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Phosphide bromides or bromide phosphides are compounds containing anions composed of bromide (Br⁻) and phosphide (P³⁻) anions. Usually phosphorus is covalently connected into more complex structures. They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the phosphide chlorides, phosphide iodides, nitride bromides, arsenide bromides, and antimonide bromides.

List

formula	system	space group	unit cell Å	volume	density	comment	ref
Ca₂PBr	cubic	I43d	a=5.96 Z=2			red brown	^[1]
Ca₂PBr	hexagonal	R3m	a=4.23 c=20.9 Z=3				^[1]
Cu₁₂P₂₀Br₁₀	triclinic	P	a = 9.886, b = 13.190, c = 14.763, α = 70.83°, β = 82.68°, γ = 80.13°, Z = 2	1786.1			^[2]
Cu₁₃P₁₅Br₁₂							^[3]
Cu₆PS₅Br	cubic	P43m	a=9.732 Z=4	921.8	4.701	red	^[4]
(CuBr)₂P₈Se₃	orthorhombic	Pbcm	a=8.761 b=11.957 c=13.858 Z=4	1451.8			^[5]
Sr₂PBr	cubic	I43d	a=9.31 Z=2			brown violet	^[1]
Sr₂PBr	hexagonal	R3m	a=4.44 c=22.0 Z=3			dark reddish brown	^[1]
Sr₂P₇Br	cubic	P2₁3	a=9.789 Z=4	938.0	3.342	red band gap 2.1 eV	^[6]
Y₂PBr₂	rhombohedral		a=3.9807 c=29.250				^[7]
Ag₆PS₅Br	cubic	P43m	a=10.3765 Z=4	1117.26	5.460	red	^[4]
Cd₅P₂Br₄	orthorhombic	Pna2₁	a=12.189, b=7.7080, c=13.664				^[8]
Sn₂₄P_19.3Br₈							^[9]
Sn₁₇Zn₇P₂₂Br₈	cubic	Pm3n	a=10.7449				^[10]
Sn_24−xIn_xP_19.2+0.2x x<16	cubic	Pm3n					^[11]
Si_30+xP_16–xTe_8–xBr_x x = 1–6.4	cubic	Pm3n	a=9.9720 - 10.0405				^[12]
Ba₂PBr	hexagonal	R3m	a=4.67 c=23.3 Z=3				^[1]
Ba₂P₇Br	monoclinic	P2₁/m	a=6.294 b=6.835 c=11.850 β=95.819 Z=2	507.2	3.742	orange	^[13]
La₂PBr₂	trigonal	P3m1	a=4.311 c=11.000 Z=1	177.04	5.28		^[7]
La₃Zn₄P_6.6Br_0.8	orthorhombic	Cmcm	a=4.099 b=14.229 c=20.388 Z=4	1189.0	5.290	black	^[14]
Eu₂PBr		R3m	a = 4.385, c = 21.90, Z = 3				^[15]
W₄(PBr)Br₁₀	monoclinic	C12/m1	a=14.0933 b=10.3228 c=11.8169 β=93.906 Z=4	1715.16		dark green	^[16]
Hg₂P₃Br	orthorhombic	Pbcn	a = 8.014, b = 8.902, c = 7.823, Z = 4				^[17]
Hg₇P₄Br₆	monoclinic	P2₁/c	a = 6.0452, b = 19.848, c = 7.5596 β = 104.214° Z=2	879.3	7.582	brown	^[18]
(Hg₂P)₂HgBr₄	monoclinic	P2₁	a=7.776 b=12.226 c=7.930 β=121.34 Z=2	643.9	7.141	discovered in 1907; bright yellow; air with light sensitive	^[19]
[Hg₇P₄Br₃](SnBr₃)	cubic	P2₁3	a=12.490 Z=4				^[20]

References

^ ^a ^b ^c ^d ^e Hadenfeldt, Claus; Kosiol, Wilfried (1975-06-01). "Darstellung und Eigenschaften von Phosphidbromiden des Calciums, Strontiums und Bariums / Preparation and Properties of Phosphide Bromides of Calcium, Strontium, and Barium". Zeitschrift für Naturforschung B. 30 (5–6): 378–384. doi:10.1515/znb-1975-5-616. ISSN 1865-7117. S2CID 94967271.
^ Freudenthaler, E.; Pfitzner, A. (1997-02-01). Freudenthaler, E.; Pfitzner, A. (eds.). "Crystal structure of Cu 12 P 20 Br 10 , a polyphosphide containing a new phosphorus polymer". Zeitschrift für Kristallographie - Crystalline Materials. 212 (2): 103–109. Bibcode:1997ZK....212..103F. doi:10.1524/zkri.1997.212.2.103. ISSN 2194-4946.
^ Freudenthaler, E (November 1997). "Copper(I) halide-phosphorus adducts: a new family of copper(I) ion conductors". Solid State Ionics. 101–103: 1053–1059. doi:10.1016/S0167-2738(97)00169-0.
^ ^a ^b Gao, Lihua; Wu, Xiaowen; Yang, Daqing; Tian, Xinyu; Xu, Jingjing; Zhang, Bingbing; Wu, Kui (2021). "M 6 PS 5 X (M = Ag, Cu; X = Cl, Br) chalcohalides exhibiting strong nonlinear optical responses and high laser damage resistances". Dalton Transactions. 50 (48): 17901–17905. doi:10.1039/D1DT03251H. ISSN 1477-9226. PMID 34851337. S2CID 244148134.
^ Nilges, S.; Nilges, T.; Haeuseler, H.; Pfitzner, A. (November 2004). "(CuBr)2P8Se3: preparation, structural, and vibrational spectroscopic characterization of an adduct of P8Se3 cages to Cu2Br2 rhombs". Journal of Molecular Structure. 706 (1–3): 89–94. Bibcode:2004JMoSt.706...89N. doi:10.1016/j.molstruc.2004.01.037.
^ Dolyniuk, Juli-Anna; Tran, Nhon; Lee, Kathleen; Kovnir, Kirill (July 2015). "Sr 2 P 7 X ( X = Cl, Br, and I): Synthesis, Crystal and Electronic Structures of Double Zintl Salts Containing Heptaphosphanortricyclane, P 7 3-: Double Zintl Salts with Heptaphosphanortricyclane, P 7 3-". Zeitschrift für anorganische und allgemeine Chemie. 641 (8–9): 1422–1427. doi:10.1002/zaac.201500140.
^ ^a ^b Oeckler, Oliver; Mattausch, Hansjürgen; Simon, Arndt (2007-11-01). "Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds". Zeitschrift für Naturforschung B. 62 (11): 1377–1382. doi:10.1515/znb-2007-1105. ISSN 1865-7117. S2CID 95077294.
^ M.M., Shatruk; L.N., Reshetova; A.V., Shevel'kov; B.A., Popovkin (2000). "Cd₅P₂Br₄ - the first cadmium analogue of salts of Millon's base" [Cd₅P₂Br₄ - the first cadmium analogue of salts of Millon's base]. Zhurnal Neorganicheskoj Khimii (in Russian). 45 (4). ISSN 0044-457X.
^ Stefanoski, S.; Reshetova, L. N.; Shevelkov, A. V.; Nolas, G. S. (July 2009). "Low-Temperature Transport Properties of Sn24P19.3Br8 and Sn17Zn7P22Br8". Journal of Electronic Materials. 38 (7): 985–989. Bibcode:2009JEMat..38..985S. doi:10.1007/s11664-008-0644-8. ISSN 0361-5235. S2CID 135898461.
^ Kovnir, Kirill A.; Shatruk, Mikhail M.; Reshetova, Lyudmila N.; Presniakov, Igor A.; Dikarev, Evgeny V.; Baitinger, Michael; Haarmann, Frank; Schnelle, Walter; Baenitz, Michael; Grin, Yuri; Shevelkov, Andrei V. (August 2005). "Novel compounds Sn20Zn4P22−vI8 (), Sn17Zn7P22I8, and Sn17Zn7P22Br8: Synthesis, properties, and special features of their clathrate-like crystal structures". Solid State Sciences. 7 (8): 957–968. doi:10.1016/j.solidstatesciences.2005.04.002.
^ Reshetova, L. N.; Shevelkov, A. V. (January 2012). "Synthesis and clathrate-type crystal structure of a solid solution in the Sn-In-P-Br system". Russian Chemical Bulletin. 61 (1): 28–32. doi:10.1007/s11172-012-0004-y. ISSN 1066-5285. S2CID 95316491.
^ Abramchuk, Nikolay S.; Carrillo-Cabrera, Wilder; Veremchuk, Igor; Oeschler, Niels; Olenev, Andrei V.; Prots, Yurii; Burkhardt, Ulrich; Dikarev, Evgeny V.; Grin, Juri; Shevelkov, Andrei V. (2012-11-05). "Homo- and Heterovalent Substitutions in the New Clathrates I Si 30 P 16 Te 8– x Se x and Si 30+ x P 16– x Te 8– x Br x : Synthesis, Crystal Structure, and Thermoelectric Properties". Inorganic Chemistry. 51 (21): 11396–11405. doi:10.1021/ic3010097. ISSN 0020-1669. PMID 23072375.
^ Dolyniuk, Juli-Anna; Kovnir, Kirill (2013-08-26). "Zintl Salts Ba2P7X (X = Cl, Br, and I): Synthesis, Crystal, and Electronic Structures". Crystals. 3 (3): 431–442. doi:10.3390/cryst3030431. ISSN 2073-4352.
^ Wang, Jian; Kaseman, Derrick; Lee, Kathleen; Sen, Sabyasachi; Kovnir, Kirill (2016-07-12). "Enclathration of X@La 4 Tetrahedra in Channels of Zn–P Frameworks in La 3 Zn 4 P 6 X (X = Cl, Br)". Chemistry of Materials. 28 (13): 4741–4750. doi:10.1021/acs.chemmater.6b01752. ISSN 0897-4756.
^ Hadenfeldt, C.; Held, W. (September 1986). "Darstellung, eigenschaften und kristallstruktur der Europium(ii)-phosphidhalogenide Eu2PCl, Eu2PBr und Eu2PI". Journal of the Less Common Metals (in German). 123 (1–2): 25–35. doi:10.1016/0022-5088(86)90111-6.
^ Ströbele, Markus; Eichele, Klaus; Meyer, Hans-Jürgen (2015-02-02). "Cluster Harvesting in the WBr 6 –P System". Inorganic Chemistry. 54 (3): 989–992. doi:10.1021/ic502333u. ISSN 0020-1669. PMID 25392957.
^ Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (1994-07-01). Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (eds.). "Helical [unk](P 1− ) chains in the structures of Hg 2 P 3 Br and Hg 2 P 3 Cl". Zeitschrift für Kristallographie - Crystalline Materials. 209 (7): 583–585. Bibcode:1994ZK....209..583S. doi:10.1524/zkri.1994.209.7.583. ISSN 2194-4946.
^ Shevelkov, A.V.; Dikarev, E.V.; Popovkin, B.A. (June 1993). "Syntheses and Crystal Structure of Hg7P4Br6". Journal of Solid State Chemistry. 104 (2): 177–180. Bibcode:1993JSSCh.104..177S. doi:10.1006/jssc.1993.1151.
^ Shevelkov, Andrei V.; Mustyakimov, Marat Yu.; Dikarev, Evgeny V.; Popovkin, Boris A. (1996). "(Hg2P)2HgBr4: a phosphorus analogue of the Millon's base salts". Journal of the Chemical Society, Dalton Transactions (1): 147–148. doi:10.1039/dt9960000147. ISSN 0300-9246.
^ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2002). "A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions". European Journal of Inorganic Chemistry. 2002 (3): 547–553. doi:10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N.

[:0-1] Hadenfeldt, Claus; Kosiol, Wilfried (1975-06-01). "Darstellung und Eigenschaften von Phosphidbromiden des Calciums, Strontiums und Bariums / Preparation and Properties of Phosphide Bromides of Calcium, Strontium, and Barium". Zeitschrift für Naturforschung B. 30 (5–6): 378–384. doi:10.1515/znb-1975-5-616. ISSN 1865-7117. S2CID 94967271.

[2] Freudenthaler, E.; Pfitzner, A. (1997-02-01). Freudenthaler, E.; Pfitzner, A. (eds.). "Crystal structure of Cu 12 P 20 Br 10 , a polyphosphide containing a new phosphorus polymer". Zeitschrift für Kristallographie - Crystalline Materials. 212 (2): 103–109. Bibcode:1997ZK....212..103F. doi:10.1524/zkri.1997.212.2.103. ISSN 2194-4946.

[3] Freudenthaler, E (November 1997). "Copper(I) halide-phosphorus adducts: a new family of copper(I) ion conductors". Solid State Ionics. 101–103: 1053–1059. doi:10.1016/S0167-2738(97)00169-0.

[:1-4] Gao, Lihua; Wu, Xiaowen; Yang, Daqing; Tian, Xinyu; Xu, Jingjing; Zhang, Bingbing; Wu, Kui (2021). "M 6 PS 5 X (M = Ag, Cu; X = Cl, Br) chalcohalides exhibiting strong nonlinear optical responses and high laser damage resistances". Dalton Transactions. 50 (48): 17901–17905. doi:10.1039/D1DT03251H. ISSN 1477-9226. PMID 34851337. S2CID 244148134.

[5] Nilges, S.; Nilges, T.; Haeuseler, H.; Pfitzner, A. (November 2004). "(CuBr)2P8Se3: preparation, structural, and vibrational spectroscopic characterization of an adduct of P8Se3 cages to Cu2Br2 rhombs". Journal of Molecular Structure. 706 (1–3): 89–94. Bibcode:2004JMoSt.706...89N. doi:10.1016/j.molstruc.2004.01.037.

[6] Dolyniuk, Juli-Anna; Tran, Nhon; Lee, Kathleen; Kovnir, Kirill (July 2015). "Sr 2 P 7 X ( X = Cl, Br, and I): Synthesis, Crystal and Electronic Structures of Double Zintl Salts Containing Heptaphosphanortricyclane, P 7 3-: Double Zintl Salts with Heptaphosphanortricyclane, P 7 3-". Zeitschrift für anorganische und allgemeine Chemie. 641 (8–9): 1422–1427. doi:10.1002/zaac.201500140.

[degruyter.com-7] Oeckler, Oliver; Mattausch, Hansjürgen; Simon, Arndt (2007-11-01). "Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds". Zeitschrift für Naturforschung B. 62 (11): 1377–1382. doi:10.1515/znb-2007-1105. ISSN 1865-7117. S2CID 95077294.

[8] M.M., Shatruk; L.N., Reshetova; A.V., Shevel'kov; B.A., Popovkin (2000). "Cd₅P₂Br₄ - the first cadmium analogue of salts of Millon's base" [Cd₅P₂Br₄ - the first cadmium analogue of salts of Millon's base]. Zhurnal Neorganicheskoj Khimii (in Russian). 45 (4). ISSN 0044-457X.

[9] Stefanoski, S.; Reshetova, L. N.; Shevelkov, A. V.; Nolas, G. S. (July 2009). "Low-Temperature Transport Properties of Sn24P19.3Br8 and Sn17Zn7P22Br8". Journal of Electronic Materials. 38 (7): 985–989. Bibcode:2009JEMat..38..985S. doi:10.1007/s11664-008-0644-8. ISSN 0361-5235. S2CID 135898461.

[10] Kovnir, Kirill A.; Shatruk, Mikhail M.; Reshetova, Lyudmila N.; Presniakov, Igor A.; Dikarev, Evgeny V.; Baitinger, Michael; Haarmann, Frank; Schnelle, Walter; Baenitz, Michael; Grin, Yuri; Shevelkov, Andrei V. (August 2005). "Novel compounds Sn20Zn4P22−vI8 (), Sn17Zn7P22I8, and Sn17Zn7P22Br8: Synthesis, properties, and special features of their clathrate-like crystal structures". Solid State Sciences. 7 (8): 957–968. doi:10.1016/j.solidstatesciences.2005.04.002.

[11] Reshetova, L. N.; Shevelkov, A. V. (January 2012). "Synthesis and clathrate-type crystal structure of a solid solution in the Sn-In-P-Br system". Russian Chemical Bulletin. 61 (1): 28–32. doi:10.1007/s11172-012-0004-y. ISSN 1066-5285. S2CID 95316491.

[12] Abramchuk, Nikolay S.; Carrillo-Cabrera, Wilder; Veremchuk, Igor; Oeschler, Niels; Olenev, Andrei V.; Prots, Yurii; Burkhardt, Ulrich; Dikarev, Evgeny V.; Grin, Juri; Shevelkov, Andrei V. (2012-11-05). "Homo- and Heterovalent Substitutions in the New Clathrates I Si 30 P 16 Te 8– x Se x and Si 30+ x P 16– x Te 8– x Br x : Synthesis, Crystal Structure, and Thermoelectric Properties". Inorganic Chemistry. 51 (21): 11396–11405. doi:10.1021/ic3010097. ISSN 0020-1669. PMID 23072375.

[13] Dolyniuk, Juli-Anna; Kovnir, Kirill (2013-08-26). "Zintl Salts Ba2P7X (X = Cl, Br, and I): Synthesis, Crystal, and Electronic Structures". Crystals. 3 (3): 431–442. doi:10.3390/cryst3030431. ISSN 2073-4352.

[14] Wang, Jian; Kaseman, Derrick; Lee, Kathleen; Sen, Sabyasachi; Kovnir, Kirill (2016-07-12). "Enclathration of X@La 4 Tetrahedra in Channels of Zn–P Frameworks in La 3 Zn 4 P 6 X (X = Cl, Br)". Chemistry of Materials. 28 (13): 4741–4750. doi:10.1021/acs.chemmater.6b01752. ISSN 0897-4756.

[15] Hadenfeldt, C.; Held, W. (September 1986). "Darstellung, eigenschaften und kristallstruktur der Europium(ii)-phosphidhalogenide Eu2PCl, Eu2PBr und Eu2PI". Journal of the Less Common Metals (in German). 123 (1–2): 25–35. doi:10.1016/0022-5088(86)90111-6.

[16] Ströbele, Markus; Eichele, Klaus; Meyer, Hans-Jürgen (2015-02-02). "Cluster Harvesting in the WBr 6 –P System". Inorganic Chemistry. 54 (3): 989–992. doi:10.1021/ic502333u. ISSN 0020-1669. PMID 25392957.

[17] Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (1994-07-01). Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (eds.). "Helical [unk](P 1− ) chains in the structures of Hg 2 P 3 Br and Hg 2 P 3 Cl". Zeitschrift für Kristallographie - Crystalline Materials. 209 (7): 583–585. Bibcode:1994ZK....209..583S. doi:10.1524/zkri.1994.209.7.583. ISSN 2194-4946.

[18] Shevelkov, A.V.; Dikarev, E.V.; Popovkin, B.A. (June 1993). "Syntheses and Crystal Structure of Hg7P4Br6". Journal of Solid State Chemistry. 104 (2): 177–180. Bibcode:1993JSSCh.104..177S. doi:10.1006/jssc.1993.1151.

[19] Shevelkov, Andrei V.; Mustyakimov, Marat Yu.; Dikarev, Evgeny V.; Popovkin, Boris A. (1996). "(Hg2P)2HgBr4: a phosphorus analogue of the Millon's base salts". Journal of the Chemical Society, Dalton Transactions (1): 147–148. doi:10.1039/dt9960000147. ISSN 0300-9246.

[20] Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2002). "A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions". European Journal of Inorganic Chemistry. 2002 (3): 547–553. doi:10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N.

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