Search Results: Phosphazenes

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Phosphazene
Senin, 2025-11-03 15:21:34

a double bond between P and N. One class of phosphazenes have the formula R−N=P(−NR2)3. These phosphazenes are also known as iminophosphoranes and phosphine...

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Iminophosphorane
Kamis, 2026-05-14 22:05:33

phosphinimines, λ5-phosphazenes, acyclic phosphazenes) are a class of organophosphorus compounds and an acyclic subclass of phosphazenes with the general...

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Phosphorus
Minggu, 2026-07-19 01:36:10

exist mainly as rings such as the trimer hexachlorophosphazene. The phosphazenes arise by treatment of phosphorus pentachloride with ammonium chloride:...

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Superbase
Kamis, 2025-11-20 22:34:49

species, where nitrogen act as a proton acceptor. These include the phosphazenes, phosphanes, amidines, and guanidines. Other organic compounds that meet...

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P4-t-Bu
Minggu, 2026-08-16 01:15:17

(2016), "Experimental basicities of superbasic phosphonium ylides and phosphazenes", J. Org. Chem., vol. 81, no. 17, pp. 7349–7361, doi:10.1021/acs.joc...

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Polyphosphazene
Minggu, 2026-04-26 17:03:12

many references to cyclomatrix polymers derived from cyclic trimeric phosphazenes incorporated into cross-linked resins for fire resistant circuit boards...

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Lithium polymer battery
Selasa, 2026-08-11 06:12:35

carbonate) (PTMC), polypropylene oxide (PPO), poly[bis(methoxy-ethoxy-ethoxy)phosphazene] (MEEP), etc. PEO exhibits the most promising performance as a solid...

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Organic base
Minggu, 2025-06-22 03:41:08

alkylamines, such as methylamine imidazole benzimidazole histidine guanidine phosphazene bases hydroxides of quaternary ammonium cations or some other organic...

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Bis(triphenylphosphine)iminium chloride
Senin, 2026-08-10 11:14:09

weakly coordinating cation to isolate reactive anions. [(Ph3P)2N]+ is a phosphazene. [(Ph3P)2N]Cl is prepared in two steps from triphenylphosphine Ph3P:...

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Hexachlorophosphazene
Rabu, 2026-06-17 05:46:23

(1991-03-01). "Syntheses and structures of cyclic and short-chain linear phosphazenes bearing 4-phenylphenoxy side groups". Journal of the American Chemical...

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7-Methyl-1,5,7-triazabicyclo(4.4.0)dec-5-ene
Senin, 2026-03-09 14:26:46

T. (2009). Superbases for Organic Synthesis: Guanidines, Amidines, Phosphazenes and Related Organocatalysts. John Wiley & Sons. ISBN 9780470740866. Simoni...

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Verkade base
Rabu, 2025-07-23 18:02:15

acids, the Verkade base catalyzes a variety of condensation reactions. Phosphazenes are phosphorus(V) derivatives with the formula RN=P(NR2)3. Verkade, John...

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Tetraazidomethane
Minggu, 2026-08-09 00:18:52

reactions with alkenes and alkynes, and reaction with phosphines to form phosphazenes. "The Exciting Chemistry of Tetraazidomethane", Klaus Banert, Young-Hyuk...

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Non-nucleophilic base
Senin, 2025-10-13 08:49:36

DBU 2,6-Di-tert-butylpyridine, a weak non-nucleophilic base pKa = 3.58 Phosphazene bases, such as t-Bu-P4 Non-nucleophilic bases of high strength are usually...

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(Trimethylsilyl)methyllithium
Jumat, 2025-07-25 15:52:05

(2007) [1989]. "Organosilicon Derivatives of Cyclic and High Polymeric Phosphazenes". Inorganic Syntheses. Vol. 25. pp. 60–68. doi:10.1002/9780470132562...

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Cyclodiphosphazane
Sabtu, 2025-12-27 07:40:40

four membered P2N2 ring systems and one of the major classes of cyclic phosphazene compounds. Bis(chloro)cyclodiphosphazanes, (cis-[ClP(μ-NR)]2) are important...

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Perfluorobutanesulfonyl fluoride
Selasa, 2026-06-09 20:10:55

such as DBU or phosphazenes to give alkenyl nonaflates in high yields without formation of a discrete enolate. Use of the P2 phosphazene base at -30 to...

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1,1,3,3-Tetramethylguanidine
Selasa, 2026-03-03 08:32:51

Basicity Scale in THF Solution Ranging from 2-Methoxypyridine to EtP1(pyrr) Phosphazene". J. Org. Chem. 67 (6): 1873–1881. doi:10.1021/jo016185p. PMID 11895405...

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Silazane
Minggu, 2025-07-06 20:28:12

moisture sensitive. With water they convert to silanols or siloxanes. Phosphazene Paraformaldehyde Adamson, G. W.; Daly, J. J. (1970). "Crystal and Molecular...

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Poly(phthalaldehyde)
Selasa, 2025-12-30 17:54:29

proposed the use of phosphazene bases to speed up the reaction and lower the polydispersity index. Up until 2023, three different phosphazene bases have been...

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Double bond rule
Jumat, 2026-05-15 11:00:27

compounds silanimines, rare, easy oligomerization, observed only at low temp phosphazene (P=N) sulfilimines O Singlet oxygen silanones, Si=O bonds extremely reactive...

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Poly(dichlorophosphazene)
Kamis, 2022-09-22 02:41:39

Handbook of Polymer Synthesis Mario Gleria, Roger De Jaeger (2004) Phosphazenes: A Worldwide InsightNova Publishers, 2004. 1047 pages. ISBN 1-59033-423-X...

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Vadapalli Chandrasekhar
Minggu, 2026-08-09 15:49:52

 375–. ISBN 978-1-78262-433-2. Mario Gleria; Roger De Jaeger (2004). Phosphazenes: A Worldwide Insight. Nova Publishers. pp. 827–. ISBN 978-1-59033-423-2...

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Johnson–Corey–Chaykovsky reaction
Sabtu, 2026-02-14 03:40:39

the aldehyde is blocked by the camphor moiety. The reaction employs a phosphazene base to promote formation of the ylide. Catalytic reagents have been...

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Nontrigonal pnictogen compounds
Rabu, 2025-05-28 18:50:08

phosphorus compounds can also be oxidized by organic azide to yield phosphazenes. These sterically constrained phosphorus compounds show remarkable reactivity...

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Dodecahedrane
Minggu, 2026-06-28 21:12:12

1002/1521-3765(20020118)8:2<509::AID-CHEM509>3.0.CO;2-D. PMID 11843163, the phosphazene base "P2F" is described in Link, Reinhard; Schwesinger, Reinhard (July...

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Octachlorotetraphosphazene
Rabu, 2026-06-17 05:48:00

Octachlorotetraphosphazene is an inorganic compound with the formula (NPCl2)4. The molecule has a cyclic, unsaturated backbone consisting of alternating...

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Tris(2,4,6-trimethoxyphenyl)phosphine
Selasa, 2026-07-28 20:27:07

"Tris(2,4,6-trimethoxyphenyl)phosphine – a Lewis base able to compete with phosphazene bases in catalysing oxa-Michael reactions". Catalysis Science & Technology...

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Fotretamine
Minggu, 2025-12-21 12:58:57

Fotretamine (INNTooltip International Nonproprietary Name), also known as fotrin, is an alkylating antineoplastic and immunosuppressant. The drug entered...

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High-refractive-index polymer
Selasa, 2026-08-11 10:43:22

environment. Phosphorus-containing groups, such as phosphonates and phosphazenes, often exhibit high molar refractivity and optical transmittance in the...

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Outline of organic chemistry
Rabu, 2026-08-12 14:09:34

Organolithiums Organosilanes Organophosphate Compounds Polyphosphates Phosphazenes Iminophosphoranes Polyphosphazenes Phosphinates Phosphines Diphosphines...

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Hexafluorophosphazene
Rabu, 2026-06-17 05:54:10

hypothetical compound N≡PF2 (phosphazyl difluoride). Its classification as a phosphazene highlights its relationship to benzene. Hexafluorophosphazene has a hexagonal...

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Β-Butyrolactone
Minggu, 2026-08-16 15:05:20

diazabicycloundecene (DBU), 1,5,7-triazabicyclo(4.4.0)dec-5-en (TBD) and the phosphazene BEMP are able to catalyze the ring-opening polymerization of β-butyrolactone...

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Fluorescent glucose biosensor
Selasa, 2026-03-31 22:14:09

PHB, PVA, PNVP, P(HEMA),[clarification needed] p(biscarboxy-phenoxy-phosphazene), p(GEMA-sulfate), and others), or a hybrid of the two. In addition to...

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