Pine Mountain Valley is located at 32° 47′ 55″ N, 84° 49′ 24″ W (32.798611 N, -84.823333 W).[2] The community is located at the intersection of Georgia State Routes 116 and 354. GA-116 runs from west to east through the community, leading east 9 mi (14 km) to Shiloh and southwest 4 mi (6.4 km) to Hamilton, the Harris County seat. GA-354 runs northwest 7 mi (11 km) to the city of Pine Mountain. The community is located in the Piedmont region of the state just to the south of the Pine Mountain Range.