Сульфид дититана

Сульфид дититана
Общие
Систематическое
наименование
Сульфид дититана
Традиционные названия Сернистый титан
Хим. формула Ti2S
Физические свойства
Состояние кристаллы
Молярная масса 127,80 г/моль
Плотность 4,8 г/см³
Термические свойства
Температура
 • разложения 1305 °C
Приведены данные для стандартных условий (25 °C, 100 кПа), если не указано иное.

Сульфи́д дитита́на — бинарное неорганическое соединение титана и серы с формулой Ti2S, кристаллы.

Получение

  • Нагревание стехиометрической смеси чистых веществ:

Физические свойства

Сульфид дититана образует кристаллы ромбической сингонии, пространственная группа P nnm, параметры ячейки a = 1,135 нм, b = 1,406 нм, c = 0,332 нм, Z = 12 [1][2][3][4].

Соединение образуется по перитектической реакции при температуре 1410 °C.

Примечания

  1. Диаграммы состояния двойных металлических систем / Под ред. Н. П. Лякишева. — М.: Машиностроение, 2000. — Т. 3 Книга 2. — 448 с. — ISBN 5-217-02932-3.
  2. B. Predel. S-Ti (Sulfur-Titanium) // Landolt-Börnstein - Group IV Physical Chemistry. — 1998. — Т. 5J. — С. 1—4. — doi:10.1007/10551312_2665.
  3. J. L. Murray. The S−Ti (Sulfur-Titanium) system // Bulletin of Alloy Phase Diagrams. — 1986. — Т. 7, № 2. — С. 156—163. — doi:10.1007/BF02881555.
  4. J. P. Owens, B. R. Conrad, N. F. Franzen. The crystal structure of Ti2S // Acta Cryst.. — 1967. — Т. 23. — С. 77—82. — doi:10.1107/S0365110X67002154.


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