Serratinina

 
Serratinina
Nombre IUPAC
11-Metil-8-oxo-2,3,6,7,12,13-hexahidro-1H,5H,8H-indeno[7a],1-H-indolizina
General
Fórmula estructural Imagen de la estructura
Fórmula molecular C16H25NO3
Identificadores
Número CAS 5545-99-3[1]​
ChEBI 6556
ChemSpider 137448
PubChem 156059
UNII HQE44UVY3J
KEGG C09869
InChI=InChI=1S/C30H49N3O/c1-18-11-22-16-28-25(23-15-27(22)29(12-18)32(4)17-23)8-7-24(31-28)14-21-10-19(2)13-30-26(21)6-5-9-33(30)20(3)34/h18-19,21-27,29-30H,5-17H2,1-4H3/t18-,19+,21-,22+,23-,24+,25-,26+,27-,29+,30-/m1/s1
Key: ZGALAVFQYJOLRQ-XLMCSZFMSA-N
Propiedades físicas
Apariencia Prismas (Acetona)
Masa molar 279,378 g/mol
Punto de fusión 244 °C (517 K)
Valores en el SI y en condiciones estándar
(25 ℃ y 1 atm), salvo que se indique lo contrario.
[editar datos en Wikidata]

La serratinina es un alcaloide indolizidínico biosintetizado de la lisina. Este compuesto fue aislado de la planta Lycopodium serratum (Lycopodiaceae). [α]8D = -27.8 (c, 1.44 en EtOH).[2]​[3]​

Biosíntesis

Inubushi propuso el siguiente esquema de biosíntesis para la fawcetidina y la serratinina[4]​





Derivados

 Nombre    Estructura    Fórmula molecular    CAS   Masa molecular (g/mol)   Estado   Fuente natural    Otras propiedades  
Serratezomina B
C16H25NO4 301679-57-2 295.378 Sólido amorfo Aislado de Lycopodium serratum var. serratum[5]​ [α]D = +7 (c, 1.3 en MeOH)
Huperserratinina
C25H33NO5 158182-11-7 427.539 Sólido. PF = 217 - 218 °C. Aislado de Huperzia serrata (Lycopodiaceae)[6]​ [α]D = -3.5 (c, 0.2 en EtOH)
8-Desoxiserratinina
C16H25NO2 18331-31-2 263.379 Sólido con apariencia de columnas (Acetato de etilo o acetona) PF = 223 °C Aislado de Lycopodium serratum (Lycopodiaceae)[7]​ [α]17D = -15.6 ( c, 1.00 en EtOH)
8-Desoxi-13-deshidroserratinina
C16H23NO2 14478-54-7 261.363 Agujas finas PF = 110 -112 °C Aislado de Lycopodium phlegmaria (Lycopodiaceae)[8]​

Referencias

  1. ↑ Número CAS
  2. ↑ Inubushi, Y. et al., Tet. Lett., 1966, 6, 1537- 1549
  3. ↑ Zhou, B.-N. et al., Phytochemistry, 1993, 34, 1425- 1428
  4. ↑ Y. Inubushi, H. Ishii, B. Yasui, T. Harayama, Tetrahedron Lett. 1966, 7, 1551
  5. ↑ Morita, H. et al., JOC, 2000, 65, 6241- 6245
  6. ↑ Zhu, D.-Y. et al., Phytochemistry, 1994, 36, 1069- 1072
  7. ↑ Inubushi, Y. et al., Yakugaku Zasshi, 1967, 87, 1394- 1404
  8. ↑ Ishii, H. et al., Chem. Pharm. Bull., 1970, 18, 1880- 1885


Read other articles:

Bradley Johnson

Bradley Johnson Informasi pribadiNama lengkap Bradley Paul JohnsonTanggal lahir 28 April 1987 (umur 36)Tempat lahir Hackney, London, InggrisTinggi 1,83 m (6 ft 0 in)Posisi bermain GelandangInformasi klubKlub saat ini Derby CountyNomor 15Karier junior1997-2002 Arsenal2003–2004 Cambridge UnitedKarier senior*Tahun Tim Tampil (Gol)2003–2004 Waltham Forest 2004–2005 Cambridge United 1 (0)2005–2008 Northampton Town 53 (8)2005–2006 → Gravesend & Northfleet (pinja...

 

中国人民解放军陆军第十四集团军炮兵旅

陆军第十四集团军炮兵旅陆军旗存在時期1950年 - 2017年國家或地區 中国效忠於 中国 中国共产党部門 中国人民解放军陆军種類炮兵功能火力支援規模约90门火炮直屬南部战区陆军參與戰役1979年中越战争 中越边境冲突 老山战役 成都军区对越轮战 紀念日10月25日 陆军第十四集团军炮兵旅（英語：Artillery Brigade, 14th Army），是曾经中国人民解放军陆军第十四集团军下属�...

 

Gregorio Sablan

Northern Mariana Islander politician (born 1955) Gregorio SablanOfficial portrait, 2009Delegate to theU.S. House of Representativesfrom the Northern Mariana Islands'at-large districtIncumbentAssumed office January 3, 2009Preceded byPedro Tenorio (Resident Representative)Member of the Northern Mariana Islands House of Representativesfrom the 2nd districtIn office1982–1986 Personal detailsBorn (1955-01-19) January 19, 1955 (age 69)Saipan, Mariana Islands, Trust Territory ...

Konrad Rudnicki

Polish astronomer Konrad Rudnicki RighteousAmong the Nations The Holocaust Rescuers of Jews Righteousness Seven Laws of Noah Yad Vashem By country Austrian Croatian German Hungarian Lithuanian Norwegian Polish (list) Romanian Serbian Ukrainian vte Konrad Rudnicki (born 2 July 1926 in Warsaw, Poland, died 12 November 2013 in Kraków, Poland) was a Polish astronomer, professor at the Jagiellonian University in Kraków, and a priest of the Old Catholic Mariavite Church.[1] He was a membe...

 

Slovenia

Republik SloveniaRepublika Slovenija (Slovenia) Bendera Lambang Lagu kebangsaan:  Zdravljica (Roti panggang) Perlihatkan BumiPerlihatkan peta EropaPerlihatkan peta BenderaLokasi  Slovenia  (hijau gelap)– di Eropa  (hijau & abu-abu)– di Uni Eropa  (hijau) Ibu kota(dan kota terbesar)Ljubljana46°3′N 14°30′E / 46.050°N 14.500°E / 46.050; 14.500Bahasa resmiSloveniaBahasa yang diakui HungariaItaliaKelompo...

 

WIAT

CBS affiliate in Birmingham, Alabama This article is about the television station in Birmingham, Alabama. For the achievement test, see Wechsler Individual Achievement Test. For other uses, see IAT. WBMG redirects here. Not to be confused with WBNG-TV. WIATBirmingham–Tuscaloosa–Anniston, AlabamaUnited StatesCityBirmingham, AlabamaChannelsDigital: 30 (UHF)Virtual: 42BrandingCBS 42ProgrammingAffiliations42.1: CBSfor others, see § SubchannelsOwnershipOwnerNexstar Media Group(Nexstar Me...

Flashdance

1983 American romantic drama film by Adrian Lyne This article is about the 1983 film. For other uses, see Flashdance (disambiguation). FlashdanceTheatrical release posterDirected byAdrian LyneScreenplay by Tom Hedley Joe Eszterhas Story byTom HedleyProduced by Don Simpson Jerry Bruckheimer Starring Jennifer Beals Michael Nouri CinematographyDonald PetermanEdited by Walt Mulconery Bud Smith Music byGiorgio MoroderProductioncompanyPolyGram PicturesDistributed byParamount PicturesRelease date Ap...

 

國民陣線

国民阵线Barisan NasionalNational Frontباريسن ناسيونلபாரிசான் நேசனல்国民阵线标志简称国阵，BN主席阿末扎希总秘书赞比里署理主席莫哈末哈山总财政希山慕丁副主席魏家祥维纳斯瓦兰佐瑟古律创始人阿都拉萨成立1973年1月1日 (1973-01-01)[1]设立1974年7月1日 (1974-07-01)前身 联盟总部 马来西亚  吉隆坡 50480 秋傑区敦依斯迈路太子世贸中心（英�...

 

Koronas-Foton

Russo Research Satllite Koronas-FotonMission typeSolar researchOperatorRoskosmosMEPhINIIEMCOSPAR ID2009-003A SATCAT no.33504Mission duration3 years planned10 months achieved[citation needed] Spacecraft propertiesBusMeteor-MLaunch mass1,900 kilograms (4,200 lb) Start of missionLaunch date30 January 2009, 13:30:00 (2009-01-30UTC13:30Z) UTCRocketTsyklon-3Launch sitePlesetsk 32/2 End of missionDisposalDecommissioned after malfunctionDeactivated1 December 2009 ...

L-410

L-410 L-410 merupakan salah satu pesawat penumpang sipil (airliner) komersial bertenaga baling-baling yang dibuat oleh perusahaan Ceko. Pesawat ini diproduksi di Let Kunovice. Dipakai pertama kali pada tahun 1970. Diproduksi tahun 1969. Sejak tahun 2017, maskapai dalam negeri, Susi Air mulai mengoperasikan pesawat ini dengan jenis LET 410 UVP-E20[1]. Maskapai yang beroperasi South East Asian Airlines (7) Kazan Air Enterprize (13) Rovno Universal Avia (13) Atlantic Airlines de Honduras...

 

Diego Morales (politician)

Indiana politician Diego MoralesAddressing CPAC Hungary 2023Secretary of State of IndianaIncumbentAssumed office January 1, 2023GovernorEric HolcombPreceded byHolli Sullivan Personal detailsBorn (1979-02-15) February 15, 1979 (age 45)GuatemalaPolitical partyRepublicanSpouseSidoniaResidence(s)Indianapolis, Indiana, U.S.EducationIndiana University, Southeast (BA)Purdue University (MBA) Diego Morales (born February 15, 1979) is a Guatemalan-American politician from Indiana. A Republican...

 

Appalachian Ohio

Region of Ohio Appalachian Ohio, shaded in green, shown within Appalachia. Appalachian Ohio is a bioregion and political unit in the southeastern part of the U.S. state of Ohio, characterized by the western foothills of the Appalachian Mountains and the Appalachian Plateau. The Appalachian Regional Commission defines the region as consisting of thirty-two counties.[1] This region roughly overlaps with the Appalachian mixed-mesophytic forests, which begin in southeast Ohio and southwes...

Robert Horne, 1st Viscount Horne of Slamannan

British politician (1871–1940) The Right HonourableThe Viscount Horne of SlamannanGBE PC KCChancellor of the ExchequerIn office1 April 1921 – 19 October 1922MonarchGeorge VPrime MinisterDavid Lloyd GeorgePreceded byAusten ChamberlainSucceeded byStanley BaldwinPresident of the Board of TradeIn office19 March 1920 – 1 April 1921MonarchGeorge VPrime MinisterDavid Lloyd GeorgePreceded bySir Auckland GeddesSucceeded byStanley BaldwinMinister of LabourIn office10 Jan...

 

Dál Riata

Gaelic kingdom that included parts of western Scotland and northeastern Ulster in Ireland Dalriada redirects here. For the neighbouring Irish kingdom sometimes called Dalaradia, see Dál nAraidi. For other uses, see Dalriada (disambiguation). Dál Riata498–850Satellite image of Scotland and Northern Ireland showing the approximate greatest extent of Dál Riata (shaded). The mountainous spine which separates the east and west coasts of Scotland can be seen.CapitalDunaddCommon languagesO...

 

一中同表

一中同表，是台灣处理海峡两岸关系问题的一种主張，認為中华人民共和国與中華民國皆是“整個中國”的一部份，二者因為兩岸現狀，在各自领域有完整的管辖权，互不隶属，同时主張，二者合作便可以搁置对“整个中國”的主权的争议，共同承認雙方皆是中國的一部份，在此基礎上走向終極統一。最早是在2004年由台灣大學政治学教授張亞中所提出，希望兩岸由一中各表�...

USCGC Cayuga

Lake-class cutter of the United States Coast Guard USCGC Cayuga underway, circa 1936 History United States NameUSCGC Cayuga NamesakeLake Cayuga BuilderUnited Shipyards, Inc. Launched7 October 1931 Commissioned22 March 1932 Decommissioned12 May 1941 Fate Transferred to Royal Navy 12 May 1941 United Kingdom NameHMS Totland NamesakeTotland Bay Launched7 Oct 1931 Commissioned12 May 1941 DecommissionedMay 1946 IdentificationY88 Fate Returned to USCG May 1946 United States NameUSCGC Mocoma Namesake...

 

Flora and fauna of Cornwall

Some of the plants in Trebah garden Cornwall is known for its Cornish palm (Cordyline australis). These examples are at St Mary's Church, in Penzance Cornwall is the county that forms the tip of the southwestern peninsula of England; this area has a mild and warm climate regulated by the Gulf Stream. The mild climate allows rich plant cover, such as palm trees in the far south and west of the county and in the Isles of Scilly, due to sub-tropical conditions in the summer. On Cornwall's moors...

 

Jérémy Clément

Questa voce sull'argomento calciatori francesi è solo un abbozzo. Contribuisci a migliorarla secondo le convenzioni di Wikipedia. Segui i suggerimenti del progetto di riferimento. Jérémy ClémentNazionalità Francia Altezza180 cm Peso77 kg Calcio RuoloAllenatore (ex centrocampista) Termine carriera18 aprile 2020 - giocatore CarrieraSquadre di club1 2003-2006 Olympique Lione35 (1)2006-2007 Rangers19 (0)2007-2011 Paris Saint-Germain140 (5)2011-2017 Saint-Étien...

Lahti L-39

Questa voce o sezione sull'argomento armi da fuoco non cita le fonti necessarie o quelle presenti sono insufficienti. Commento: Bibliografia inesistente. Puoi migliorare questa voce aggiungendo citazioni da fonti attendibili secondo le linee guida sull'uso delle fonti. Segui i suggerimenti del progetto di riferimento. Questa voce o sezione sull'argomento armi da fuoco è priva o carente di note e riferimenti bibliografici puntuali. Commento: Due sole note: voce per lo più senza ri...

 

Jans Martense Schenck house

Historic house in New York City Jans Martense Schenck house New Netherland series Exploration Fortifications: Fort Amsterdam Fort Nassau (North) Fort Orange Fort Nassau (South) Fort Goede Hoop De Wal Fort Casimir Fort Altena Fort Wilhelmus Fort Beversreede Fort Nya Korsholm De Rondout Settlements: Noten Eylandt Nieuw Amsterdam Rensselaerswijck Nieuw Haarlem Beverwijck Wiltwijk Bergen Pavonia Vriessendael Achter Col Vlissingen Oude Dorpe Colen Donck Greenwich Heemstede Rustdorp Gravesende Breu...