Oxalate nitrate

An oxalate nitrate is a chemical compound or salt that contains oxalate and nitrate anions (NO3- and C2O42-). These are mixed anion compounds. Some have third anions. Oxalate acts as a ligand, which normally complexes two metal atoms.

Naming

An oxalate nitrate compound may also be called a nitrate oxalate. In chemical formulae, oxalate may be indicated by "ox". As a ligand oxalate is termed "oxalato", and nitrate, "nitrato".

Production

Most oxalate nitrates are formed by crystallisation from water solutions. One issue is the insolubility of metal oxalates.

Properties

On heating, oxalate nitrates lose NO2, NO, CO, and CO2 and form metal carbonates or oxides.

Related to these are the oxalate phosphates and oxalate perchlorates.

List

name formula ratio

C2O4:NO3

mw system space group unit cell Å volume density properties references
phen = 1,10-phenanthroline [Cr(phen)2(C2O4)]NO3·H2C2O4·H2O monoclinic Cc a=15.856 b=14.353 c=13.141 β=106.517° Z=4 2867 1.553 orange [1]
bpy = 2,2′-bipyridine [Cr(bpy)2(C2O4)]NO3·1/2H2C2O4·4H2O monoclinic P21/c a=10.5565 b=17.1770 c=14.8525 β=99.272° Z=4 2658.00 1.578 orange [1]
fac-triammin-aquo-oxalato-cobalt(III)-nitrate monohydrate, fac-[Co(NH3)3(C2O4)(H2O)]NO3·H2O monoclinic P21/n a=7.853 b=10.000 c=13.192 β=105.06° [2]
[Co(NH3)4(C2O4)]NO3·H2O P212121 a=7.944 b=9.90 c=12.700 Z=4 999.15 1.968
Oxalato di(1,10-phenanthroline-N,N′) cobalt(III) nitrate 3.88 hydrate [Co(C12H8N2)2(C2O4)]NO3·3.88H2O 639.14 orthorhombic Ibca a = 15.492 b = 17.938 c = 19.635 Z = 8 5457 1.556 pink [3]
ept = N-(2-aminoethyl)-1,3-diaminopropane [(Ni(ept)H2O)2ox](NO3)2 [4]
Ni2en4(C2O4)(NO3)2 [5]
bpy = 2,2′-bipyridine [{Ni(bpy)2}2(μ-C2O4)](NO3)2·H2C2O4 1044.23 triclinic P1 a 9.2921 b 12.8702 c 18.9812 α 84.660° β 75.969° γ 85.056° Z=2 2187.9 1.585 violet [6]
m-xpt = bis(pyridyltriazole) ligand [Ni2(m-xpt)2(C2O4)](NO3)2 [7]
dien = diethylenetriamine (H3dien)[Ni(NO3)(C2O4)2].2H2O monoclinic P21/c a=10.218 b=11.074 c=14.897 β=103.988° blue [8]
bpt = pyridyltriazole ligand Cu2(bpt)2(NO3)2(DMF)2(C2O4) [7]
[(Cu(ept))2ox](NO3)2·H2O [4]
Diethylenetriammonium nitrato-bis(oxalato)cuprate (II) dihydrate (H3dien)[Cu(NO3)(C2O4)2].2H2O monoclinic P21/c a = 10.1054 b = 11.0825 c = 14.8238 β = 103.516° Z = 4 1614.2 [9]
dien=diethylenetriamine [Cu2(C2O4)(dien)2](NO3)3 monoclinic P2/c a = 23.7888(10), b = 6.7055(3), c = 12.7842(6) and β = 95.534 [10]
Sparteine copper(II) nitrate oxalate Cu2(C15H26N2)2(NO3)2(C2O4) 1:2 light green [11]
di-2-pyridylamine Cu2(dpyam)2(μ-C2O4)(NO3)2(DMF)2 triclinic P1 a=8.353 b=9.100 c=12.245 α=72.035° β=75.228° γ=78.552° [12]
(μ2-oxalato)-bis(di-2-pyridylamine)-bis(N,N',-dimethylformamide)-di-copper(ii) iodide nitrate [Cu2(dpyam)2(μ-C2O4)(DMF)2](I)1.6(NO3)0.4 triclinic P1 a=8.4616 b=8.9112 c=12.3824 α=71.913° β=76.329° γ=80.225° [13]
Cu2(dpyam)2(C2O4)(NO3)2((CH3)2SO)2] [14]
Cu2(bpy)2(C2O4)(NO3)2(H2O)2 [14]
meprizole=(4-methoxy-2-(5-methoxy-3-methylo-pyrazol-1-yl)-6-methylpyrmadine) [Cu2(mepirizole)2(C2O4)(NO3)2(H2O)]2[Cu2(mepirizole)2(C2O4)(NO3)2] monoclinic P21/c a=20.073 b=13.842 c=11.451 β=119.09° Z=4 [15]
Cu2(histamine)2(C2O4)(H2O)2(NO3)2 triclinic P1 a=7.579 b=8.133 c=9.161 α=77.06° β=89.23° γ=82.54° Z=1 545.6 [16]
[Cu2(bpy)2(C2O4)(H2O)2][Cu(bpy)(C2O4)](NO3)2 [17]
trimeen = N,N,N'-trimethylethylenediamine [(Cu(trimeen)H2O)2ox](NO3)2 ·2H2O [18]
Pz2CPh2 = diphenyldipyrazolylmethane Cu2(Pz2CPh2)2(NO3)2(μ-C2O4) triclinic P1 a = 8.863 b = 10.241 c = 11.43 α = 98.98° β = 110.45° γ = 103.66° Z=2 [19]
Pz3m2CPh2 = diphenylbis(3-methylpyrazolyl)methane [Cu2(Pz3m2CPh2)2(H2O)2(μ-C2O4)](NO3)2·H2O monoclinic C2/c a = 23.459 b = 8.8568 c = 21.782 β = 100.889° Z=4 [19]
phen = 1,10-phenanthroline; (μ2-Oxalato-O,O',O'',O''')-diaqua-bis(1,10-phenanthroline)-di-copper(ii) dinitrate [Cu2(ox)(phen)2(H2O)2](NO3)2 monoclinic P21/n a=7.128 b=11.715 c=16.529 β=91.80° [20]
4,4’-bipyridine; 1,10-phenanthroline; [Cu2(ox)(4,4’-bpy)(phen)2](NO3)2 855.72 monoclinic C2/c a=23.144 b=10.6601 c=13.4363 β=93.123° Z=4 3310.4 green [21]
Bipy = 2,2′-bipyridine; Cu2(Bipy)2(H2O)2(C2O4)(NO3)2 [22]
μ-oxalato-κ4O1,O2:O1′,O2′-bis(aqua(nitrato-κO){[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II)) μ-oxalato-κ4O1,O2:O1′,O2′-bis((methanol-κO)(nitrato-κO){[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II)) [Cu2(C2O4)(NO3)2(C7H9N3)2(H2O)2][Cu2(C2O4)(NO3)2(C7H9N3)2(CH4O)2] triclinic P1 a = 9.8358 b = 12.377 c = 12.714 α = 103.704° β = 112.573° γ = 107.821° Z = 1 1245.15 [23]
(μ2-oxalato)-bis(dimethylsulfoxido)-bis(di-2-pyridylamine)-dinitrato-di-copper(ii) [Cu2(dpyam)2(C2O4)(NO3)2((CH3)2SO)2 triclinic P1 a 8.7190 b 8.9680 c 11.421 α 68.58° β 77.79° γ 80.58° [24]
(μ2-Oxalato-O,O',O'',O''')-diaqua-bis(2,3-bis(2-pyridyl)pyrazine)-di-copper(ii) dinitrate tetrahydrate [Cu2(dpp)2(H2O)2(NO3)2(ox)]·4H2O monoclinic P21/c a=9.704b=7.2598 c=25.865 β=97.395° [25]
L=4,4′-methylenebis(1-(2-pyridyl)-3,5-dimethylpyrazole;

(μ2-4,4'-Methylenebis(1-(2-pyridyl)-3,5-dimethylpyrazole))-bis(nitrato-O)-di-copper acetonitrile solvate

CuL(C2O4)(NO3) monoclinic P2/n a=8.5679 b=9.3862 c=20.5910 β=101.038° [26]
bis(μ2-oxalato)-tetrakis(2,2'-bipyridine)-(oxalato)-di-copper(ii)-chromium(iii) nitrate monohydrate [{Cu(μ-C2O4)(bpy)2}2Cr(C2O4)]NO3·H2O monoclinic C2/c a=6.428 b=17.162 c=16.749 β=110.721° [27]
bis(tris(2,2'-bipyridine)-copper(ii)) tris(oxalato)-chromium(iii) nitrate nonahydrate [Cu(bpy)3]2[Cr(C2O4)3]NO3·9H2O monoclinic P21/c a=31.314 b=13.536 c=22.202 β=132.01° [27]
(μ2-Oxalato)-tetrakis(μ2-N,N'-propane-1,3-bis(3-methoxysalicylideneiminato))-diaqua-bis(nitrato-O)-tetra-copper(ii)-di-neodymium(iii) dinitrate hexahydrate [{(LCuII(ONO2))(LCuII(H2O))NdIII}2(μ-C2O4)](NO3)2 · 6H2O monoclinic P21 a=16.982 b=15.241 c=17.368 β=96.71° [28]
(H3O,N2H5)5{[Ce(H2O)][Ce(NO3)]2(C2O4)6}.6H2O tetragonal P43212 a=11.6521 c=27.9597 [29]
(H3O,N2H5)2{Nd(C2O4)2NO3} monoclinic P21/c a=9.296 b=17.214 c=9.214 β=116.586 [29]
(H3O,N2H5)2(NO3)2{Eu2(H2O)6(C2O4)3} monoclinic P21/n a=8.0806 b=18.986 c=17.318 β=99.331° [29]
melaminium [C3H7N6]6[Dy(C2O4)4][NO3] triclinic P1 a=9.777 b=10.676 c=25.083 α=97.18° β=79.81° γ=86.52° 2570 [30]
melaminium [C3H7N6]6[Ho(C2O4)4][NO3] triclinic P1 a=9.760 b=10.660 c=25.051 α=87.24° β=87.24° γ=79.96° 2559 [30]
(N2H5){Er(C2O4)2}.2H2O tetragonal P43212 a=11.3348 c=9.2646
melaminium [C3H7N6]6[Yb(C2O4)4][NO3] triclinic P1 a=9.7297 b=10.5937 c=24.9904 α=87.271° β=80.123° γ=86.955° 2532.15 [30]
lead nitrate oxalate Pb2(NO3)2(C2O4)⋅2H2O monoclinic P21/c a=10.623 b=7.9559 c=6.1932 β=104.49° Z=4 [31][32]
(OPb2)2(C2O4)(NO3)2 monoclinic P21/c a=11.8682 b=5.2501 c=9.0989 β=96.741° [33]
μ-Oxalato-κ4O1,O2:O1′,O2′-bis[aqua(2,2′-bipyridine-κN)(nitrato-κ2O,O′)lead(II)] Pb2(C2O4)(NO3)2(C10H8N2)2(H2O)2 monoclinic P21/c a=9.579 b=20.633 c=6.765 β=91.687° Z=2 1336.5 [34]
bipy = 2,2′-bipyridine; (μ2-oxalato)-bis(2,2'-bipyridine)-dinitrato-diaqua-di-lead Pb2(ox)(bipy)2(NO3)2(H2O)2 monoclinic P21/c a=9.5444 b=20.5956 c=6.7449 β=91.819° [35]
phen = 1,10-phenanthroline {Pb(phen)2}2Cr(ox)2(phen)][Cr(ox)2(phen)](NO3)2 triclinic P1 a 13.311 b 18.861 c 19.500 α 115.14° β 107.54° γ 96.28° [36]
AgPb(C2O4)(NO3) heat decompose to Ag and PbCO3 [37]
tetraethyldiglycolamide [Th(TEDGA)2(C2O4)][NO3]2[H2C2O4].6H2O 1128.86 tetragonal P42212 a=18.714 c=12.9212 Z=4 4525.2 1.657 @100K Th is 10 coordinate [38]
tetraethyldiglycolamide [Th2(C2O4)3(TEDGA)4][NO3][HC2O4][H2C2O4]4.7H2O 2340.47 triclinic P1 a=15.6611 b=17.9082 c=18.1814 α=89.896° β=65.549° γ=87.623° Z=2 4637.2 1.676 @100K is 10 coordinate, bicapped square antiprism [38]
diammonium oxalatotetranitratouranylate (NH4)2[{UO2(NO3)2}2(μ4-C2O4)] · 2H2O 1:4 monoclinic P21/c a = 8.650 b = 11.700 c = 20.213 β = 93.92° Z = 4 2040.9 [39]
Aqua-(2,2'-bipyridine)-bis(nitrato)-(μ2-oxalato)-dioxo-uranium(vi)-copper(ii) UO2Cu(C2O4)(NO3)2(bipy)(H2O) triclinic P1 a 7.7582 b 11.0274 c 12.181 α 66.717° β 85.541° γ 87.653° [40]
(μ2-2,2'-bipyrimidine)-bis(μ2-oxalato)-bis(μ2-hydroxo)-tetraoxo-bis(nitrato)-di-copper-di-uranium [(UO2)2Cu2(C2O4)2(bipym)3(OH)2]·2NO3 triclinic P1 a 9.9169 b 10.9294 c 11.1783 α 103.449° β 110.754° γ 110.069° [40]
[C6H14N]4[UO2(C2O4)2(HC2O4)]NO3·2H2O 1033.86 monoclinic P21/c a=11.9358 b=18.7279 c=19.1956 β=102.210° Z=4 4193.8 1.637 [41]
[C8H18N][UO2(C2O4)(NO3)] monoclinic P21/c a=11.3688 b=11.0238 c=13.4478 β=11.465° Z=4 1557.5 2.338 [41]

References

  1. ^ a b Androš, Lidija; Jurić, Marijana; Molčanov, Krešimir; Planinić, Pavica (2012). "Supramolecular architectures of novel chromium(iii) oxalate complexes: steric effects of the ligand size and building-blocks approach". Dalton Transactions. 41 (48): 14611–14624. doi:10.1039/c2dt32249h. ISSN 1477-9226. PMID 23103949.
  2. ^ Hrib, Cristian; Blaurock, Steffen; Edelmann, Frank (2014-11-28). "Crystallization and Structure Determination of Fac-Triammin-Aquo-Oxalato-Cobalt (III)-Nitrate Monohydrate". Crystals. 4 (4): 490–497. doi:10.3390/cryst4040490. ISSN 2073-4352.
  3. ^ Abdelhak, Jawher; Cherni, S. Namouchi; Jouini, Tahar (2004). "Crystal Structure of Oxalato Di(1,10-phenanthroline-N,N')cobalt(III) Nitrate 3.88 Hydrate [Co(C12H8N2)2(C2O4)]NO3 3.88H2O". Analytical Sciences: X-ray Structure Analysis Online. 20: X65 – X66. doi:10.2116/analscix.20.x65. ISSN 1348-2238.
  4. ^ a b Smékal, Zdeněk; Trávníček, Zdeněk; Nádvorník, Milan; Šindelář, Zdeněk; Klička, Roman; Marek, Jaromír (1998). "Synthesis and Characterization of (μ-Oxalato)nickel(II), Copper(II) and Zinc(II) Complexes with Chelating Polyamines". Collection of Czechoslovak Chemical Communications. 63 (6): 783–792. doi:10.1135/cccc19980783. ISSN 0010-0765.
  5. ^ Ball, P. W.; Blake, A. B. (1969). "Magnetic properties of polynuclear complexes. Part I. Superexchange in some binuclear nickel(II) complexes". Journal of the Chemical Society A: Inorganic, Physical, Theoretical: 1415–1422. doi:10.1039/j19690001415. ISSN 0022-4944.
  6. ^ Dubraja, Lidija Androš; Matković-Čalogović, Dubravka; Planinić, Pavica (2015). "Crystal disassembly and reassembly of heterometallic Ni II –Ta V oxalate compounds". CrystEngComm. 17 (9): 2021–2029. doi:10.1039/C4CE02516D. ISSN 1466-8033.
  7. ^ a b Gao, Sen (2020-07-24). Transition Metal Complexes of Pyridyltriazole and Bipyridine Ligands (Doctor of Philosophy thesis). Louisiana State University and Agricultural and Mechanical College. doi:10.31390/gradschool_dissertations.5353.
  8. ^ Akouibaa, Mohamed; Hassani, Hicham Oudghiri; Ouarsal, Rachid; Rakib, Souâd; Lachkar, Mohammed; Poupon, Morgane; Dusek, Michal; Morley, Nicola; Bali, Brahim El (December 2022). "(H3dien)[Ni(NO3)(C2O4)2].2H2O: Synthesis, crystal structure, catalytic activity and magnetic study". Chemical Data Collections. 42: 100969. doi:10.1016/j.cdc.2022.100969. S2CID 253473558.
  9. ^ Akouibaa, Mohamed; Kadiri, Mariya; Driouch, Majid; Tanji, Karim; Ouarsal, Rachid; Rakib, Souâd; Sfaira, Mouhcine; Morley, Nicola; Lachkar, Mohammed; El Bali, Brahim; Zarrouk, Abdelkader; Bendeif, El-Eulmi (October 2023). "Synthesis, catalytic activity, magnetic study and anticorrosive activity of mild steel in HCl 1 M medium of (H3dien)[Cu(NO3)(C2O4)2].2H2O. A redetermination at 100 K". Materials Chemistry and Physics. 307: 128130. doi:10.1016/j.matchemphys.2023.128130. S2CID 259266416.
  10. ^ Akouibaa, Mohamed; Lakkab, Imane; Direm, Amani; Lachkar, Mohammed; Ouarsal, Rachid; Rakib, Souâd; Nasif, Vesim; Sayin, Koray; Morley, Nicola; Bali, Brahim El (June 2023). "[Cu2(ox)(dien)2](NO3)3, a precursor for preparation of CuO nanoparticles: Synthesis, structural, Hirshfeld surface analyses, and physico-chemical investigations". Journal of Molecular Structure. 1282: 135258. doi:10.1016/j.molstruc.2023.135258. S2CID 257264452.
  11. ^ Lee, Yong-Min; Kim, Yong-Kyu; Jung, Hee-Cheul; Kim, Young-Inn; Choi, Sung-Nak (2002-03-20). "Copper(II) Oxyanion Complexes Derived from Sparteine Copper(II) Dinitrate: Synthesis and Characterization of 4- and 5-Coordinate Copper(II) Complexes". Bulletin of the Korean Chemical Society. 23 (3): 404–412. doi:10.5012/BKCS.2002.23.3.404.
  12. ^ Youngme, Sujittra; Gunnasoot, Pimprapun; Chaichit, Narongsak; Pakawatchai, Chaveng (November 2004). "Dinuclear copper(II) complexes with ferromagnetic and antiferromagnetic interactions mediated by a bridging oxalato group: structures and magnetic properties of [Cu2L4(μ-C2O4)](PF6)2(H2O)2 and [Cu2L2(μ-C2O4)(NO3)2((CH3)2NCOH)2] (L = di-2-pyridylamine)". Transition Metal Chemistry. 29 (8): 840–846. doi:10.1007/s11243-004-1566-9. ISSN 0340-4285. S2CID 97352070.
  13. ^ Cheansirisomboon, Achareeya; Youngme, Sujittra; Pakawatchai, Chaveng; Chaichit, Narongsak (March 2010). "Synthesis and crystal structure of two new dinuclear oxalato-bridged copper(II) complexes containing bis(2-pyridyl)amine as a ligand". Mendeleev Communications. 20 (2): 109–110. doi:10.1016/j.mencom.2010.03.015.
  14. ^ a b Kang, Dae-Bok (2005-12-20). "Influence of Jahn-Teller Distortion on the Magnetic Coupling in Oxalato-Bridged Copper(II) Dimers: An Orbital Interpretation of the Superexchange Mechanism" (PDF). Bulletin of the Korean Chemical Society. 26 (12): 1965–1968. doi:10.5012/bkcs.2005.26.12.1965. ISSN 0253-2964.
  15. ^ Soto, L.; Garcia, J.; Escriva, E.; Legros, J. P.; Tuchagues, J. P.; Dahan, F.; Fuertes, A. (August 1989). "Synthesis, characterization and magnetic properties of .mu.-oxalato- and .mu.-oxamido-bridged copper(II) dimers. Crystal and molecular structures of [Cu2(mepirizole)2(C2O4)(H2O)2](PF6)2.cntdot.mepirizole.cntdot.3H2O and [Cu2(mepirizole)2(C2O4)(NO3)2(H2O)]2[Cu2(mepirizole)2(C2O4)(NO3)2]". Inorganic Chemistry. 28 (17): 3378–3386. doi:10.1021/ic00316a028. ISSN 0020-1669.
  16. ^ Min, Kil Sik; Suh, Myunghyun Paik (June 2000). "Self-Assembly, Structures, and Magnetic Properties of Ladder-Like Copper(II) Coordination Polymers". Journal of Solid State Chemistry. 152 (1): 183–190. Bibcode:2000JSSCh.152..183M. doi:10.1006/jssc.2000.8682.
  17. ^ Juan Shi; Guang-Ming Yang; Peng Cheng; Dai-Zheng Liao; Zong-Hui Jiang; Geng-Lin Wang (January 1997). "Synthesis, structure and magnetic properties of oxalate-bridged complex [Cu2(bpy)2(C2O4)(H2O2)][Cu(bpy)(C2O4)](NO3)2". Polyhedron. 16 (3): 531–534. doi:10.1016/0277-5387(96)00244-6.
  18. ^ Smékal, ZdenĚk; Langer, Vratislav; Wrzeszcz, Grzegorz; Klasová, Petra (2002-01-01). "Synthesis and Characterization of Binuclear (μ-Oxalato) Copper(II) Complexes with N,N′ -Diethylethylenediamine or N,N,N′ -Trimethylethylenediamine". Journal of Coordination Chemistry. 55 (5): 595–608. doi:10.1080/00958970290020900. ISSN 0095-8972. S2CID 98024533.
  19. ^ a b Shaw, Janet L.; Yee, Gordon T.; Wang, Guangbin; Benson, David E.; Gokdemir, Cagil; Ziegler, Christopher J. (2005-07-01). "Magneto−Structural Relationships in a Series of Dinuclear Oxalato-Bridged (Diphenyldipyrazolylmethane)copper(II) Complexes". Inorganic Chemistry. 44 (14): 5060–5067. doi:10.1021/ic048229t. ISSN 0020-1669. PMID 15998034.
  20. ^ Manna, Subal Chandra; Ribas, Joan; Zangrando, Ennio; Ray Chaudhuri, Nirmalendu (May 2007). "Supramolecular networks of dinuclear copper(II): Synthesis, crystal structure and magnetic study". Inorganica Chimica Acta. 360 (8): 2589–2597. doi:10.1016/j.ica.2006.12.041.
  21. ^ Kim, Jung-Sook; Lee, Uk; Koo, Bon-Kweon (2010-02-20). "1D Chain Crystal Structure of Copper(II) Oxalate Containing a 4,4'-Bipyridine and 1,10-Phenanthroline Ligands: [Cu 2 (ox)(4,4'-bpy)(phen) 2 ](NO 3 ) 2". Bulletin of the Korean Chemical Society. 31 (2): 487–490. doi:10.5012/bkcs.2010.31.02.487. ISSN 0253-2964.
  22. ^ Boutobba, Zina; Direm, Amani; Sayin, Koray; El Bali, Brahim; Lachkar, Mohammed; Benali-Cherif, Nourredine (March 2020). "Crystal structure, Hirshfeld surface analysis and theoretical calculations of an oxalato-bridged copper(II) complex: μ-oxalato-bis[(2,2'-bipyridine) hydrate copper(II) nitrate]". Journal of the Iranian Chemical Society. 17 (3): 671–685. doi:10.1007/s13738-019-01805-0. ISSN 1735-207X. S2CID 207912853.
  23. ^ Diallo, Madina; Tamboura, Farba Bouyagui; Gaye, Mohamed; Barry, Aliou Hamady; Bah, Youssouph (2008-09-01). "The cocrystal μ-oxalato-κ 4 O 1 , O 2 : O 1′ , O 2′ -bis(aqua(nitrato-κ O ){[1-(2-pyridyl-κ N )ethylidene]hydrazine-κ N }copper(II)) μ-oxalato-κ 4 O 1 , O 2 : O 1′ , O 2′ -bis((methanol-κ O )(nitrato-κ O ){[1-(2-pyridyl-κ N )ethylidene]hydrazine-κ N }copper(II)) (1/1)". Acta Crystallographica Section E. 64 (9): m1124 – m1125. doi:10.1107/S1600536808024550. ISSN 1600-5368. PMC 2960478. PMID 21201585.
  24. ^ Youngme, Sujittra; van Albada, Gerard A; Chaichit, Narongsak; Gunnasoot, Pimprapun; Kongsaeree, Palangpon; Mutikainen, Ilpo; Roubeau, Olivier; Reedijk, Jan; Turpeinen, Urho (September 2003). "Synthesis, spectroscopic characterization, X-ray crystal structure and magnetic properties of oxalato-bridged copper(II) dinuclear complexes with di-2-pyridylamine". Inorganica Chimica Acta. 353: 119–128. doi:10.1016/S0020-1693(03)00207-X.
  25. ^ Carranza, José; Grove, Hilde; Sletten, Jorunn; Lloret, Francesc; Julve, Miguel; Kruger, Paul E.; Eller, Chad; Rillema, D. Paul (December 2004). "Synthesis, X-ray Crystal Structure and Magnetic Properties of Oxalato-Bridged Copper( II ) Complexes with 2,3-Bis(2-pyridyl)pyrazine, 2,3-Bis(2-pyridyl)quinoxaline and 2,2′-Bipyrazine as Peripheral Ligands". European Journal of Inorganic Chemistry. 2004 (24): 4836–4848. doi:10.1002/ejic.200400500. ISSN 1434-1948.
  26. ^ Hawes, Chris S.; Kruger, Paul E. (2013). "Discrete and Polymeric Cu(II) Coordination Complexes with a Flexible bis-(pyridylpyrazole) Ligand: Structural Diversity and Unexpected Solvothermal Reactivity". Australian Journal of Chemistry. 66 (4): 401. doi:10.1071/CH12443. ISSN 0004-9425.
  27. ^ a b Jurić, Marijana; Planinić, Pavica; Brničević, Nevenka; Milić, Dalibor; Matković-Čalogović, Dubravka; Pajić, Damir; Zadro, Krešo (July 2006). "New Heterometallic (Cu II and Cr III ) Complexes – First Crystal Structure of an Oxalate-Bridged Ferromagnetically Coupled [Cu II Cr III Cu II ] System". European Journal of Inorganic Chemistry. 2006 (13): 2701–2710. doi:10.1002/ejic.200501092. ISSN 1434-1948.
  28. ^ Gheorghe, Ruxandra; Andruh, Marius; Costes, Jean-Pierre; Donnadieu, Bruno; Schmidtmann, Marc; Müller, Achim (November 2007). "Making 3d–4f hexanuclear clusters from heterotrinuclear cationic building blocks". Inorganica Chimica Acta. 360 (14): 4044–4050. doi:10.1016/j.ica.2007.05.018.
  29. ^ a b c Tamain, Christelle; Rivenet, Murielle; Arab-Chapelet, Bénédicte; Grandjean, Stéphane; Abraham, Francis (2010). "New Lanthanide Oxalato-nitrates Crystallized From Acidic Solutions". MRS Proceedings. 1265. doi:10.1557/PROC-1265-AA04-05. ISSN 0272-9172.
  30. ^ a b c Vella-Zarb, Liana; Baisch, Ulrich (2017-11-17). "Melaminium Lanthanide Oxalate Coordination Compounds –Synthesis and Structural Varieties". Zeitschrift für anorganische und allgemeine Chemie. 643 (21): 1712–1716. doi:10.1002/zaac.201700299. ISSN 0044-2313.
  31. ^ Boudaren, Chaouki; Auffrédic, Jean-Paul; Louër, Michèle; Louër, Daniel (September 2003). "A powder X-ray diffraction study of lead chloride oxalate Pb 2 Cl 2 (C 2 O 4 ): ab initio structure determination and thermal behavior". Powder Diffraction. 18 (3): 205–213. doi:10.1154/1.1590352. ISSN 0885-7156. S2CID 98700786.
  32. ^ Boudaren, Chaouki; Auffrédic, Jean-Paul; Bénard-Rocherullé, Patricia; Louër, Daniel (December 2001). "Structure determination from powder diffraction data and thermal behaviour of layered lead nitrate oxalate hydrate, Pb2(NO3)2(C2O4).2H2O". Solid State Sciences. 3 (8): 847–858. doi:10.1016/S1293-2558(01)01188-8.
  33. ^ Thirumurugan, A.; Rao, C.N.R. (May 2008). "Hybrid structures formed by homo- and heteroleptic aliphatic dicarboxylates of lead with 2-D inorganic connectivity". Journal of Solid State Chemistry. 181 (5): 1184–1194. Bibcode:2008JSSCh.181.1184T. doi:10.1016/j.jssc.2008.02.021.
  34. ^ Pan, Gang-Hong; Tang, Jin-Niu; Huang, Zhong-Jing; Li, Long; Zhang, Chun-Mei (2012-10-15). "μ-Oxalato-κ 4 O 1 , O 2 : O 1′ , O 2′ -bis[aqua(2,2′-bipyridine-κ N )(nitrato-κ 2 O , O ′)lead(II)]". Acta Crystallographica Section E. 68 (10): m1310. doi:10.1107/S1600536812040196. ISSN 1600-5368. PMC 3470178. PMID 23125622.
  35. ^ Bhunia, Apurba; Zangrando, Ennio; Mistri, Soumen; Manna, Subal Chandra (January 2014). "Oxalato-bridged oligonuclear complexes of cadmium(II)/lead(II) with bipyridine coligands: Synthesis, crystal structure, electronic spectra, density functional theory calculation and effect of organic compounds on the fluorescence property". Inorganica Chimica Acta. 409: 528–537. doi:10.1016/j.ica.2013.10.001.
  36. ^ Bhunia, Apurba; Zangrando, Ennio; Khatua, Snehadrinarayan; Manna, Subal Chandra (November 2022). "Synthesis, crystal structure, electrochemistry and thermal analysis of an oxalato bridged Cr(III)-Pb(II) heterometallic coordination compound". Journal of Molecular Structure. 1267: 133562. Bibcode:2022JMoSt126733562B. doi:10.1016/j.molstruc.2022.133562. S2CID 250080604.
  37. ^ Nassar, A. M.; Abo Zeid, E. F.; Elseman, A. M.; Alotaibi, N. F. (2018). "A novel heterometallic compound for design and study of electrical properties of silver nanoparticles-decorated lead compounds". New Journal of Chemistry. 42 (2): 1387–1395. doi:10.1039/C7NJ03682E. ISSN 1144-0546.
  38. ^ a b Farger, P.; Haidon, B.; Roussel, P.; Arab-Chapelet, B.; Rivenet, M. (2018). "Single-Crystal to Single-Crystal Transformation in the Thorium-TEDGA-Oxalate-Nitrate System Description and Comparison of the Main Structural Features". Unknown.
  39. ^ Belomestnykh, V. I.; Sveshnikova, L. B.; Mikhailov, Yu. N. (June 2013). "Synthesis and structure of the oxalatotetranitratouranylate complex (NH4)2[{UO2(NO3)2}2(μ4-C2O4)] · 2H2O". Russian Journal of Inorganic Chemistry. 58 (6): 664–670. doi:10.1134/S0036023613060053. ISSN 0036-0236. S2CID 98853037.
  40. ^ a b Thuéry, Pierre; Rivière, Eric (2013). "Uranyl–copper(ii) heterometallic oxalate complexes: coordination polymers and frameworks". Dalton Transactions. 42 (29): 10551–10558. doi:10.1039/c3dt51020d. ISSN 1477-9226. PMID 23760346.
  41. ^ a b He, Jiangang; Liu, Chunli; Wei, Wenqi; Wang, Shuao; Ge, Rui; Qiao, Xueling; Wang, Yaxing (2017-09-01). "Synthesis, structure and optical properties of two uranyl oxalate complexes templated by protonated amines". SCIENTIA SINICA Chimica. 47 (9): 1140–1147. doi:10.1360/N032017-00040. ISSN 1674-7224.

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