Template:Infobox lead

Lead, 82Pb
A small gray metal cube surrounded by three gray metal nuggets in front of a light gray background
Lead
Pronunciation/lɛd/ (led)
Appearancemetallic gray
Standard atomic weight Ar°(Pb)
Lead in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
Sn

Pb

Fl
thalliumleadbismuth
Atomic number (Z)82
Groupgroup 14 (carbon group)
Periodperiod 6
Block  p-block
Electron configuration[Xe] 4f14 5d10 6s2 6p2
Electrons per shell2, 8, 18, 32, 18, 4
Physical properties
Phase at STPsolid
Melting point600.61 K ​(327.46 °C, ​621.43 °F)
Boiling point2022 K ​(1749 °C, ​3180 °F)
Density (at 20 °C)11.348 g/cm3[3]
when liquid (at m.p.)10.66 g/cm3
Heat of fusion4.77 kJ/mol
Heat of vaporization179.5 kJ/mol
Molar heat capacity26.650 J/(mol·K)
Specific heat capacity128.62 J/(kg·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 978 1088 1229 1412 1660 2027
Atomic properties
Oxidation statescommon: +2, +4
−4,[10] −2,[4] −1,[5] 0,[6] +1,[7] +3[8][9]
ElectronegativityPauling scale: 2.33 (in +4), 1.87 (in +2)
Ionization energies
  • 1st: 715.6 kJ/mol
  • 2nd: 1450.5 kJ/mol
  • 3rd: 3081.5 kJ/mol
Atomic radiusempirical: 175 pm
Covalent radius146±5 pm
Van der Waals radius202 pm
Color lines in a spectral range
Spectral lines of lead
Other properties
Natural occurrenceprimordial
Crystal structureface-centered cubic (fcc) (cF4)
Lattice constant
Face-centered cubic crystal structure for lead
a = 494.99 pm (at 20 °C)[3]
Thermal expansion28.73×10−6/K (at 20 °C)[3]
Thermal conductivity35.3 W/(m⋅K)
Electrical resistivity208 nΩ⋅m (at 20 °C)
Magnetic orderingdiamagnetic
Molar magnetic susceptibility−23.0×10−6 cm3/mol (at 298 K)[11]
Young's modulus16 GPa
Shear modulus5.6 GPa
Bulk modulus46 GPa
Speed of sound thin rod1190 m/s (at r.t.) (annealed)
Poisson ratio0.44
Mohs hardness1.5
Brinell hardness38–50 MPa
CAS Number7439-92-1
History
Namingpossibly from a PIE root meaning “to flow”, for its low melting point
DiscoveryMiddle East (7000 BCE)
Symbol"Pb": from Latin plumbum
Isotopes of lead
Main isotopes[12] Decay
Isotope abun­dance half-life (t1/2) mode pro­duct
202Pb synth 5.25×104 y ε 202Tl
204Pb 1.40% stable
205Pb synth 1.70×107 y ε 205Tl
206Pb 24.1% stable
207Pb 22.1% stable
208Pb 52.4% stable
209Pb trace 3.235 h β 209Bi
210Pb trace 22.2 y β 210Bi
α 206Hg
211Pb trace 36.16 min β 211Bi
212Pb trace 10.627 h β 212Bi
214Pb trace 27.06 min β 214Bi
Isotopic abundances vary greatly by sample[1]
 Category: Lead
| references
Pb · Lead
Tl ←

ibox Tl

iso
82
Pb  [e]
IB-Pb [e]
IBisos [e]
→ Bi

ibox Bi

indexes by PT (page)
child table, as reused in {IB-Pb}
Main isotopes of lead
Main isotopes[12] Decay
Isotope abun­dance half-life (t1/2) mode pro­duct
202Pb synth 5.25×104 y ε 202Tl
204Pb 1.40% stable
205Pb synth 1.70×107 y ε 205Tl
206Pb 24.1% stable
207Pb 22.1% stable
208Pb 52.4% stable
209Pb trace 3.235 h β 209Bi
210Pb trace 22.2 y β 210Bi
α 206Hg
211Pb trace 36.16 min β 211Bi
212Pb trace 10.627 h β 212Bi
214Pb trace 27.06 min β 214Bi
Isotopic abundances vary greatly by sample[1]
Data sets read by {{Infobox element}}
Name and identifiers
Symbol etymology (11 non-trivial)
Top image (caption, alt) caption:
alt:
Pronunciation
Allotropes (overview)
Group (overview)
Period (overview)
Block (overview)
Natural occurrence
Phase at STP
Oxidation states
Spectral lines image
Electron configuration (cmt, ref)
Isotopes
Standard atomic weight
  most stable isotope
Wikidata
Wikidata *
* Not used in {{Infobox element}} (2023-01-01)
See also {{Index of data sets}} · Cat:data sets (45) · (this table: )

References

  1. ^ a b c "Standard Atomic Weights: Lead". CIAAW. 2020.
  2. ^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
  3. ^ a b c Arblaster, John W. (2018). Selected Values of the Crystallographic Properties of Elements. Materials Park, Ohio: ASM International. ISBN 978-1-62708-155-9.
  4. ^ Pb(−2) has been observed in BaPb, see Ferro, Riccardo (2008). Nicholas C. Norman (ed.). Intermetallic Chemistry. Elsevier. p. 505. ISBN 978-0-08-044099-6. and Todorov, Iliya; Sevov, Slavi C. (2004). "Heavy-Metal Aromatic Rings: Cyclopentadienyl Anion Analogues Sn56− and Pb56− in the Zintl Phases Na8BaPb6, Na8BaSn6, and Na8EuSn6". Inorganic Chemistry. 43 (20): 6490–94. doi:10.1021/ic000333x.
  5. ^ Pb(−1) has been observed in CsPb, see Hewaidy, I. F.; Busmann, E.; Klemm, W. (1964). "Die Struktur der AB-Verbindungen der schweren Alkalimetalle mit Zinn und Blei". Zeitschrift für anorganische und allgemeine Chemie (in German). 328 (5–6): 283–293. doi:10.1002/zaac.19643280511.
  6. ^ Pb(0) carbonyls have been observed in reaction between lead atoms and carbon monoxide; see Ling, Jiang; Qiang, Xu (2005). "Observation of the lead carbonyls PbnCO (n=1–4): Reactions of lead atoms and small clusters with carbon monoxide in solid argon". The Journal of Chemical Physics. 122 (3) 34505. Bibcode:2005JChPh.122c4505J. doi:10.1063/1.1834915. ISSN 0021-9606. PMID 15740207. Also, Pb(0) has been observed in [SiII(Xant)SiII]PbFe(CO)4; see Jian Xu; Sudip Pan; Shenglai Yao; Gernot Frenking; Matthias Driess (2022). "The Heaviest Bottleable Metallylone: Synthesis of a Monatomic, Zero-Valent Lead Complex ("Plumbylone")". Angewandte Chemie International Edition. 61 (38) e202209442. doi:10.1002/anie.202209442. PMC 9545849. PMID 35848899.
  7. ^ Siew-Peng Chia; Hong-Wei Xi; Yongxin Li; Kok Hwa Lim; Cheuk-Wai So (2013). "A Base-Stabilized Lead(I) Dimer and an Aromatic Plumbylidenide Anion". Angew. Chem. Int. Ed. 52 (24): 6298–6301. doi:10.1002/anie.201301954. PMID 23629949.
  8. ^ Becker, M.; Förster, C.; Franzen, C.; et al. (2008). "Persistent radicals of trivalent tin and lead". Inorganic Chemistry. 47 (21): 9965–78. doi:10.1021/ic801198p. PMID 18823115.
  9. ^ Mosseri, S.; Henglein, A.; Janata, E. (1990). "Trivalent lead as an intermediate in the oxidation of lead(II) and the reduction of lead(IV) species". Journal of Physical Chemistry. 94 (6): 2722–26. Bibcode:1990JPhCh..94.2722M. doi:10.1021/j100369a089.
  10. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 28. doi:10.1016/C2009-0-30414-6. ISBN 978-0-08-037941-8.
  11. ^ Weast, Astle & Beyer 1983, p. E110.
  12. ^ a b Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3) 030001. doi:10.1088/1674-1137/abddae.

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