Висмутид родия

Висмутид родия
Общие
Систематическое наименование	Висмутид родия
Традиционные названия	Висмутистый родий
Хим. формула	RhBi
Рац. формула	BiRh
Физические свойства
Состояние	кристаллы
Молярная масса	311,89 г/моль
Плотность	12,5 г/см³
Термические свойства
Температура
• разложения	977 ^[1] °C
Классификация
Рег. номер CAS	59125-90-5
PubChem	71443137
SMILES	[Bi].[Rh]
InChI	InChI=1S/Bi.Rh IGGYEOUOHHZFSP-UHFFFAOYSA-N
Приведены данные для стандартных условий (25 °C, 100 кПа), если не указано иное.

Висмутид родия — бинарное неорганическое соединение родия и висмута с формулой RhBi, кристаллы.

Получение

Сплавление стехиометрических количеств чистых веществ:

{\mathsf {Rh+Bi\ {\xrightarrow {977^{o}C}}\ RhBi}}

Физические свойства

Висмутид родия образует кристаллы гексагональной сингонии, пространственная группа P 6₃/mmc, параметры ячейки a = 0,40953 нм, c = 0,56658 нм, Z = 2, структура типа арсенида никеля NiAs ^[1]^[2]^[3].

Соединение образуется по перитектической реакции при температуре 977°С и имеет область гомогенности 48÷50,6 ат.% родия ^[1] (997°С и 45÷48 ат.% в ^[2]).

Примечания

↑ ¹ ² ³ Диаграммы состояния двойных металлических систем / Под ред. Н. П. Лякишева. — М.: Машиностроение, 1996. — Т. 1. — 992 с. — ISBN 5-217-02688-X.
↑ ¹ ² H. Okamoto. Bi-Rh (Bismuth-Rhodium) // Journal of Phase Equilibria and Diffusion. — 2010. — Т. 31, № 2. — С. 204. — doi:10.1007/s11669-010-9660-5.
↑ B. Predel. Bi-Rh (Bismuth-Rhodium) // Landolt-Börnstein - Group IV Physical Chemistry. — 1992. — Т. 5b. — С. 1-4. — doi:10.1007/10040476_580.

Соединения родия

Бромид родия(III) (RhBr₃)
Гексанитрородат(III) калия (K₃[Rh(NO₂)₆])
Гексахлорородат(III) натрия (Na₃[RhCl₆])
Гидроксид родия(III) (Rh(OH)₃)
Гидроксид родия(IV) (Rh(OH)₄)
Додекакарбонил родия (Rh₄(CO)₁₂)
Иодид родия(III) (RhI₃)
Нитрат родия(III) (Rh(NO₃)₃)
Оксид родия(II) (RhO)
Оксид родия(III) (Rh₂O₃)
Оксид родия(IV) (RhO₂)
Октакарбонил родия (Rh₂(CO)₈)
Родоцен
Сульфид родия(II) (RhS)
Сульфид родия(III) (Rh₂S₃)
Тетракарбонилродиевая кислота (HRh(CO)₄)
Фторид родия(III) (RhF₃)
Фторид родия(IV) (RhF₄)
Хлорид родия(II) (RhCl₂)
Хлорид родия(III) (RhCl₃)

Соединения висмута

Это заготовка статьи о неорганическом веществе. Помогите Википедии, дополнив её.

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