Water (H 2O) is the oxide of hydrogen and most familiar oxygen compound. Its bulk properties partly result from the interaction of its component atoms, oxygen and hydrogen, with atoms of nearby water molecules. Hydrogen atoms are covalently bonded to oxygen in a water molecule but also have an additional attraction (about 23.3 kJ·mol−1 per hydrogen atom) to an adjacent oxygen atom in a separate molecule.[2] These hydrogen bonds between water molecules hold them approximately 15% closer than what would be expected in a simple liquid with just Van der Waals forces.[3][4]
Oxides, such as iron oxide or rust, Fe 2O 3, form when oxygen combines with other elements
Due to its electronegativity, oxygen forms chemical bonds with almost all other free elements at elevated temperatures to give corresponding oxides. However, some elements, such as iron which oxidises to iron oxide, or rust, Fe 2O 3, readily oxidise at standard conditions for temperature and pressure (STP). The surface of metals like aluminium and titanium are oxidized in the presence of air and become coated with a thin film of oxide that passivates the metal and slows further corrosion.[5] So-called noble metals, such as gold and platinum, resist direct chemical combination with oxygen, and substances like gold(III) oxide (Au 2O 3) must be formed by an indirect route.
The alkali metals and alkali earth metals all react spontaneously with oxygen when exposed to dry air to form oxides, and form hydroxides in the presence of oxygen and water. As a result, none of these elements is found in nature as a free metal. Caesium is so reactive with oxygen that it is used as a getter in vacuum tubes. Although solid magnesium reacts slowly with oxygen at STP, it is capable of burning in air, generating very high temperatures, and its metal powder may form explosive mixtures with air.
Peroxides retain some of oxygen's original molecular structure ((−O-O−). White or light yellow sodium peroxide (Na 2O 2) is formed when metallic sodium is burned in oxygen. Each oxygen atom in its peroxide ion may have a full octet of 4 pairs of electrons.[6]Superoxides are a class of compounds that are very similar to peroxides, but with just one unpaired electron for each pair of oxygen atoms (O− 2).[6] These compounds form by oxidation of alkali metals with larger ionic radii (K, Rb, Cs). For example, potassium superoxide (KO 2) is an orange-yellow solid formed when potassium reacts with oxygen.
Hydrogen peroxide (H 2O 2) can be produced by passing a volume of 96% to 98% hydrogen and 2 to 4% oxygen through an electric discharge.[7] A more commercially-viable method is to allow autoxidation of an organic intermediate, 2-ethylanthrahydroquinone dissolved in an organic solvent, to oxidize to H 2O 2 and 2-ethylanthraquinone.[7] The 2-ethylanthraquinone is then reduced and recycled back into the process.
Oxygen can form oxides with heavier noble gases xenon and radon, although this needs indirect methods. Even though no oxides of krypton are known, oxygen is able to form covalent bonds with krypton in an unstable compound Kr(OTeF5)2.
One unexpected oxygen compound is dioxygenyl hexafluoroplatinate, O+ 2PtF− 6, discovered in studying the properties of platinum hexafluoride (PtF 6).[8] A change in color when this compound was exposed to atmospheric air suggested that dioxygen was being oxidized (in turn the difficulty of oxidizing oxygen led to the hypothesis that xenon might be oxidized by PtF 6, resulting in discovery of the first xenon compound xenon hexafluoroplatinateXe+ PtF− 6). The cations of oxygen are formed only in the presence of stronger oxidants than oxygen, which limits them to the action of fluorine and certain fluorine compounds. Simple oxygen fluorides are known.[9]
Organic compounds
Acetone is an important feeder material in the chemical industry. (oxygen is in red, carbon in black and hydrogen in white)
Oxygen reacts spontaneously with many organic compounds at or below room temperature in a process called autoxidation.[7] Alkaline solutions of pyrogallol, benzene-1,2,3-triol absorb oxygen from the air, and are used in the determination of the atmospheric concentration of oxygen. Most of the organic compounds that contain oxygen are not made by direct action of oxygen. Organic compounds important in industry and commerce are made by direct oxidation of a precursor include:[6]
The element is found in almost all biomolecules that are important to, or generated by, life. Only a few common complex biomolecules, such as squalene and the carotenes, contain no oxygen. Of the organic compounds with biological relevance, carbohydrates contain the largest proportion by mass of oxygen (about 50%). All fats, fatty acids, amino acids, and proteins contain oxygen (due to the presence of carbonyl groups in these acids and their ester residues). Furthermore, seven of the amino acids which are incorporated into proteins, have oxygen incorporated into their side-chains, as well. Oxygen also occurs in phosphate (PO43−) groups in the biologically important energy-carrying molecules ATP and ADP, in the backbone and the purines (except adenine) and pyrimidines of RNA and DNA, and in bones as calcium phosphate and hydroxylapatite.
^Chemical properties of Oxygen[1], Lenntech. Accessed January 25, 2008. "Oxygen is reactive and will form oxides with all other elements except helium, neon, argon and krypton."
^P. Maksyutenko, T. R. Rizzo, and O. V. Boyarkin (2006). "A direct measurement of the dissociation energy of water", J. Chem. Phys. 125 doi 181101.
^Also, since oxygen has a higher electronegativity than
hydrogen, the charge difference makes it a polar molecule. The interactions between the different dipoles of each molecule cause a net attraction force.
^Cotton, F. Albert and Wilkinson, Geoffrey (1972). Advanced Inorganic Chemistry: A comprehensive Text. (3rd Edition). New York, London, Sydney,
Toronto: Interscience Publications. ISBN0-471-17560-9.
