苯并[ghi]苝是一种稠环芳香烃,化学式为C22H12。北海道石為此化合物的天然結晶礦物。
合成与反应
苯并[ghi]苝可由苝和硝基乙烯在1,2-二氯苯中于175 °C反应制得。[2]
它和溴在铁存在下于二氯甲烷中反应,可以得到3,8-二溴苯并[ghi]苝。[3]
参考文献
- ^ Ma, Ying-Ge; Lei, Ying Duan; Xiao, Hang; Wania, Frank; Wang, Wen-Hua. Critical Review and Recommended Values for the Physical-Chemical Property Data of 15 Polycyclic Aromatic Hydrocarbons at 25 °C. Journal of Chemical & Engineering Data (American Chemical Society (ACS)). 2009-11-17, 55 (2): 819–825. ISSN 0021-9568. doi:10.1021/je900477x.
- ^ Fort, Eric H.; Scott, Lawrence T. One‐Step Conversion of Aromatic Hydrocarbon Bay Regions into Unsubstituted Benzene Rings: A Reagent for the Low‐Temperature, Metal‐Free Growth of Single‐Chirality Carbon Nanotubes. Angewandte Chemie International Edition (Wiley). 2010-07-29, 49 (37): 6626–6628. ISSN 1433-7851. doi:10.1002/anie.201002859.
- ^ Hogan, David T.; Zhou, Wen; Gelfand, Benjamin S.; Sutherland, Todd C. Rational assembly of benzenoid rings in benzo[ghi]perylene yields a diversity of edge features with site-selective reactivity. Organic Chemistry Frontiers (Royal Society of Chemistry (RSC)). 2023, 10 (14): 3467–3478. ISSN 2052-4129. doi:10.1039/d3qo00718a.