铂化钡是一种离子化合物,化学式为BaPt,其中含有罕见的负氧化态的铂离子(Pt2−)。
制备
铂化钡可以由铂和钡于1223K在氩气中反应得到:[2]
- Ba + Pt → BaPt
相关化合物
参考资料
- ^ 1.0 1.1 1.2 Jansen, Martin. Effects of relativistic motion of electrons on the chemistry of gold and platinum. Solid State Sciences. 2005-11-30, 7 (12): 1464–1474. doi:10.1016/j.solidstatesciences.2005.06.015.
- ^ Covalently Bonded [Pt]- Chains in BaPt: Extension of the Zintl−Klemm Concept to Anionic Transition Metals? .Andrey Karpov , Jürgen Nuss , Ulrich Wedig 等. J. Am. Chem. Soc., 2004, 126 (43), pp 14123–14128. DOI: 10.1021/ja0401186