1,2-二(二苯基膦基)乙烯

1,2-二(二苯基膦基)乙烯
IUPAC名
1,1'-(1Z)-1,2-ethenediylbis[1,1-diphenylphosphine
识别
CAS号 17427-91-7  checkY
983-81-3（1E）  checkY
983-80-2（1Z）  checkY
性质
化学式 C26H22P2
摩尔质量 396.4 g·mol−1
外观 白色固体
熔点 125 °C（398 K）
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

1,2-二(二苯基膦基)乙烯（dppv）是一种有机磷化合物，化学式为C2H2(PPh2)2，其中Ph为C6H5。它的顺式和反式异构体都是已知的，但顺式异构体研究更多。它可由二苯基膦和1,2-二氯乙烯在氢氧化钾的存在下于DMSO中反应得到。[1]它可以和金属形成配合物。[2][3]它可以被过氧化氢氧化为相应的P,P'-二氧化物。[4]

参考文献

  1. ^ Khachatryan, R. A.; Grigoryan, N. Yu.; Indzhikyan, M. G. Acetylenic hydrocarbons and vinyl halides in alkylation of PH acids under phase-transfer catalytic conditions or in superbasic media. Zhurnal Obshchei Khimii, 1994. 64 (8): 1260-1265. ISSN: 0044-460X.
  2. ^ Scott D. Boelter, Dan R. Davies, Peter Margl, Kara A. Milbrandt, Darrek Mort, Britt A. Vanchura, David R. Wilson, Molly Wiltzius, Mari S. Rosen, Jerzy Klosin. Phospholane-Based Ligands for Chromium-Catalyzed Ethylene Tri- and Tetramerization. Organometallics. 2020-04-13, 39 (7): 976–987 [2021-08-02]. ISSN 0276-7333. doi:10.1021/acs.organomet.9b00722 （英语）. 
  3. ^ Ebrahim M. Mothi, Helen Stoeckli-Evans, Krishnaswamy Panchanatheswaran. Reaction of a Rigid Diphosphine, cis -1,2-bis(diphenylphosphino)ethylene with SnBr 4 and SnI 4 : Phosphine and Phosphine Oxide Coordination. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. 2016-09-01, 46 (9): 1371–1375 [2021-08-02]. ISSN 1553-3174. doi:10.1080/15533174.2015.1136953 （英语）. 
  4. ^ Paul T. Morse, Richard J. Staples, Shannon M. Biros. Th(IV) complexes with cis-ethylenebis(diphenylphosphine oxide): X-ray structures and NMR solution studies. Polyhedron. 2016-08, 114: 2–12 [2021-08-02]. doi:10.1016/j.poly.2015.05.016. （原始内容存档于2020-02-20） （英语）. 

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