Metilamin-korinoid protein Co-metiltransferaza

Metilamin-korinoid protein Co-metiltransferaza
Identifikatori
EC broj2.1.1.248
Baze podataka
IntEnzIntEnz pregled
BRENDABRENDA pristup
ExPASyNiceZyme pregled
KEGGKEGG pristup
MetaCycmetabolički put
PRIAMprofil
Strukture PBPRCSB PDB PDBe PDBj PDBsum

Metilamin-korinoid protein Co-metiltransferaza (EC 2.1.1.248, mtmB (gen), monometilaminska metiltransferaza) je enzim sa sistematskim imenom monometilamin:5-hidroksibenzimidazolilkobamid Co-metiltransferaza.[1][2][3] Ovaj enzim katalizuje sledeću hemijsku reakciju

metilamin + [Co(I) metilamin-specifični korinoidni protein] [metil-Co(III) metilamin-specifični korinoidni protein] + amonijak

Enzim koji katalizuje transfer metil grupa sa metilamina na metilamin-specifični korinoidni protein (MtmC), učestvuje u metanogenezi. Ovaj enzim sadrži neobičnu aminokiselinu pirolizin.

Reference

  1. ^ Burke, S.A. & Krzycki, J.A. (1997). „Reconstitution of Monomethylamine:Coenzyme M methyl transfer with a corrinoid protein and two methyltransferases purified from Methanosarcina barkeri”. J. Biol. Chem. 272: 16570—16577. PMID 9195968. 
  2. ^ Burke, S.A., Lo, S.L. and Krzycki, J.A. (1998). „Clustered genes encoding the methyltransferases of methanogenesis from monomethylamine”. J. Bacteriol. 180: 3432—3440. PMID 9642198. 
  3. ^ Krzycki, J.A. (2004). „Function of genetically encoded pyrrolysine in corrinoid-dependent methylamine methyltransferases”. Curr. Opin. Chem. Biol. 8: 484—491. PMID 15450490. 

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