Petroleum ether is the petroleum fraction consisting of aliphatichydrocarbons and boiling in the range 35–60 °C, and commonly used as a laboratory solvent.[4] Despite the name, petroleum ether is not an ether.
Properties
litre bottle
Petroleum ether consists mainly of aliphatic hydrocarbons and is usually low in aromatics. It is commonly hydrodesulfurized and may be hydrogenated to reduce the amount of aromatic and other unsaturated hydrocarbons.[5]
Standards
DIN 51630 has an initial boiling point above 25 °C, and its final boiling point up to 80 °C.[5]
The naphtha mixtures that are distilled at a lower boiling temperature have a higher volatility and, generally speaking, a higher degree of toxicity than the higher boiling fractions.[6]
Inhalation overexposure causes primarily central nervous system (CNS) effects (headaches, dizziness, nausea, fatigue, and incoordination). In general, the toxicity is more pronounced with petroleum ethers containing higher concentrations of aromatic compounds. n-Hexane causes axonal damage in peripheral nerves.[3]