4-Hidroksifenilacetatna dekarboksilaza

4-Hidroksifenilacetatna dekarboksilaza
Identifikatori
EC broj 4.1.1.83
CAS broj 340137-18-0
IntEnz IntEnz view
BRENDA BRENDA entry
ExPASy NiceZyme view
KEGG KEGG entry
MetaCyc metabolic pathway
PRIAM profile
PDB RCSB PDB PDBe PDBj PDBsum

4-Hidroksifenilacetatna dekarboksilaza (EC 4.1.1.83, p-hidroksifenilacetatna dekarboksilaza, p-Hpd, 4-Hpd, 4-hidroksifenilacetatna karboksilijaza) je enzim sa sistematskim imenom 4-(hidroksifenil)acetat karboksilijaza (formira 4-metilfenol).[1][2][3] Ovaj enzim katalizuje sledeću hemijsku reakciju

(4-hidroksifenil)acetat + H+ 4-metilfenol + CO2

Enzim iz anaerobne Clostridium difficile takođe može da koristi (3,4-dihidroksifenil)acetat kao supstrat, pri čemu se formira 4-metilkatehol kao produkt.

Reference

  1. ↑ D'Ari, L. and Barker, H.A. (1985). „p-Cresol formation by cell-free extracts of Clostridium difficile”. Arch. Microbiol. 143: 311-312. PMID 3938267. 
  2. ↑ Selmer, T. and Andrei, P.I. (2001). „p-Hydroxyphenylacetate decarboxylase from Clostridium difficile. A novel glycyl radical enzyme catalysing the formation of p-cresol”. Eur. J. Biochem. 268: 1363-1372. PMID 11231288. 
  3. ↑ Andrei, P.I., Pierik, A.J., Zauner, S., Andrei-Selmer, L.C. and Selmer, T. (2004). „Subunit composition of the glycyl radical enzyme p-hydroxyphenylacetate decarboxylase. A small subunit, HpdC, is essential for catalytic activity”. Eur. J. Biochem. 271: 2225-2230. PMID 15153112. 

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