Fluorid platiničný

Fluorid platiničný
Struktura pevného fluoridu platiničného
Struktura pevného fluoridu platiničného
Obecné
Systematický názevFluorid platiničný
Anglický názevPlatinum pentafluoride
Německý názevPlatin(V)-fluorid
Sumární vzorecPtF5
Vzhledčervená pevná látka
Identifikace
Registrační číslo CAS13782-84-8
SMILESF[Pt](F)(F)(F)F
Vlastnosti
Molární hmotnost290,07 g/mol
Teplota tání75–76 °C
Teplota varu300–305 °C
Není-li uvedeno jinak, jsou použity
jednotky SI a STP (25 °C, 100 kPa).
Některá data mohou pocházet z datové položky.

Fluorid platiničný je chemická sloučenina se vzorcem PtF5. Poprvé byl připraven fluorací chloridu platnatého při teplotě nad 350 °C,[1] při kontaktu s vodou hydrolyzuje.[1]

Jeho struktura se skládá z tetramerních útvarů, které jsou velmi podobné fluoridu rutheničnému. V těchto tetramerech má každý atom platiny oktaedrickou konfiguraci, oktaedry jsou propojeny přes vrcholy.[2]

Odkazy

Reference

V tomto článku byl použit překlad textu z článku Platinum pentafluoride na anglické Wikipedii.

  1. ↑ a b Proceedings of the Chemical Society. January 1960. Proceedings of the Chemical Society. 1960, čís. January, s. 1. Dostupné online [cit. 2019-09-27]. ISSN 0369-8718. DOI 10.1039/ps9600000001. (anglicky) 
  2. ↑ MUELLER, B. G.; SERAFIN, M. ChemInform Abstract: Single-Crystal Investigations on PtF4 and PtF5.. ChemInform. 2010-08-21, roč. 23, čís. 45, s. no–no. Dostupné online [cit. 2019-09-27]. DOI 10.1002/chin.199245006. (anglicky) 
Fluoridy s prvkem v oxidačním čísle V.
Fluorid arseničný (AsF5) • Fluorid zlatičný (Au2F10) • Fluorid bismutičný (BiF5) • Fluorid bromičný (BrF5) • Fluorid chlorečný (ClF5) • Fluorid chromičný (CrF5) • Fluorid jodičný (IF5) • Fluorid iridičný (IrF5) • Fluorid manganičný (MnF5) • Fluorid molybdeničný (MoF5) • Fluorid dusičný (NF5) • Fluorid niobičný (NbF5) • Fluorid neptuničný (NpF5) • Fluorid osmičný (OsF5) • Fluorid fosforečný (PF5) • Fluorid protaktiničný (PaF5) • Fluorid platiničný (PtF5) • Fluorid plutoničný (PuF5) • Fluorid rheničný (ReF5) • Fluorid rhodičný (RhF5) • Fluorid rutheničný (RuF5) • Dekafluorid disíry (S2F10) • Fluorid antimoničný (SbF5) • Fluorid tantaličný (TaF5) • Fluorid technecičný (TcF5) • Fluorid uraničný (U2F10) • Fluorid vanadičný (VF5) • Fluorid wolframičný (WF5)

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