Kalifornium(III) fluorida

Kalifornium(III) fluorida
Nama

Nama IUPAC Kalifornium(III) fluorida
Nama lain Kalifornium trifluorida
Penanda
Nomor CAS	42775-52-0
Model 3D (JSmol)	Gambar interaktif
3DMet	{{{3DMet}}}
Nomor EC
Nomor RTECS	{{{value}}}
InChI InChI=1S/Cf.3FH/h;3*1H/q+3;;;/p-3 Key: RFYJBQZVUMTFMQ-UHFFFAOYSA-K
SMILES [Cf+3].[F-].[F-].[F-]
Sifat
Rumus kimia	CfF₃
Massa molar	308,00 g·mol⁻¹
Penampilan	Padatan kuning kehijauan
Densitas	g/cm³
Struktur
Struktur kristal	Ortorombik
Senyawa terkait
Senyawa terkait	Berkelium trifluorida Einsteinium trifluorida
Bahaya
Bahaya utama	Radioaktif
Kecuali dinyatakan lain, data di atas berlaku pada suhu dan tekanan standar (25 °C [77 °F], 100 kPa).
Referensi

Kalifornium(III) fluorida adalah senyawa anorganik biner dari kalifornium dan fluorin dengan rumus CfF₃.^[1] Seperti pada kalifornium oksida (Cf₂O₃) dan senyawa kalifornium halida lainnya, termasuk kalifornium klorida (CfCl₃), bromida (CfBr₃), dan iodida (CfI₃), atom kalifornium dalam senyawa ini memiliki keadaan oksidasi +3.

Sifat fisik

Kalifornium(III) merupakan padatan berwarna kuning kehijauan^[2] dan memiliki dua struktur kristal yang bergantung pada suhu. Pada suhu rendah, struktur ortorombik (jenis YF₃) ditemukan dengan parameter kisi a = 665,3(3) pm, b = 703,9(1) pm, dan c = 439,3(3) pm. Pada suhu yang lebih tinggi, senyawa ini memiliki struktur trigonal (jenis LaF₃) dengan: a = 694,5(3) pm dan c = 710,1(2) pm. Di sini, setiap atom kalifornium dikelilingi oleh sembilan atom fluorin dalam struktur prisma trigonal bertudung-tiga yang terdistorsi.^[3]^[4]

Referensi

^ Haupt, Axel (22 Maret 2021). Organic and Inorganic Fluorine Chemistry: Methods and Applications (dalam bahasa Inggris). Walter de Gruyter GmbH & Co KG. hlm. 618. ISBN 978-3-11-065933-7. Diakses tanggal 10 Februari 2024.
^ "WebElements Periodic Table » Californium » californium trifluoride". webelements.com. Diakses tanggal 10 Februari 2024.
^ Stevenson, J. N.; Peterson, J. R. (1 Oktober 1973). "The trigonal and orthorhombic crystal structures of CfF3 and their temperature relationship". Journal of Inorganic and Nuclear Chemistry (dalam bahasa Inggris). 35 (10): 3481–3486. doi:10.1016/0022-1902(73)80356-2. ISSN 0022-1902. Diakses tanggal 10 Februari 2024.
^ Macintyre, Jane E. (23 July 1992). Dictionary of Inorganic Compounds (dalam bahasa Inggris). CRC Press. hlm. 2825. ISBN 978-0-412-30120-9. Diakses tanggal 10 Februari 2024.

Senyawa kalifornium

Cf(II)

CfI₂

Cf(III)

Senyawa organokalifornium(III)	CfCp₃

Cf(IV)

CfO₂

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