One of the key observations of Kirillov was that coadjoint orbits of a Lie group G have natural structure of symplectic manifolds whose symplectic structure is invariant under G. If an orbit is the phase space of a G-invariant classical mechanical system then the corresponding quantum mechanical system ought to be described via an irreducible unitary representation of G. Geometric invariants of the orbit translate into algebraic invariants of the corresponding representation. In this way the orbit method may be viewed as a precise mathematical manifestation of a vague physical principle of quantization. In the case of a nilpotent group G the correspondence involves all orbits, but for a general G additional restrictions on the orbit are necessary (polarizability, integrality, Pukánszky condition). This point of view has been significantly advanced by Kostant in his theory of geometric quantization of coadjoint orbits.
Complex irreducible representations of compact Lie groups have been completely classified. They are always finite-dimensional, unitarizable (i.e. admit an invariant positive definite Hermitian form) and are parametrized by their highest weights, which are precisely the dominant integral weights for the group. If G is a compact semisimple Lie group with a Cartan subalgebrah then its coadjoint orbits are closed and each of them intersects the positive Weyl chamber h*+ in a single point. An orbit is integral if this point belongs to the weight lattice of G.
The highest weight theory can be restated in the form of a bijection between the set of integral coadjoint orbits and the set of equivalence classes of irreducible unitary representations of G: the highest weight representation L(λ) with highest weight λ∈h*+ corresponds to the integral coadjoint orbit G·λ. The Kirillov character formula amounts to the character formula earlier proved by Harish-Chandra.
^Vogan, David (1986), "Representations of reductive Lie groups", Proceedings of the International Congress of Mathematicians (Berkeley, California): 245–266
Dulfo; Pederson; Vergne (1990), The Orbit Method in Representation Theory: Proceedings of a Conference Held in Copenhagen, August to September 1988 (Progress in Mathematics), Birkhäuser
Kirillov, A. A. (1961), "Unitary representations of nilpotent Lie groups", Doklady Akademii Nauk SSSR, 138: 283–284, ISSN0002-3264, MR0125908
Kirillov, A. A. (1976) [1972], Elements of the theory of representations, Grundlehren der Mathematischen Wissenschaften, vol. 220, Berlin, New York: Springer-Verlag, ISBN978-0-387-07476-4, MR0412321