Carbonate oxalate

The carbonate oxalates are mixed anion compounds that contain both carbonate (CO3) and oxalate (C2O4) anions. Most compounds incorporate large trivalent metal ions, such as the rare earth elements. Some carbonate oxalate compounds of variable composition are formed by heating oxalates.[1]

Formation

One method to form carbonate oxalates is to heat a metal salt with ascorbic acid, which decomposes to oxalate and carbonate and combines with the metal.[2]

Reactions

When heated, oxalate carbonates decompose to carbon monoxide and carbonates, which form oxides at higher temperatures.[2]

List

formula name formula weight crystal form space group unit cell Å volume Å3 density properties references
Sc [3]
K4Ti2O2(C2O4)3·CO3 [4]
[Co*(C2O4)(CO3)]2− anionic complex [5]
[CoIII(CO3)(C2O4)(NH3)2]- anionic complex [6]
Sr[TiO(C2O4)CO3] [7]
[Y(H2O)]2(C2O4)(CO3)2 yttrium oxalate carbonate 421.876 orthorhombic C2221 a = 7.8177, b = 14.943, c = 9.4845, Z = 4 1108.0 2.526 [8]
Ba[ZrO(C2O4)(CO3)] [9]
[Ce(H2O)]2[(C2O4)2(CO3)]·2.5H2O triclinic P1_ a 6.329 b 8.743 c 13.000, α 105.61° β 90.55° γ 105.10° [10]
Pr4(C2O4)4(CO3)2]·3H2O catena(bis(μ4-Oxalato)-(μ3-oxalato)-(μ2-oxalato)-bis(μ6-carbonato)-bis(μ2-aqua)-diaqua-tetra-praseodymium hydrate) triclinic P1_ a 6.298 b 8.673 c 12.970, α 105.42° β 90.55° γ 105.01° [11]
Pr2(C2O4)(CO3)2 [12]
Nd4(C2O4)4(CO3)2]·3H2O catena-[bis(μ4-Oxalato)-(μ3-oxalato)-(μ2-oxalato)-bis(μ6-carbonato)-bis(μ2-aqua)-diaqua-tetra-neodymium hydrate] triclinic P1_ a 6.273(6)Å b 8.616(7)Å c 12.928(9)Å, α 105.50(6)° β 90.52(7)° γ 105.00(6)° [11]
(NH4)2[Nd2(CO3)(C2O4)3(H2O)]·H2O diammonium aqua—carbonato-tri—oxalato-dineodymium(III) hydrate triclinic P1_ a=8.706 b=9.530 c=10.327 α = 73.35° β = 86.90° γ = 80.50° Z=2 809.69 2.808 [13]
Eu4(C2O4)4(CO3)2·3H2O catena(bis(μ4-Oxalato)-(μ3-oxalato)-(μ2-oxalato)-bis(μ6-carbonato)-bis(μ2-aqua)-diaqua-tetra-europium hydrate) triclinic P1_ a 6.179 b 8.464 c 12.856, α 105.13° β 90.46° γ 104.86° [11]
[Eu(H2O)]2(C2O4)(CO3)2 [14]
[Gd(H2O)]2(C2O4)(CO3)2 [14]
[Tb(H2O)]2(C2O4)(CO3)2 [14]
[Dy(H2O)]2(C2O4)(CO3)2 [14]
[Ho(H2O)]2(C2O4)(CO3)2 [14]
Er2(CO3)2(C2O4)(H2O)2 monoclinic Cm a = 7.773, b = 14.920, c = 4.7309, β = 90.12° Z = 2 [15]
Pb[ZrО(C2O4)CO3]
Pb4(CO3)2(C2O4)(OH)2 535.41 monoclinic P21/c a=11.8593 b=5.2486 c=9.0997 β =96.669 Z=4 562.58 6.321 colourless [16]
(NH4)4[Th(CO3)2(C2O4)2]•0.5Н2O [17]
(NH4)4[Th(CO3)2(C2O4)2]•10Н2O [17]
(CN3H6)3(NH4)[Th(CO3)2(C2O4)2]•3Н2O [17]
(CN3H6)3(NH4)[Th(CO3)3(C2O4)]•1.5Н2O [17]
(CN3H6)3(NH4)[Th(CO3)3(C2O4)]•3Н2O [17]
(CN3H6)6[Th2(CO3)5(C2O4)] hexaguandinium pentacarbonatooxalato dithorium [18]
(CN3H6)6[Th2(CO3)5(C2O4)2]•4Н2O [17]
(CN3H6)6[Th2(CO3)5(C2O4)2]•8Н2O [17]
(CN3H6)6[Th2(CO3)4(C2O4)3]•14Н2O [17]
(CN3H6)8[Th2(CO3)7(C2O4)] [17]
(CN3H6)8[Th2(CO3)7(C2O4)]•5Н2O [17]
(CN3H6)8[Th2(CO3)7(C2O4)]•6Н2O [17]
(CN3H6)8[Th2(CO3)5(C2O4)3]•Н2O [17]
(CN3H6)10[Th2(CO3)8(C2O4)]•8Н2O [17]
Na4[Th2(OH)2(CO3)4(C2O4)]•4Н2O [17]
Na4[Th2(OH)6(CO3)2(C2O4)]•2Н2O [17]
Na8Th(C2O4)2(CO3)4 •11Н2O [19]
Na8[Th(CO3)5(C2O4)]•11Н2O [17]
Na10[Th(CO3)5(C2O4)2]•11Н2O [17]
Na10[Th(CO3)5(C2O4)2]•16Н2O [17]
Na10[Th(OH)2(CO3)3(C2O4)3]•8Н2O [17]
Na10[Th(OH)2(CO3)3(C2O4)3] [17]
Na12[Th(CO3)6(C2O4)2]•11Н2O [17]
K2[Th2(OH)2(CO3)3(C2O4)]•2Н2O [17]
K2[Th2(OH)2(CO3)3(C2O4)] [17]
K4[Th(CO3)3(C2O4)]•6Н2O [17]
K5[Th2(OH)(CO3)4(C2O4)2]•2Н2O [17]
K6[Th(CO3)4(C2O4)]•8Н2O [17]
K6[Th(CO3)3(C2O4)2]•4Н2O [17]
K6[Th2(CO3)5(C2O4)2]•2Н2O [17]
K6[Th2(CO3)4(C2O4)3]•6Н2O [17]
K8[Th2(CO3)5(C2O4)3]•13Н2O [17]
K8[Th2(CO3)5(C2O4)3]•16Н2O [17]
K10[Th2(CO3)7(C2O4)2]•8Н2O [17]
K10[Th2(CO3)7(C2O4)2]•12Н2O [17]
K10[Th2(CO3)7(C2O4)2]•14Н2O [17]
K10[Th2(CO3)5(C2O4)4]•5Н2O [17]
K10[Th2(CO3)5(C2O4)4]•7Н2O [17]
(NH4)(CN3H6)3[(UO2)2(CO3)(C2O4)2(C3H4N2O2)] · H2O [20]
(CN3H6)4[(UO2)2(CO3)(C2O4)2(C5H8N2O2)] · 1.5H2O guanidonium μ-carbonate μ-ethylmethylgyoximatedioxylatediuranylate sesquihydrate monoclinic P21 a=6.909 b=15.794 c=30.064 β=96.720° Z=4 3258 2.383 red plates [20][21]
(CN3H6)4[(UO2)2(CO3)(C2O4)2(C6H8N2O2)] · 3H2O [20]
(NH4)(CN3H6)4[(UO2)2(CO3)(C2O4)2(C6H4N2O2)] · H2O [20]
(CN3H6)4[(UO2)2(C6H8N2O2)(CO3)(C2O4)2] · (C6H10N2O2) · 2H2O guanidinium (3-methyl-1,2-cyclopenadionedioxime)dioxalato (μ-3-methyl-1,2-cyclopenadionedioxato) μ-carbonatodiuranylate dihydrate triclinic P1_ a=9.2474 b=14.8562 c=16.8917 α = 68.504° β = 77.721° γ = 89.792° Z=2 2102.7 2.108 red [22]
(CN3H6)4[(UO2)2(CO3)(C2O4)2(C7H10N2O2)] · H2O [20]
NH4(CN3H6)3[(UO2)2(C7H10N2O2)(CO3)(C2O4)2] · 2H2O ammonium guanidinium dioxalato (μ-3-methyl-1,2-cyclopenadionedioxato) μ-carbonatodiuranylate dihydrate orthorhombic P212121 a=9.904 b=17.400 c=18.757 Z=4 3232.2 2.393 red [22]
(CN3H6)4[(UO2)2(CO3)(C2O4)2(C6H10N2O2)] · H2O guanidinium dioxalato μ-diethylglyoximato μ-carbonatodiuranylate monohydrate 1176.59 monoclinic P21/n a=7.6140 b=15.4388 c=28.010 β=95.99° Z=4 3274.6 2.387 orange [23]
(CN3H6)2(C2H2N2)[(UO2)2(CO3)(C2O4)2(C6H10N2O2)] · 3H2O guanidinium ethylenediammonium dioxalato μ-diethylglyoximato μ-carbonatodiuranylate monohydrate orange [23]
[C(NH2)3]10[(UO2)6(μ3-O)2(μ2-OH)2(C2O4)4(CO3)4]· 2H2O 2913.21 triclinic P1_ a=11.5919 b=11.7868 c=13.3545 α = 102.637° β = 93.278° γ = 95.273° Z=1 1759.7 2.749 yellow [24]
Pu Plutonium(III) oxalate carbonate [25]

References

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Dewan Perwakilan RakyatKota Langsa DPRK Langsa2019-2024JenisJenisUnikameral Jangka waktu5 tahunSejarahSesi baru dimulai2 September 2019PimpinanKetuaZulkifli Latief (PA) sejak 30 Desember 2019 Wakil Ketua ISaifullah (Golkar) sejak 28 Oktober 2019 Wakil Ketua IIIr. Joni (Demokrat) sejak 28 Oktober 2019 KomposisiAnggota25Partai & kursi  PDI-P (1)   NasDem (1)   Hanura (3)   Demokrat (4)   Golkar (4)   Gerindra (3)  ...

 

 

Mammalian protein found in Homo sapiens ABCB1IdentifiersAliasesABCB1, ABC20, CD243, CLCS, GP170, MDR1, P-GP, PGY1, ATP binding cassette subfamily B member 1, P-glycoprotein, P-gp, PgpExternal IDsOMIM: 171050 MGI: 97570 HomoloGene: 55496 GeneCards: ABCB1 Gene location (Mouse)Chr.Chromosome 5 (mouse)[1]Band5 A1|5 3.43 cMStart8,710,077 bp[1]End8,798,575 bp[1]RNA expression patternBgeeHumanMouse (ortholog)n/aTop expressed inleft colonirisPaneth celljejunumcrypt of lie...

Municipal unit in Dibër, AlbaniaBazMunicipal unitBazCoordinates: 41°38′N 19°56′E / 41.633°N 19.933°E / 41.633; 19.933Country AlbaniaCountyDibërMunicipalityMatPopulation (2011) • Municipal unit2,228Time zoneUTC+1 (CET) • Summer (DST)UTC+2 (CEST) Baz is a village and a former municipality in the Dibër County, northern Albania. At the 2015 local government reform it became a subdivision of the municipality Mat.[1] The p...

 

 

Laws regarding homosexuality in Asia Same-sex sexual activity legal   Marriage performed   Marriage recognized   Other type of partnership   Legislation or binding domestic court ruling establishing same-sex marriage, but no supporting legislation has been passed   Legal guardianships or unregistered cohabitation   Limited foreign recognition (residency rights)   No recognition of same-sex couples   Restrictions ...

 

 

Le xylène, ou diméthylbenzène, est un groupe d'hydrocarbures aromatiques dérivés méthylés du benzène. Il est représenté par trois isomères structuraux : 1,2-diméthylbenzène, 1,3-diméthylbenzène et 1,4-diméthylbenzène (appelés respectivement ortho-diméthylbenzène, méta-diméthylbenzène et para-diméthylbenzène). Le xylène technique est un mélange des trois isomères, de composition voisine de méta- (60 %), ortho- (10-25 %) et para- (10-25 %). Struc...

Ecumenical Christian organization World Reformed FellowshipTypeFellowshipClassificationProtestantOrientationConfessionally ReformedOrigin2000; 24 years ago (2000)Members7,281,267Official websitewww.wrf.global The World Reformed Fellowship (WRF) is an ecumenical, Christian fellowship that advances partnerships among confessional Reformed churches around the world.[1] History The World Fellowship of Reformed Churches was formed in 1994 by the Presbyterian Church in Ame...

 

 

Försvarsmaktens logistik(FMLOG) Vapen för Försvarsmaktens logistik tolkat efter dess blasonering.InformationOfficiellt namnFörsvarsmaktens logistikDatum2002–LandSverigeFörsvarsgrenFörsvarsmaktsgemensamtTypLogistikförbandRollMilitärlogistikDel avHögkvarteretFöregångareNorra underhållsregementet,Mellersta underhållsregementet,Södra underhållsregementet,Underhållsgrupp Gotland,Försvarsmaktens Flygverkstäder,Örlogsvarvet Muskö,FMV Resmat,Militära servicekontoret,F...

 

 

This article currently links to a large number of disambiguation pages (or back to itself). Please help direct these ambiguous links to articles dealing with the specific meaning intended. Read the FAQ. (June 2024) 64th season of the EFL Cup Football tournament season 2024–25 EFL CupCarabao CupWembley Stadium hosted the finalTournament detailsCountryEnglandWalesDates13 August 2024 – 16 March 2025[1]Teams92Defending championsLiverpool← 2023–242025–26 → The...

Skagabyggð SkagabyggðMunisipalitasNegara IslandiaRegionNorðurland vestraLuas • Total488,59 km2 (18,865 sq mi)Populasi (2017) • Total93 • Kepadatan0,0.019/km2 (0,0.049/sq mi)LAU5611 Skagabyggð adalah salah satu munisipalitas di Islandia yang menjadi bagian region Norðurland vestra. Kode LAU munisipalitas ini adalah 5611. Menurut sensus 2017, jumlah penduduk munisipalitas yang luasnya 488,59 kilometer persegi ini adalah 93 j...

 

 

Men's 15 kilometre classicalat the XIX Olympic Winter GamesVenueSoldier HollowDates12 FebruaryCompetitors67 from 26 nationsWinning time37:07.4Medalists Andrus Veerpalu Estonia Frode Estil Norway Jaak Mae Estonia← 19882006 → Cross-country skiing at the2002 Winter OlympicsDistance10 kmwomen15 kmmenwomenPursuitmenwomen30 kmmenwomen50 kmmenRelaymenwomenSprintSprintmenwomenvte The men's 15 kilometre classical cross-country skiing competition at the 2...