*Club domestic league appearances and goals, correct as of 23:50, 15 August 2024 (UTC) ‡ National team caps and goals, correct as of 23:58, 10 October 2024 (UTC)
Djené was named in the Coton Sport's squad for the 2012 CAF Champions League campaign.[4] In November 2013, he went on a trial at Ligue 2 side RC Lens,[5] only returning to his parent club six months later.[6]
In August 2014, Djené went on a trial at Spanish Segunda División side AD Alcorcón,[7] joining the club permanently on 25 October.[8] He made his debut on the following day, starting in a 1–3 home loss against Real Zaragoza.[9]
On 23 March 2015, after already being a regular starter for the Madrid side, Djené renewed his contract until 2018.[10] On 9 May, he scored his first professional goal, netting the game's only in an away success at CE Sabadell FC.
Djené's debut in the top division of Spanish football came on 20 August 2017, starting in a 0–0 away draw against Athletic Bilbao.[13] He scored his first goal in the category on 17 March, netting the equalizer in a 2–1 away defeat of Real Sociedad.
Djené was included in Didier Six's 23-man squad for the 2013 Africa Cup of Nations,[15] and appeared in all of Togo's matches during the tournament, being eventually knocked out in the quarter-finals. He has made over 65 appearances for Togo.