ニトロン酸モノオキシゲナーゼ

ニトロン酸モノオキシゲナーゼ（英:nitronate monooxygenase）は、窒素代謝酵素の一つで、次の化学反応を触媒する酸化還元酵素である。

ニトロン酸モノオキシゲナーゼ
識別子
EC番号 1.13.12.16
データベース
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BRENDA BRENDA entry
ExPASy NiceZyme view
KEGG KEGG entry
MetaCyc metabolic pathway
PRIAM profile
PDB構造 RCSB PDB PDBj PDBe PDBsum
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テンプレートを表示
エチルニトロン酸 + O2 + FMNH2 アセトアルデヒド + 亜硝酸 + FMN + H2O

反応式の通り、この酵素の基質はエチルニトロン酸とO2とFMNH2、生成物はアセトアルデヒドと亜硝酸とFMNとH2Oである。

組織名はnitronate:oxygen 2-oxidoreductase (nitrite-forming)で、別名にNMO、2-nitropropane dioxygenase (incorrect)がある。

参考文献

  • Francis, K., Russell, B. and Gadda, G. (2005). “Involvement of a flavosemiquinone in the enzymatic oxidation of nitroalkanes catalyzed by 2-nitropropane dioxygenase.”. J. Biol. Chem. 280: 5195-5204. PMID 15582992. 
  • Ha, J.Y., Min, J.Y., Lee, S.K., Kim, H.S., Kim do, J., Kim, K.H., Lee, H.H., Kim, H.K., Yoon, H.J. and Suh, S.W. (2006). “Crystal structure of 2-nitropropane dioxygenase complexed with FMN and substrate. Identification of the catalytic base.”. J. Biol. Chem. 281: 18660-18667. PMID 16682407. 
  • Gadda, G. and Francis, K. (2009). “Nitronate monooxygenase, a model for anionic flavin semiquinone intermediates in oxidative catalysis.”. Arch. Biochem. Biophys.. PMID 19577534. 
  • Francis, K. and Gadda, G. (2009). “Kinetic evidence for an anion binding pocket in the active site of nitronate monooxygenase.”. Bioorg. Chem. 37: 167-172. PMID 19683782. 

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