Amonyum bisülfat

 

Amonyum bisülfat
Ball-and-stick model of an ammonium cation (left) and a bisulfite anion (right)
Adlandırmalar
IUPAC adı
Amonyum hidrojen sülfat
Tanımlayıcılar
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.332 Bunu Vikiveri'de düzenleyin
RTECS numarası
  • WS990000
UNII
  • InChI=1S/H3N.H2O4S/c;1-5(2,3)4/h1H3;(H2,1,2,3,4) 
    Key: BIGPRXCJEDHCLP-UHFFFAOYSA-N 
  • InChI=1/H3N.H2O4S/c;1-5(2,3)4/h1H3;(H2,1,2,3,4)
    Key: BIGPRXCJEDHCLP-UHFFFAOYAA
  • [O-]S(=O)(=O)O.[NH4+]
Özellikler
Molekül formülü (NH4)HSO4
Molekül kütlesi 115.11 g/mol
Görünüm Kristal Beyaz
Yoğunluk 1.78 g/cm3
Erime noktası 147 °C (297 °F; 420 K)
Çözünürlük (su içinde) Çok çözünür
Çözünürlük (başka çözücü içinde) Metanol'de çözünür
Aseton'da çözünmez.
Tehlikeler
NFPA 704
(yangın karosu)
NFPA 704 four-colored diamondSağlık 3: Kısa maruziyet ciddi geçici veya kalıcı hasara neden olabilir. Örnek: Klor gazıYanıcılık 0: Yanmaz. Örnek: SuKararsızlık 0: Genellikle yangın maruziyeti koşullarında dahi normalde kararlıdır ve su ile reaksiyona girmez. Örnek: Sıvı azotÖzel tehlikeler (beyaz): kod yok
3
0
0
Güvenlik bilgi formu (SDS) External MSDS
Benzeyen bileşikler
Diğer anyonlar
 Amonyum tiyosülfat
Amonyum sülfit
Amonyum sülfat
Amonyum persülfat
Diğer katyonlar
 Sodyum bisülfat
Potasyum bisülfat
Aksi belirtilmediği sürece madde verileri, Standart sıcaklık ve basınç koşullarında belirtilir (25 °C [77 °F], 100 kPa).
Bilgi kutusu kaynakları

Amonyum hidrojen sülfat olarak da bilinen amonyum bisülfat, (NH4) HSO4 formülüne sahip beyaz, kristalimsi bir katıdır. Bu tuz, sülfürik asidin amonyakla yarı nötralizasyonunun ürünüdür.

Üretimi

Yaygın olarak, ticari kimyasal metil metakrilata giden "aseton siyanohidrin rotası"nın bir yan ürünü olarak toplanır.[1]

Aynı zamanda yüksek saflıkta tuz üreten sülfamik asidin sulu çözelti içinde hidrolizi ile de elde edilebilir:

H
3NSO
3 + H
2O → (NH
4)HSO
4

Ayrıca amonyum sülfatın termal ayrışmasıyla da ortaya çıkar:

(NH
4)
2SO
4 → (NH
4)HSO
4 + NH
3

Uygulamaları

Değerli bir gübre olan amonyum sülfat oluşturmak için amonyakla daha da nötralleştirilebilir. Sodyum bisülfat çok daha yaygın olmasına rağmen, sülfürik asite daha zayıf bir alternatif olarak kullanılabilir.

Doğal oluşumu

(NH4)3 H(SO4) 2 formülünün ilgili bir bileşiği, kömür yangını ortamlarından bilinen nadir mineral letovisit olarak ortaya çıkar.[2][3]

Kaynakça

  1. ^ William Bauer, Jr. "Methacrylic Acid and Derivatives" in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH, Weinheim. DOI:10.1002/14356007.a16_441.
  2. ^ "Letovicite". 15 Nisan 2024 tarihinde kaynağından arşivlendi. Erişim tarihi: 17 Mayıs 2024. 
  3. ^ "List of Minerals". 21 Mart 2011. 15 Mart 2013 tarihinde kaynağından arşivlendi. Erişim tarihi: 17 Mayıs 2024. 

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