顺,顺-1,3,5-三胺基环己烷

顺,顺-1,3,5-三胺基环己烷
IUPAC名
(1s,3s,5s)-Cyclohexane-1,3,5-triamine
别名 TACH；cis,cis-Cyclohexane-1,3,5-triamine
识别
CAS号 26150-46-9
PubChem 427712
ChemSpider 19549297
SMILES
 
  • C1[C@@H](C[C@@H](C[C@@H]1N)N)N
性质
化学式 C6H15N3
摩尔质量 129.2 g·mol−1
外观 无色液体
沸点 285 °C（558 K）
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

顺,顺-1,3,5-三胺基环己烷是一种有机化合物，化学式为(CH2CHNH2)3。它属于三胺。在三胺基环己烷的众多同分异构体中，顺,顺-1,3,5-衍生物引起了关注，因为它是一种常见的三足配体（英语：tripodal ligand），缩写为tach。它是一种无色的油状液体，也是常用的三齿配体。

它由环己烷的三氨基甲酸酯制备。这个三氨基甲酸酯由环己烷三羧酸开始通过库尔提斯重排反应生成。[1]

Structure of [Ni(TACH)(H2O)3]2+ (color code: blue = nitrogen, red = oxygen; dark blue = nickel).[2]

相关配体

参考文献

  1. ^ Bowen, Tom; Planalp, Roy P.; Brechbiel, Martin W. An improved synthesis of cis,cis-1,3,5-triaminocyclohexane. Synthesis of novel hexadentate ligand derivatives for the preparation of gallium radiopharmaceuticals. Bioorganic & Medicinal Chemistry Letters. 1996, 6 (7): 807–810. doi:10.1016/0960-894X(96)00110-2. 
  2. ^ Schwarzenbach, Gerold; Bürgi, Hans-Beat; Jensen, William P.; Lawrance, Geoffrey A.; Mønsted, Lene; Sargeson, Alan M. Acid cleavage of nickel(II) complexes containing cis,cis-1,3,5-cyclohexanetriamine (TACH), crystal structure of [Ni(tach)(H2O)3](NO3)2, and a correlation between the structure and reactivity of nickel–polyamine complexes. Inorganic Chemistry. 1983, 22 (26): 4029–4038. doi:10.1021/ic00168a042. 

Read other articles:

Calophyllum

Calophyllum Bunga nyamplung (Calophyllum inophyllum) Klasifikasi ilmiah Kerajaan: Plantae Divisi: Magnoliophyta Kelas: Magnoliopsida Ordo: Malpighiales Famili: Clusiaceae Subfamili: Kielmeyeroideae Tribus: Calophylleae Genus: CalophyllumL., 1753[1] Spesies Lihat pada teks. Calophyllum (dari bahasa Yunani: kalos yang artinya cantik, dan phullon yang artinya daun) adalah genus dari sekitar 200 spesies tanaman hijau abadi dari suku Clusiaceae. Calophyllum dapat ditemukan di Madagaskar, ...

 

Franklin Chang Díaz

Dalam nama Spanyol ini, nama keluarganya adalah Chang. Franklin Chang DíazChang Díaz pada 1997Lahir5 April 1950 (umur 73)San José, Kosta RikaKebangsaanKosta Rika dan Amerika SerikatAlmamaterUniversitas Connecticut (BS, 1973)Massachusetts Institute of Technology (ScD, 1977)PekerjaanFisikawan, insinyur, wirausahawanKarier luar angkasaBotanis NASAWaktu di luar angkasa66 hari 18 jam 16 menitSeleksi1980 NASA GroupMisiSTS-61-C, STS-34, STS-46, STS-60, STS-75, STS-91, STS-111.Lambang misi Fr...

 

The Perfect Husband

The Perfect HusbandSutradaraRudi AryantoProduserSukhdev SinghWicky V. OlindoSkenarioSukhdev SinghTisa TSBenni SetiawanBerdasarkannovel The Perfect Husbandkarya Indah RiyanaPemeran Dimas Anggara Amanda Rawles Maxime Bouttier Slamet Rahardjo Tanta Ginting Bunga Zainal Maya Wulan Dolly Martin Ade Yunita Claudy Putri Maudy Effrosina Carmela Van der Kruk Penata musikJoseph S. DjafarSinematograferRoy LolangPenyuntingWawan I. WibowoPerusahaanproduksiScreenplay FilmsLegacy PicturesDistributorSc...

Danau Tangxun

Danau Tangxun汤逊湖Tangxun Hu, Danau Tangsun, Tangsun Hu, T’ang-sun HuLetakDistrik Hongshan/Distrik Jiangxia, Wuhan, HubeiBagian dariCekungan Sungai YangtzeTerletak di negaraTiongkokArea permukaan> 476 km2 (184 sq mi)Ketinggian permukaan10 meter (33 ft)KepulauanPulau Zanglong (藏龙岛)[1] Danau Tangxun Hanzi tradisional: 湯遜湖 Hanzi sederhana: 汤逊湖 Alih aksara Mandarin - Hanyu Pinyin: Tāngxùn Hú Yue (Kantonis) - Jyutping: tong1seon3 wu4 Danau ...

 

الدوري الإيطالي الدرجة الثانية 1981–82

يفتقر محتوى هذه المقالة إلى الاستشهاد بمصادر. فضلاً، ساهم في تطوير هذه المقالة من خلال إضافة مصادر موثوق بها. أي معلومات غير موثقة يمكن التشكيك بها وإزالتها. (نوفمبر 2019) الدوري الإيطالي الدرجة الثانية 1981–82 تفاصيل الموسم الدوري الإيطالي الدرجة الثانية  النسخة 50  البلد ...

 

Copyright

Legal concept regulating rights of a creative work Not to be confused with Copywriting. This article is about the legal right. For the symbol, see Copyright symbol. For the band, see Copyright (band). For the Wikipedia policy, see Wikipedia:Copyrights. Intellectual property Authors' rights Copyleft Copyright Database right Farmers' rights Geographical indication Indigenous intellectual property Industrial design right Integrated circuit layout design protection Moral rights Patent Peasants' r...

Rupa Goswami

Indian guru, poet and philosopher of the Gaudiya Vaishnava tradition (1489-1564) This article needs additional citations for verification. Please help improve this article by adding citations to reliable sources. Unsourced material may be challenged and removed.Find sources: Rupa Goswami – news · newspapers · books · scholar · JSTOR (March 2017) (Learn how and when to remove this template message) Rupa Goswami Part of a series onVaishnavism Supreme dei...

 

Kucing hutan

Kucing hutan Kucing hutan India Status konservasi Risiko Rendah  (IUCN 3.1)[1] CITES Apendiks II (CITES)[1] Klasifikasi ilmiah Genus: Felis Spesies: chaus Subspecies See text Penyebaran kucing hutan pada tahun 2016[1] Sinonim[2] Daftar Felis catolynx Pallas, 1811 F. erythrotus Hodgson, 1836 F. rüppelii von Brandt, 1832 F. jacquemontii Geoffroy Saint-Hilaire, 1844 F. shawiana Blanford, 1876 Lynx chrysomelanotis (Nehring, 1902) Kucing hutan (Felis cha...

 

Gereja Bunda dari Loreta, Warsawa

Gereja Bunda dari LoretaGereja Paroki Bunda dari Loretabahasa Polandia: Kościół Najświętszej Matki Bożej Loretańskiej w WarszawieGereja Bunda dari LoretaLokasiWarsawaNegaraPolandiaDenominasiGereja Katolik RomaArsitekturStatusParokiStatus fungsionalAktifAdministrasiKeuskupanKeuskupan Agung Warsawa Gereja Bunda Maria dari Loreta (bahasa Polandia: Kościół Matki Bożej Loretańskiej) adalah sebuah gereja paroki Katolik yang terletak di Praga, sebuah distrik di Warsawa, Polandia,...

Abisso Milwaukee

Coordinate: 19°35′N 66°30′W / 19.583333°N 66.5°W19.583333; -66.5 Prospettiva della fossa di Porto Rico nella quale si trova l'abisso Milwaukee L'abisso Milwaukee (in inglese: Milwaukee Deep o Milwaukee Depth) è un abisso oceanico facente parte della fossa di Porto Rico, situato a circa 135 km a nord dell'isola di Porto Rico. Scende fino ad una profondità di circa 8 300 metri sotto il livello del mare,[1][2] che ne fanno il punto in assoluto ...

 

Asosa Zone

Zone in Benishangul-Gumuz Region of Ethiopia Map of the regions and zones of Ethiopia Assosa is a zone in Benishangul-Gumuz Region of Ethiopia. This Zone was named after the Assosa Sultanate, which had approximately the same boundaries. Assosa is bordered on the south by the Mao-Komo special woreda, on the west by Sudan, and on the northeast by the Kamashi. The largest town in this zone is Assosa. Its highest point is Mount Bambashi, located in the woreda of the same name. The majority ethnic...

 

Operation Anubis

För en egyptisk gud, se Anubis. För ett släkte av skalbaggar, se Anubis (djur). Operation Anubis Läget utanför ekonomidepartementets byggnad i Barcelona, samtidigt som myndigheten genomsöktes av Guardia Civil. Typ av händelse – spansk polisaktion Tid och plats – 20 september 2017–december 2017,  Katalonien ( Spanien) Mål – återställa respekten för Spaniens grundlag; undanröja risken för eventuellt utlysande av katalansk självständighet Utl�...

منزل الرفاعي

بيت الرفاعيمعلومات عامةنوع المبنى بيت أثريالمكان جزيرة فرسان، منطقة جازانالبلد السعوديةتعديل - تعديل مصدري - تعديل ويكي بيانات بيت الرفاعي أو منزل الرفاعي هو أحد المواقع الأثرية بجزيرة فرسان التابعة لمنطقة جازان جنوب غرب السعودية،[1] وشيد سنة 1341هـ.[2] بنى المنزل تا...

 

Allison Hightower

American basketball player Allison HightowerPersonal informationBorn (1988-04-06) April 6, 1988 (age 36)Dallas, TexasNationalityAmericanListed height5 ft 10 in (1.78 m)Listed weight139 lb (63 kg)Career informationHigh schoolSeguin (Arlington, Texas)CollegeLSU (2006–2010)WNBA draft2010: 2nd round, 15th overall pickSelected by the Connecticut SunPlaying career2010–presentPositionGuardCareer history2010–2014Connecticut Sun2017Washington Mystics Career highligh...

 

The Mission (band)

English gothic rock band This article needs additional citations for verification. Please help improve this article by adding citations to reliable sources. Unsourced material may be challenged and removed.Find sources: The Mission band – news · newspapers · books · scholar · JSTOR (June 2021) (Learn how and when to remove this message) The MissionThe Mission performing in 2017Background informationOriginLeeds, EnglandGenresGothic rockpost-punkhar...

Carl Cheffers

American football official (born 1960) Carl CheffersCheffers in 2019Born (1960-07-22) July 22, 1960 (age 63)Whittier, California, U.S.NationalityAmericanOccupationNFL official (2000–present) Carl Cheffers (born July 22, 1960) is an American football official who officiates games for the National Football League (NFL). He has been an NFL official since the 2000 NFL season.[1] Officiating career As a college student, Cheffers became interested in officiating through his father, a...

 

Kagurabue

Musical instrument The kagurabue (神楽笛) is a six or seven-hole transverse bamboo flute used to support Japanese kagura performance.[1] The Kagurabue can also be known as a yamatobue (大和笛). References ^ David Petersen (March 2007). An Invitation to Kagura: Hidden Gem of the Traditional Japanese Performing Arts. David Petersen. pp. 275–. ISBN 978-1-84753-006-6. Retrieved 17 July 2011. 2 Malm, William P (1959). Japanese music and musical instruments ([1st ed.]). p5...

 

Supermarine Seal II

1920s British flying boat Seal II Role Reconnaissance flying boatType of aircraft Manufacturer Supermarine Designer R.J. Mitchell First flight May 1921 Number built 1 Variants Supermarine Seagull Fleet Spotting Gunnery Amphibian The Supermarine Seal II was a British flying boat developed by Supermarine after it secured a British Air Ministry order for a prototype three-seater fleet spotter amphibian. The prototype, which had to be capable of landing on Royal Air Force (RAF) aircraft carriers...

Nirai Kudam

8 August 1969 Indian film Nirai KudamPosterDirected byMuktha SrinivasanScreenplay byCho[1]Story byMahendran[2]Produced byMuktha RamaswamyStarringSivaji GanesanVanisriCinematographyM. KarnanEdited byL. BaluMusic byV. KumarProductioncompanyMuktha FilmsRelease date 8 August 1969 (1969-08-08) CountryIndiaLanguageTamil Nirai Kudam (transl. Full Pitcher) is a 1969 Indian Tamil-language film, directed by Muktha Srinivasan and produced by V. Ramasamy. The film sta...

 

Pull-off

Stringed instrument playing technique G run in G major variation[1] Playⓘ contains both hammer-ons and a pull-off. A pull-off is a stringed instrument playing and articulation technique performed by plucking or pulling the finger that is grasping the sounding part of a string off the fingerboard of either a fretted or unfretted instrument. This intermediate- to advanced playing technique is done using the tip of a finger or fingernail on the fretting hand. Pull-offs are done to faci...