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溴氧化铋

溴氧化铋
英文名 Bismuth(III) oxybromide
别名 氧溴化铋
溴化氧铋
识别
CAS号 7787-57-7  checkY
性质
化学式 BiBrO
摩尔质量 304.88 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

溴氧化铋是一种无机化合物,化学式为BiOBr。它在冷碱溶液中稳定,加热转化为Bi2O3[1]

制备

硝酸铋溴化钠的稀溶液混合搅拌,滴加氢氧化钠,可以制得溴氧化铋(BiOBr)。[2]不同的反应条件也能得到不同比例的化合物,如Bi4O5Br2[3]、Bi24O31Br10[4]等。

参考文献

  1. ^ 无机化学丛书 第四卷 氮 磷 砷分族. 科学出版社. pp 496. "4.4 铋的卤氧化物"
  2. ^ Haiping Li, Tingxia Hu, Jianqiang Liu, Shue Song, Na Du, Renjie Zhang, Wanguo Hou. Thickness-dependent photocatalytic activity of bismuth oxybromide nanosheets with highly exposed (0 1 0) facets. Applied Catalysis B: Environmental. 2016-03, 182: 431–438 [2018-08-20]. ISSN 0926-3373. doi:10.1016/j.apcatb.2015.09.050. 
  3. ^ Jun Di, Jiexiang Xia, Mengxia Ji, Sheng Yin, Hongping Li, Hui Xu, Qi Zhang, Huaming Li. Controllable synthesis of Bi4O5Br2 ultrathin nanosheets for photocatalytic removal of ciprofloxacin and mechanism insight. Journal of Materials Chemistry A. 2015, 3 (29): 15108–15118 [2018-08-20]. ISSN 2050-7488. doi:10.1039/c5ta02388b (英语). 
  4. ^ Jun Shang, Weichang Hao, Xiaojun Lv, Tianmin Wang, Xiaolin Wang, Yi Du, Shixue Dou, Tengfeng Xie, Dejun Wang, Jiaou Wang. Bismuth Oxybromide with Reasonable Photocatalytic Reduction Activity under Visible Light. ACS Catalysis. 2014-02-19, 4 (3): 954–961 [2018-08-20]. ISSN 2155-5435. doi:10.1021/cs401025u (英语). 
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