双氟配合物

双氟配合物是一种配合物，由氟气分子 (F2) 和另外一个分子组成。 第一个双氟配合物是七氟化金 (AuF7)。[1] 它看起来像一种七价金化合物， 但事实上AuF7 更像是五氟化金 (AuF5) 和 F2形成的配合物。 该结论得到了计算的多次支持。 不像双氢配合物，结构上为 η2-H2， 双氟配合物的结构是 η1-F2 （末端）。[2]

参见

参考资料

  1. ^ Timakov, A. A.; Prusakov, V. N.; Drobyshevskii, Y. V. Gold Heptafluoride. Doklady Akademii Nauk SSSR. 1986, 291: 125–128 （俄语）. 
  2. ^ Conradie, Jeanet; Ghosh, Abhik. Theoretical Search for the Highest Valence States of the Coinage Metals: Roentgenium Heptafluoride May Exist. Inorganic Chemistry. 2019, 58 (13): 8735–8738. PMID 31203606. doi:10.1021/acs.inorgchem.9b01139. 

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