Prawo Avogadra

Prawo Avogadra (znane też jako hipoteza Avogadra) – prawo fizyki sformułowane przez Amadea Avogadra, które brzmi[1]:

W tych samych warunkach fizycznych tj. w takiej samej temperaturze i pod takim samym ciśnieniem, w równych objętościach różnych gazów znajduje się taka sama liczba cząsteczek.

W warunkach normalnych jeden mol gazu doskonałego zajmuje objętość 22,415 dm³ (jest to jego objętość molowa). Dla gazów rzeczywistych objętość ta nieco się różni[2].

Prawo Avogadra jest prawem przybliżonym, którego zakres stosowalności zależy od podobieństwa porównywanych gazów rzeczywistych do gazu doskonałego. Prawo Avogadra można wyprowadzić wykorzystując równanie Clapeyrona.

Przypisy

  1. Avogadra prawo, [w:] Encyklopedia PWN [online], Wydawnictwo Naukowe PWN [dostęp 2021-12-20].
  2. objętość molowa, [w:] Encyklopedia techniki. Chemia, Władysław Gajewski (red.), Warszawa: Wydawnictwa Naukowo-Techniczne, 1965, s. 471–472, OCLC 33835352.

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