(in a chain polymerization) Chemical reaction between a chain carrier and a monomer that results in the growth of a polymer chain and the regeneration of at least one chain carrier.
Note 1: The recommended symbol for the rate constant for chain propagation in a homopolymerization is kp.
In chemistry, chain propagation (sometimes just referred to as propagation) is a process in which a reactive intermediate is continuously regenerated during the course of a chemical chain reaction. For example, in the chlorination of methane, there is a two-step propagation cycle involving as chain carriers a chlorine atom and a methyl radical[1] which are regenerated alternately:
·Cl + CH4 → HCl + ·CH3
·CH3 + Cl2 → CH3Cl + ·Cl
The two steps add to give the equation for the overall chain reaction:
CH4 + Cl2 → CH3Cl + HCl
Polymerization
In a chain-growth polymerization reaction, the reactive end-groups of a polymer chain react in each propagation step with a new monomer molecule transferring the reactive group to the last unit. Here the chain carrier is the polymer molecule with a reactive end-group, and at each step it is regenerated with the addition of one monomer unit M:
![{\displaystyle {\bigl [}{\ce {-M -}}{\bigr ]}_{n}+{\ce {M}}\rightarrow {\bigl [}{\ce {-M -}}{\bigr ]}_{n+1}}](https://wikimedia.org/api/rest_v1/media/math/render/svg/8a6a6d629ccd097107553581e6e5bbdbcce32862)
