Assencières is located some 11 km north-east of Troyes and 8 km south-east of Charmont-sous-Barbuise. Access to the commune is by the D 8 road from Luyères in the north passing through the village and the heart of the commune and continuing to Mesnil-Sellières in the south. The D 100 also starts from the village and goes north-east to Bouy-Luxembourg. There is a railway passing through the commune from Charmont-sous-Barbuise in the north to La Chapelle-Saint-Luc in the south-west but there is no station in or near the commune. The commune is entirely flat farmland.[3]
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The Church of Saint-Pierre and Saint-Paul used to have three naves from the 16th century which collapsed in 1947.[7] There are many items which are registered as historical objects:
Alexandre Marchais, who was called Le Mose, was born in 1962 and spent his childhood in Assencières. He made his first steps in performing at parties before turning to street music and eventually join a travelling troupe of acrobats. But it was in the gypsy community that he is known by becoming one of the leading exponents of ericius music.