End of Classical German Philosophy

This article needs additional citations for verification. Please help improve this article by adding citations to reliable sources. Unsourced material may be challenged and removed.Find sources: Ludwig Feuerbach and the End of Classical German Philosophy – news · newspapers · books · scholar · JSTOR (April 2024) (Learn how and when to remove this message) Ludwig Feuerbach and the End of Classical German Philosophy (German: Ludwig Feuerbach und der Ausg...

 

Canottieri Olona

Canottieri OlonaPallanuoto Segni distintiviUniformi di gara Colori sociali          Dati societariCittà Milano Paese Italia Confederazione- Federazione FIN Fondazione1894 Scioglimento1982 Rifondazione1987 Sito webhttp://www.olona1894.it/ Palmarès Scudetti1 Impianto sportivoDarsena di Milano La Canottieri Olona è una società polisportiva di Milano, vincitrice di un campionato italiano maschile di pallanuoto, plurititolata a livello mondiale ed e...

تريستان طومسون

تريستان طومسون معلومات شخصية الميلاد 13 مارس 1991 (العمر 33 سنة)تورونتو الطول 6 قدم 9 بوصة (2.1 م) مركز اللعب لاعب هجوم قوي الجسم،  ولاعب الوسط (كرة سلة)  الجنسية  كندا الوزن 108 كيلوغرام  عدد الأبناء 3   المدرسة الأم جامعة تكساس في أوستن[1]  الحياة العملية ال...

 

William Blake

William Blake ritratto da Thomas Philips nel 1807 William Blake (Londra, 28 novembre 1757 – Londra, 12 agosto 1827) è stato un poeta, pittore e incisore britannico. L'opera di Blake, largamente sottovalutata mentre egli era in vita, venne poi considerata estremamente significativa e fonte di ispirazione sia nell'ambito della poesia che in quello delle arti visive. Secondo Northrop Frye, che si dedicò allo studio dell'intero corpus poetico di Blake, i suoi versi simili a profezie costituis...

 

阿武火山群

阿武火山群の火山と溶岩の分布図 GIF版 座標: 北緯34度26分58秒 東経131度24分07秒 / 北緯34.44944度 東経131.40194度 / 34.44944; 131.40194[1]阿武火山群（あぶかざんぐん）は、山口県萩市にある独立単性火山群である。気象庁と火山噴火予知連絡会による2010年代に伴い、2003年（平成15年）に活火山に指定された。 およそ400km2の地域に約40の単成火山が点在する�...

Tirzah Garwood

English painter Tirzah GarwoodBornEileen Lucy Garwood(1908-04-11)11 April 1908Gillingham, EnglandDied27 March 1951(1951-03-27) (aged 42)Colchester, EnglandOccupation(s)Artist and engraverSpouseEric Ravilious Two Women in a Garden: Garwood (right) and Charlotte Bawden, by Eric Ravilious. Eileen Lucy Tirzah Garwood (11 April 1908 – 27 March 1951) was a British wood-engraver, painter, paper marbler, author, and a member of the Great Bardfield Artists. According to Brighton Hove museums, G...

 

Passionate and companionate love

Two types of love in romantic relationships Passionate love redirects here. For the South Korean TV series, see Passionate Love (TV series). Part of a series onLoveRed-outline heart icon Types of love Affection Bonding Broken heart Compassionate love Conjugal love Courtly love courtship troubadours Falling in love Friendship cross-sex romantic zone Interpersonal attraction Interpersonal relationship Intimacy Limerence Love addiction Love at first sight Love triangle Lovesickness Lovestruck Pa...

 

Modi (blok Unicode)

Artikel ini sebatang kara, artinya tidak ada artikel lain yang memiliki pranala balik ke halaman ini.Bantulah menambah pranala ke artikel ini dari artikel yang berhubungan atau coba peralatan pencari pranala.Tag ini diberikan pada April 2016. ModiJangkauanU+11600..U+1165F(96 titik kode)BidangSMPAksaraModiAksara utamaAbjad ModiTerpakai79 titik kodeTak terpakai17 titik kode kosongRiwayat versi Unicode7.079 (+79) Catatan: [1][2] Modi adalah blok Unicode yang mengandung karakter a...

André Brink

André Philippus Brink André Philippus Brink (Vrede, 29 maggio 1935 – Città del Capo, 6 febbraio 2015) è stato uno scrittore sudafricano autore sia in lingua inglese sia in lingua afrikaans e professore universitario a Città del Capo, città dove risiedeva. È noto soprattutto per l'intensa attività letteraria negli anni sessanta, che l'ha portato a essere assieme al più noto scrittore e pittore Breyten Breytenbach, la figura chiave del movimento Sestigers, del quale facevano parte au...

 

Ruaidrí Ua Conchobair

High King of Ireland (c. 1116 – 1198) This article includes a list of general references, but it lacks sufficient corresponding inline citations. Please help to improve this article by introducing more precise citations. (November 2010) (Learn how and when to remove this message) Ruaidrí Ua ConchobairStone carving, Cong AbbeyHigh King of IrelandReign1166 – 1198PredecessorMuirchertach Mac LochlainnSuccessorBrian Ua Néill (disputed)Bornc. 1116Tuam, Kingdom of ConnachtDied2 Dece...