Search Results: Phosphazenes
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Phosphazene
Senin, 2025-11-03 15:21:34a double bond between P and N. One class of phosphazenes have the formula R−N=P(−NR2)3. These phosphazenes are also known as iminophosphoranes and phosphine...
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Kamis, 2026-05-14 22:05:33phosphinimines, λ5-phosphazenes, acyclic phosphazenes) are a class of organophosphorus compounds and an acyclic subclass of phosphazenes with the general...
Click to read more »Phosphorus
Minggu, 2026-07-19 01:36:10exist mainly as rings such as the trimer hexachlorophosphazene. The phosphazenes arise by treatment of phosphorus pentachloride with ammonium chloride:...
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Kamis, 2025-11-20 22:34:49species, where nitrogen act as a proton acceptor. These include the phosphazenes, phosphanes, amidines, and guanidines. Other organic compounds that meet...
Click to read more »P4-t-Bu
Minggu, 2026-08-16 01:15:17(2016), "Experimental basicities of superbasic phosphonium ylides and phosphazenes", J. Org. Chem., vol. 81, no. 17, pp. 7349–7361, doi:10.1021/acs.joc...
Click to read more »Polyphosphazene
Minggu, 2026-04-26 17:03:12many references to cyclomatrix polymers derived from cyclic trimeric phosphazenes incorporated into cross-linked resins for fire resistant circuit boards...
Click to read more »Lithium polymer battery
Selasa, 2026-08-11 06:12:35carbonate) (PTMC), polypropylene oxide (PPO), poly[bis(methoxy-ethoxy-ethoxy)phosphazene] (MEEP), etc. PEO exhibits the most promising performance as a solid...
Click to read more »Organic base
Minggu, 2025-06-22 03:41:08alkylamines, such as methylamine imidazole benzimidazole histidine guanidine phosphazene bases hydroxides of quaternary ammonium cations or some other organic...
Click to read more »Bis(triphenylphosphine)iminium chloride
Senin, 2026-08-10 11:14:09weakly coordinating cation to isolate reactive anions. [(Ph3P)2N]+ is a phosphazene. [(Ph3P)2N]Cl is prepared in two steps from triphenylphosphine Ph3P:...
Click to read more »Hexachlorophosphazene
Rabu, 2026-06-17 05:46:23(1991-03-01). "Syntheses and structures of cyclic and short-chain linear phosphazenes bearing 4-phenylphenoxy side groups". Journal of the American Chemical...
Click to read more »7-Methyl-1,5,7-triazabicyclo(4.4.0)dec-5-ene
Senin, 2026-03-09 14:26:46T. (2009). Superbases for Organic Synthesis: Guanidines, Amidines, Phosphazenes and Related Organocatalysts. John Wiley & Sons. ISBN 9780470740866. Simoni...
Click to read more »Verkade base
Rabu, 2025-07-23 18:02:15acids, the Verkade base catalyzes a variety of condensation reactions. Phosphazenes are phosphorus(V) derivatives with the formula RN=P(NR2)3. Verkade, John...
Click to read more »Tetraazidomethane
Minggu, 2026-08-09 00:18:52reactions with alkenes and alkynes, and reaction with phosphines to form phosphazenes. "The Exciting Chemistry of Tetraazidomethane", Klaus Banert, Young-Hyuk...
Click to read more »Non-nucleophilic base
Senin, 2025-10-13 08:49:36DBU 2,6-Di-tert-butylpyridine, a weak non-nucleophilic base pKa = 3.58 Phosphazene bases, such as t-Bu-P4 Non-nucleophilic bases of high strength are usually...
Click to read more »(Trimethylsilyl)methyllithium
Jumat, 2025-07-25 15:52:05(2007) [1989]. "Organosilicon Derivatives of Cyclic and High Polymeric Phosphazenes". Inorganic Syntheses. Vol. 25. pp. 60–68. doi:10.1002/9780470132562...
Click to read more »Cyclodiphosphazane
Sabtu, 2025-12-27 07:40:40four membered P2N2 ring systems and one of the major classes of cyclic phosphazene compounds. Bis(chloro)cyclodiphosphazanes, (cis-[ClP(μ-NR)]2) are important...
Click to read more »Perfluorobutanesulfonyl fluoride
Selasa, 2026-06-09 20:10:55such as DBU or phosphazenes to give alkenyl nonaflates in high yields without formation of a discrete enolate. Use of the P2 phosphazene base at -30 to...
Click to read more »1,1,3,3-Tetramethylguanidine
Selasa, 2026-03-03 08:32:51Basicity Scale in THF Solution Ranging from 2-Methoxypyridine to EtP1(pyrr) Phosphazene". J. Org. Chem. 67 (6): 1873–1881. doi:10.1021/jo016185p. PMID 11895405...
Click to read more »Silazane
Minggu, 2025-07-06 20:28:12moisture sensitive. With water they convert to silanols or siloxanes. Phosphazene Paraformaldehyde Adamson, G. W.; Daly, J. J. (1970). "Crystal and Molecular...
Click to read more »Poly(phthalaldehyde)
Selasa, 2025-12-30 17:54:29proposed the use of phosphazene bases to speed up the reaction and lower the polydispersity index. Up until 2023, three different phosphazene bases have been...
Click to read more »Double bond rule
Jumat, 2026-05-15 11:00:27compounds silanimines, rare, easy oligomerization, observed only at low temp phosphazene (P=N) sulfilimines O Singlet oxygen silanones, Si=O bonds extremely reactive...
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Kamis, 2022-09-22 02:41:39Handbook of Polymer Synthesis Mario Gleria, Roger De Jaeger (2004) Phosphazenes: A Worldwide InsightNova Publishers, 2004. 1047 pages. ISBN 1-59033-423-X...
Click to read more »Vadapalli Chandrasekhar
Minggu, 2026-08-09 15:49:52375–. ISBN 978-1-78262-433-2. Mario Gleria; Roger De Jaeger (2004). Phosphazenes: A Worldwide Insight. Nova Publishers. pp. 827–. ISBN 978-1-59033-423-2...
Click to read more »Johnson–Corey–Chaykovsky reaction
Sabtu, 2026-02-14 03:40:39the aldehyde is blocked by the camphor moiety. The reaction employs a phosphazene base to promote formation of the ylide. Catalytic reagents have been...
Click to read more »Nontrigonal pnictogen compounds
Rabu, 2025-05-28 18:50:08phosphorus compounds can also be oxidized by organic azide to yield phosphazenes. These sterically constrained phosphorus compounds show remarkable reactivity...
Click to read more »Dodecahedrane
Minggu, 2026-06-28 21:12:121002/1521-3765(20020118)8:2<509::AID-CHEM509>3.0.CO;2-D. PMID 11843163, the phosphazene base "P2F" is described in Link, Reinhard; Schwesinger, Reinhard (July...
Click to read more »Octachlorotetraphosphazene
Rabu, 2026-06-17 05:48:00Octachlorotetraphosphazene is an inorganic compound with the formula (NPCl2)4. The molecule has a cyclic, unsaturated backbone consisting of alternating...
Click to read more »Tris(2,4,6-trimethoxyphenyl)phosphine
Selasa, 2026-07-28 20:27:07"Tris(2,4,6-trimethoxyphenyl)phosphine – a Lewis base able to compete with phosphazene bases in catalysing oxa-Michael reactions". Catalysis Science & Technology...
Click to read more »Fotretamine
Minggu, 2025-12-21 12:58:57Fotretamine (INNTooltip International Nonproprietary Name), also known as fotrin, is an alkylating antineoplastic and immunosuppressant. The drug entered...
Click to read more »High-refractive-index polymer
Selasa, 2026-08-11 10:43:22environment. Phosphorus-containing groups, such as phosphonates and phosphazenes, often exhibit high molar refractivity and optical transmittance in the...
Click to read more »Outline of organic chemistry
Rabu, 2026-08-12 14:09:34Organolithiums Organosilanes Organophosphate Compounds Polyphosphates Phosphazenes Iminophosphoranes Polyphosphazenes Phosphinates Phosphines Diphosphines...
Click to read more »Hexafluorophosphazene
Rabu, 2026-06-17 05:54:10hypothetical compound N≡PF2 (phosphazyl difluoride). Its classification as a phosphazene highlights its relationship to benzene. Hexafluorophosphazene has a hexagonal...
Click to read more »Β-Butyrolactone
Minggu, 2026-08-16 15:05:20diazabicycloundecene (DBU), 1,5,7-triazabicyclo(4.4.0)dec-5-en (TBD) and the phosphazene BEMP are able to catalyze the ring-opening polymerization of β-butyrolactone...
Click to read more »Fluorescent glucose biosensor
Selasa, 2026-03-31 22:14:09PHB, PVA, PNVP, P(HEMA),[clarification needed] p(biscarboxy-phenoxy-phosphazene), p(GEMA-sulfate), and others), or a hybrid of the two. In addition to...
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