Cyclobutadieneiron tricarbonyl is an organoiron compound with the formula Fe(C4H4)(CO)3. It is a yellow oil that is soluble in organic solvents. It has been used in organic chemistry as a precursor for cyclobutadiene, which is an elusive species in the free state.[1]
Cyclobutadieneiron tricarbonyl was first prepared in 1965 by Pettit from 3,4-dichlorocyclobutene and diiron nonacarbonyl:[2][3]
The compound is an example of a piano stool complex. The C-C distances are 1.426 Å.[4]
Oxidative decomplexation of cyclobutadiene is achieved by treating the tricarbonyl complex with ceric ammonium nitrate. The released cyclobutadiene is trapped with a quinone, which functions as a dienophile.[5]
Cyclobutadieneiron tricarbonyl displays aromaticity as evidenced by some of its reactions, which can be classified as electrophilic aromatic substitution:[6]
It undergoes Friedel-Crafts acylation with acetyl chloride and aluminium chloride to give the acyl derivative 2, with formaldehyde and hydrochloric acid to the chloromethyl derivative 3, in a Vilsmeier-Haack reaction with N-methylformanilide and phosphorus oxychloride to the formyl 4, and in a Mannich reaction to amine derivative 5.
The reaction mechanism is identical to that of EAS:
Several years before Petit's work, (C4Ph4)Fe(CO)3 had been prepared from the reaction of iron carbonyl and diphenylacetylene.[7]
(Butadiene)iron tricarbonyl is isoelectronic with cyclobutadieneiron tricarbonyl.
In 1956, Longuet-Higgins and Orgel[8] predicted the existence of transition-metal cyclobutadiene complexes, in which the degenerate eg orbital of cyclobutadiene has the correct symmetry for π interaction with the dxz and dyz orbitals of the proper metal. The compound was synthesized three years after the prediction[9] This is a case of theory before experiment.[10]
For the former Montreal amusement park ride, see La Ronde (amusement park). Vacuum tube which generates high-frequency radio waves High-power 140 GHz gyrotron for plasma heating in the Wendelstein 7-X fusion experiment, Germany. A gyrotron is a class of high-power linear-beam vacuum tubes that generates millimeter-wave electromagnetic waves by the cyclotron resonance of electrons in a strong magnetic field. Output frequencies range from about 20 to 527 GHz,[1][2] covering wavelen…
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