Barium bromide

Barium bromide
Barium bromide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.024 Edit this at Wikidata
EC Number
  • 234-140-0
UNII
  • InChI=1S/Ba.2BrH/h;2*1H/q+2;;/p-2 checkY
    Key: NKQIMNKPSDEDMO-UHFFFAOYSA-L checkY
  • InChI=1/Ba.2BrH/h;2*1H/q+2;;/p-2
    Key: NKQIMNKPSDEDMO-NUQVWONBAE
  • Br[Ba]Br
  • [Ba+2].[Br-].[Br-]
Properties
BaBr2 (anhydrous)

BaBr2·2H2O (dihydrate)

Molar mass 297.14 g/mol
Appearance White solid
Density 4.78 g/cm3 (anhydrous)
3.58 g/cm3 (dihydrate)
Melting point 857 °C (1,575 °F; 1,130 K)
Boiling point 1,835 °C (3,335 °F; 2,108 K)
92.2 g/100 mL (0°C)
-92.0·10−6 cm3/mol
Structure
PbCl2-type (orthorhombic, oP12)
Pnma (No. 62)
Thermochemistry
−181.1 kcal/mol
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
 Toxic
GHS labelling:
GHS07: Exclamation mark
Warning
H302, H332
P261, P264, P270, P271, P301+P312, P304+P312, P304+P340, P312, P330, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
3
0
0
Safety data sheet (SDS) NIH BaBr
Related compounds
Other anions
 Barium fluoride
Barium chloride
Barium iodide
Other cations
 Beryllium bromide
Magnesium bromide
Calcium bromide
Strontium bromide
Radium bromide
Lead bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Barium bromide is the chemical compound with the formula BaBr2. It is ionic and hygroscopic in nature.

Structure and properties

BaBr2 crystallizes in the lead chloride (cotunnite) motif, giving white orthorhombic crystals that are deliquescent.[1][2]

Coordination geometry of ions in barium bromide[1][3][4]
Ion Ba2+ Br− (tetrahedral) Br− (trigonal)
Coordination sphere {BaBr9} {BrBa4} {BrBa3}
Ball-and-stick model
Coordination number 9 4 3
Coordination geometry (7+2) coordination[5]
distorted tricapped trigonal prismatic 		distorted tetrahedral trigonal pyramidal

In aqueous solution BaBr2 behaves as a simple salt.

Solutions of barium bromide reacts with the sulfate salts to produce a solid precipitate of barium sulfate.

BaBr2 + SO2−
4 → BaSO4 + 2 Br−

Similar reactions occur with oxalic acid, hydrofluoric acid, and phosphoric acid, giving solid precipitates of barium oxalate, fluoride, and phosphate, respectively.

Preparation

Barium bromide can be prepared by treating barium sulfide or barium carbonate with hydrobromic acid:

BaS + 2 HBr → BaBr2 + H2S
BaCO3 + 2 HBr → BaBr2 + CO2 + H2O

Barium bromide crystallizes from concentrated aqueous solution in its dihydrate, BaBr2·2H2O. Heating this dihydrate to 120 °C gives the anhydrous salt.[6]

Uses

Barium bromide is a precursor to chemicals used in photography and to other bromides.
Historically, barium bromide was used to purify radium in a process of fractional crystallization devised by Marie Curie. Since radium precipitates preferentially in a solution of barium bromide, the ratio of radium to barium in the precipitate would be higher than the ratio in the solution.[7]

Safety

Barium bromide, along with other water-soluble barium salts (e.g. barium chloride), is toxic. However, there is no conclusive data available on its hazards.[8]

The compound appears in the intro title card of Breaking Bad, where the first pairs of letters are replaced with Br35 and Ba56, the symbols and atomic numbers of bromine and barium respectively.

References

  1. ^ a b Brackett, Elizabeth B.; Brackett, Thomas E.; Sass, Ronald L. (1963). "The Crystal Structures of Barium Chloride, Barium Bromide, and Barium Iodide". J. Phys. Chem. 67 (10): 2132–2135. doi:10.1021/j100804a038.
  2. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 117–119. ISBN 978-0-08-037941-8.
  3. ^ "Information card for entry 1527183". Crystallography Open Database. 1963. Retrieved 2021-03-26.
  4. ^ "ICSD 15706 : ICSD Structure : Ba Br2". Cambridge Structural Database: Access Structures. Cambridge Crystallographic Data Centre. Retrieved 2021-03-26.
  5. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 382. ISBN 978-0-08-037941-8.
  6. ^ Patnaik, Pradyot (2003), Handbook of Inorganic Chemical Compounds, McGraw-Hill Professional, pp. 81–82, ISBN 978-0-07-049439-8, retrieved 2007-12-03
  7. ^ Sime, Ruth Lewin (1996), Lise Meitner: A Life in Physics, University of California Press, p. 233, ISBN 978-0-520-20860-5, retrieved 2007-12-03
  8. ^ https://www.sigmaaldrich.com/MSDS/MSDS/DisplayMSDSPage.do?country=US&language=en&productNumber=413607&brand=ALDRICH |