硫酸盐亚硒酸盐

硫酸盐亚硒酸盐或硫酸亚硒酸盐是一类混合阴离子化合物（英语：Mixed-anion compounds），它同时含有亚硒酸根（SeO32-）和硫酸根（SO42-）离子。

除非存在有色阳离子，它们一般是无色透明的晶体。自然界中存在的硫酸盐亚硒酸盐矿物有保罗亚当斯石（加泰罗尼亚语：Pauladamsita）和宗像石（日语：宗像石）。

盐类列表

名称 化学式 Se:S比例 分子量 晶系 空间群 晶胞参数（Å） 晶胞体积 密度 注释 参考文献
二羟基硫酸亚硒酸三钴 Co3(SeO3)(SO4)(OH)2 1:1 orthorhombic Pnma a 10.8757 b 6.4782 c 11.1579 [1]
四羟基硫酸亚硒酸四铜二水合物 Cu4(SeO3)(SO4)(OH)4·2H2O 1:1 triclinic P1 a = 6.0742 b = 8.415 c = 10.780 α = 103.665 β = 95.224 γ = 90.004° Z = 2 533.0 绿色 [2]
硫酸亚硒酸镉 Cd4(SeO3)2(SO4)2 1:1 orthorhombic P212121 a=5.3524 b=14.595 c=15.892 [3]
掺硒硫酸焦亚硒酸镉二银 Ag2Cd(Se2O5)(Se0.3S0.7O4) 3.29:1 triclinic P1 a 6.7485 b 6.8504 c 9.769, α 101.36° β 105.95° γ 91.16° [4]
硫酸二亚硒酸镨二水合物 Pr2(SeO3)2(SO4)(H2O)2 2:1 monoclinic C2 a=11.719 b=6.8495 c=6.5043 β=103.265 Z=2 508.18 4.364 浅绿色 [5]
硫酸二亚硒酸钐二水合物 Sm2(SeO3)2(SO4)(H2O)2 2:1 monoclinic C2 [6]
硫酸二亚硒酸镝二水合物 Dy2(SeO3)2(SO4)(H2O)2 2:1 monoclinic C2 [6]
硫酸二亚硒酸镱二水合物 Yb2(SeO3)2(SO4)(H2O)2 2:1 monoclinic C2 [6]
硫酸亚硒酸汞 Hg2(SeO3)(SO4) 1:1 monoclinic P21/c a 6.3799 b 7.0185 c 13.4426 β 94.511° 双折射 0.133 at 532 nm and 0.126 at 1064 nm [4]
硫酸二亚硒酸三汞 Hg3(SeO3)2(SO4) 2:1 monoclinic P21 a 8.1991 b 5.2677 c 11.1199 β 108.399(6)° 白色; 带隙 4.70 eV; SHG 1.3 ×KDP [7]
二硫酸四亚硒酸三汞二镧二水合物 La2Hg3(SeO3)4(SO4)2(H2O)2 2:1 triclinic P1 a 9.1127 b 9.2446 c 13.5562 α 86.099° β 79.267° γ 61.814° [4]
四羟基硫酸亚硒酸二铜二铅 Pb2Cu2(SeO3)(SO4)(OH)4 1:1 monoclinic P21/m a = 9.802 b = 5.675 c = 9.281 β = 102.443 Z = 2 504.2 [8]

参考文献

  1. ^ Zhang, Mengsi; Song, Yujie; Zhao, Zhiying; Li, Jinyang; Zhang, Wanwan; Xie, Yaxin; Huang, Xing; Huang, Xiaoying; He, Zhangzhen. Co 3 (SeO 3 )(SO 4 )(OH) 2 : A Selenite-Sulfate Compound with a Distorted Kagomé Lattice. Inorganic Chemistry. 2020-06-15, 59 (12): 8054–8060 [2023-10-11]. ISSN 0020-1669. PMID 32458677. S2CID 218907334. doi:10.1021/acs.inorgchem.0c00316. （原始内容存档于2023-06-05） （英语）. 
  2. ^ Kampf, A. R.; Mills, S. J.; Nash, B. P. Pauladamsite, Cu 4 (SeO 3 )(SO 4 )(OH) 4 ·2H 2 O, a new mineral from the Santa Rosa mine, Darwin district, California, USA. Mineralogical Magazine. October 2016, 80 (6): 949–958. Bibcode:2016MinM...80..949K. ISSN 0026-461X. S2CID 131877389. doi:10.1180/minmag.2016.080.032 （英语）. 
  3. ^ Xie, Yiming; Wu, Jihuai. Synthesis and Structure of a Cadmium Selenite-Sulfate Cd 4 (SeO 3) 2 (SO 4) 2. Bulletin-Korean Chemical Society. 2007, 28 (8): 1416 [2023-10-11]. doi:10.5012/bkcs.2007.28.8.1416. （原始内容存档于2023-06-05）. 
  4. ^ 4.0 4.1 4.2 Li, Peng-Fei; Hu, Chun-Li; Kong, Fang; Mao, Jiang-Gao. Hg 2 (SeO 3 )(SO 4 ): the first sulfate selenite with large birefringence explored from d 10 transition metal compounds. Materials Chemistry Frontiers. 2022, 6 (23): 3567–3576. ISSN 2052-1537. S2CID 252698858. doi:10.1039/D2QM00773H （英语）. 
  5. ^ Eaton, Teresa. Lanthanide and Actinide Selenites. 2016 [2023-10-11]. （原始内容存档于2023-06-05）. 
  6. ^ 6.0 6.1 6.2 Oyeka, Ebube E.; Winiarski, Michał J.; Świątek, Hanna; Balliew, Wyatt; McMillen, Colin D.; Liang, Mingli; Sorolla, Maurice; Tran, Thao T. Ln 2 (SeO 3 ) 2 (SO 4 )(H 2 O) 2 (Ln=Sm, Dy, Yb): A Mixed‐Ligand Pathway to New Lanthanide(III) Multifunctional Materials Featuring Nonlinear Optical and Magnetic Anisotropy Properties. Angewandte Chemie. 2022-11-25, 134 (48) [2023-10-11]. ISSN 0044-8249. doi:10.1002/ange.202213499 可免费查阅. （原始内容存档于2023-06-05） （英语）. 
  7. ^ Ren, Jinxuan; Chen, Yuqi; Ren, Liying; Zhou, Yuqiao; Dong, Xuehua; Gao, Daojiang; Huang, Ling; Cao, Liling; Ye, Ning. Hg 3 (SeO 3 ) 2 (SO 4 ): A UV Nonlinear Optical Mercury Selenite Sulfate Constructed by Neat [Hg 6 O 8 (SeO 3 ) 4 ] ∞ Layers and SO 4 Tetrahedra. Inorganic Chemistry. 2023-05-31 [2023-10-11]. ISSN 0020-1669. PMID 37256655. S2CID 258988391. doi:10.1021/acs.inorgchem.3c00986. （原始内容存档于2023-06-05） （英语）. 
  8. ^ Kampf, A. R.; Mills, S. J.; Housley, R. M. The crystal structure of munakataite, Pb 2 Cu 2 (Se 4+ O 3 )(SO 4 )(OH) 4 , from Otto Mountain, San Bernardino County, California, USA. Mineralogical Magazine. December 2010, 74 (6): 991–998. ISSN 0026-461X. doi:10.1180/minmag.2010.074.6.991 （英语）. 

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